PROCESSES AND APPARATUS FOR REFINING SUGARCANE TO PRODUCE SUGARS, BIOFUELS, AND/OR BIOCHEMICALS

• US 20150079639A1
• Filed: 09/15/2014
• Published: 03/19/2015
• Est. Priority Date: 09/16/2013
• Status: Active Grant

• Current Assignee: GranBio Intellectual Property Holdings, LLC
• Original Assignee: API Intellectual Property Holdings, LLC
• Inventors: RETSINA, Theodora, O'CONNOR, Ryan
• Granted Patent: US 9,487,840 B2
• Time in Patent Office: Days
• US Class Current: 435/99
• CPC Class Codes: C12P 19/02 Monosaccharides 2-ketogulonic acid C12P7/60
• CPC Class Codes: C12P 19/14 produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase , e.g. by cellulase, hemicellulase
• CPC Class Codes: C12P 2201/00 Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
• CPC Class Codes: C12P 7/06 Ethanol, i.e. non-beverage
• CPC Class Codes: C13B 20/002 using microorganisms or enzymes
• CPC Class Codes: C13B 35/08 by physical means, e.g. osmosis
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: C13K 13/00 Sugars not otherwise provided for in this class
• CPC Class Codes: F23G 7/10 of field or garden waste or biomasses
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

Conventionally, sugarcane processing avoids leaving residual sucrose in the bagasse, since the bagasse will be burned and the value of the sucrose would be lost. However, when coupled with a Green Power+® process to extract hemicelluloses, sucrose may also be extracted and recovered from the bagasse. In some variations, a process includes mechanically treating a feedstock to generate a sucrose-rich stream and lignocellulosic material that intentionally retains a significant amount of the initial sucrose in the feedstock; extracting the lignocellulosic material with steam and/or hot water to produce cellulose-rich solids and an extract liquor containing hemicellulosic oligomers and sucrose; and then hydrolyzing the hemicellulosic oligomers into a hemicellulose sugar stream. Each of the sucrose-rich stream and the hemicellulose sugar stream (containing the starting residual sucrose) may be recovered or further processed (e.g., fermented to ethanol). Similar processes are possible with energy cane, sugar beets, and energy beets.

Claims

1. A process for refining a sucrose-containing feedstock, said process comprising:

(a) providing a feedstock containing lignocellulosic material and sucrose;

(b) mechanically treating said feedstock to generate a sucrose-rich stream and sucrose-depleted lignocellulosic material, wherein said sucrose-depleted lignocellulosic material retains at least 1% of the initial sucrose contained in said feedstock;

(c) extracting said sucrose-depleted lignocellulosic material with steam and/or hot water to produce cellulose-rich solids and an extract liquor containing hemicellulosic oligomers and extracted sucrose;

(d) hydrolyzing said hemicellulosic oligomers into a hemicellulose sugar stream, wherein said hemicellulose sugar stream comprises said extracted sucrose or a hydrolyzed form thereof;

(e) recovering or further processing said hemicellulose sugar stream;

(f) recovering or further processing said sucrose-rich stream; and

(g) combusting said cellulose-rich solids to produce steam and/or electricity.

2. The process of claim 1, wherein said feedstock is selected from the group consisting of sugarcane, energy cane, sugar beets, and energy beets.

3. The process of claim 2, wherein said feedstock is sugarcane and said lignocellulosic material contains sugarcane bagasse and optionally sugarcane straw.

4. The process of claim 1, wherein said extracted lignocellulosic material retains at least 2% of said initial sucrose contained in said feedstock.

5. The process of claim 4, wherein said extracted lignocellulosic material retains at least 5% of said initial sucrose contained in said feedstock.

6. The process of claim 1, wherein said extracted lignocellulosic material retains from about 1% to about 10% of said initial sucrose contained in said feedstock.

7. The process of claim 6, wherein said extracted lignocellulosic material retains from about 3% to about 6% of said initial sucrose contained in said feedstock.

8. The process of claim 1, wherein step (c) further includes introducing an extraction catalyst selected from an organic acid, an inorganic acid, or combinations thereof.

9. The process of claim 1, wherein step (d) employs an acid catalyst for said hydrolyzing said hemicellulosic oligomers.

10. The process of claim 1, wherein step (d) employs an enzyme catalyst for said hydrolyzing said hemicellulosic oligomers.

11. The process of claim 1, wherein at least a portion of said hemicellulose sugar stream is fermented to a fermentation product.

12. The process of claim 1, wherein at least a portion of said hemicellulose sugar stream is recovered as purified hemicellulose sugars.

13. The process of claim 1, wherein at least a portion of said sucrose-rich stream is fermented to ethanol or another fermentation product.

14. The process of claim 1, wherein at least a portion of said sucrose-rich stream is recovered as purified sucrose sugar.

15. A process for refining sugarcane, said process comprising:

(a) providing a feedstock containing sugarcane;

(b) mechanically treating said feedstock to generate a sucrose-rich stream and sucrose-depleted lignocellulosic material, wherein said sucrose-depleted lignocellulosic material retains from about 1% to about 10% of the initial sucrose contained in said sugarcane;

(c) extracting said sucrose-depleted lignocellulosic material with steam and/or hot water to produce cellulose-rich solids and an extract liquor containing hemicellulosic oligomers and extracted sucrose;

(d) hydrolyzing said hemicellulosic oligomers into a hemicellulose sugar stream, wherein said hemicellulose sugar stream comprises said extracted sucrose or a hydrolyzed form thereof;

(e) recovering or further processing said hemicellulose sugar stream;

(f) recovering or fermenting said sucrose-rich stream; and

(g) combusting said cellulose-rich solids to produce steam and/or electricity.

16. A process for refining a sucrose-containing feedstock, said process comprising:

(a) providing a feedstock containing lignocellulosic material and sucrose;

(b) mechanically treating said feedstock to generate a sucrose-rich stream and sucrose-depleted lignocellulosic material, wherein said extracted lignocellulosic material retains at least 1% of the initial sucrose contained in said feedstock;

(c) extracting said sucrose-depleted lignocellulosic material with steam and/or hot water to produce cellulose-rich solids and an extract liquor containing hemicellulosic oligomers and extracted sucrose;

(d) hydrolyzing said hemicellulosic oligomers into a hemicellulose sugar stream, wherein said hemicellulose sugar stream comprises said extracted sucrose or a hydrolyzed form thereof;

(e) recovering or further processing said hemicellulose sugar stream; and

(f) recovering or further processing said sucrose-rich stream.

17. The process of claim 16, wherein said cellulose-rich solids are combusted to produce steam and/or electricity.

18. The process of claim 16, wherein said cellulose-rich solids are pelletized.

19. The process of claim 16, wherein said cellulose-rich solids are utilized as a pulp intermediate or pulp product.

20. The process of claim 16, wherein said cellulose-rich solids are hydrolyzed to produce glucose.