TEMPERATURE-RESISTANT, TRANSPARENT ELECTRICAL CONDUCTOR, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF

• US 20150101849A1
• Filed: 10/14/2014
• Published: 04/16/2015
• Est. Priority Date: 10/11/2013
• Status: Abandoned Application

• Current Assignee: Schott AG (Carl-Zeiss-Stiftung)
• Original Assignee: Schott AG (Carl-Zeiss-Stiftung)
• Inventors: Bockmeyer, Matthias, Hoffmann, Ulf, Riethmueller, Franziska
• Application Number:
  US14/513,274
• Publication Number:
  US 20150101849A1
• Time in Patent Office: Days
• US Class Current: 174/257
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 80/00 Products made by additive manufacturing
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 17/008 comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
• CPC Class Codes: C03C 2217/445 Organic continuous phases
• CPC Class Codes: C03C 2217/479 Metals
• CPC Class Codes: H05K 1/0274 Optical details, e.g. printed circuits comprising integral optical means H05K1/0269 takes precedence; coupling light guides with opto-electronic components G02B6/42
• CPC Class Codes: H05K 1/0306 Inorganic insulating substrates, e.g. ceramic, glass
• CPC Class Codes: H05K 1/097 Inks comprising nanoparticles and specially adapted for being sintered at low temperature H05K1/095 takes precedence
• CPC Class Codes: H05K 3/1216 by screen printing or stencil printing
• CPC Class Codes: H05K 3/125 by ink-jet printing
• CPC Class Codes: H05K 3/1291 Firing or sintering at relative high temperatures for patterns on inorganic boards, e.g. co-firing of circuits on green ceramic sheets
• CPC Class Codes: H05K 3/14 using spraying techniques to apply the conductive material , e.g. vapour evaporation
• CPC Class Codes: H05K 3/4664 Adding a circuit layer by thick film methods, e.g. printing techniques or by other techniques for making conductive patterns by using pastes, inks or powders H05K3/4647 takes precedence
• CPC Class Codes: Y10S 977/834 Optical properties of nanomaterial, e.g. specified transparency, opacity, or index of refraction
• CPC Class Codes: Y10S 977/932 for electronic or optoelectronic application

Abstract

A transparent electrical conductor with a transparent substrate and an electrically conductive layer on the substrate are provided. The conductive layer has a plurality of electrically conductive nanoscale additives. The additives are in electrically conductive contact with one another, in order to form the electrically conductive layer. The substrate is formed from a glass or glass-ceramic material or a composite material having a glass and/or glass-ceramic. The additives are embedded in a matrix layer at least in some regions. The matrix layer is formed by a transparent matrix material. In order to make such a transparent electrical conductor useful, particularly for application in a display, as a touch sensor, or the like for cooking surfaces, the transparent electrical conductor exhibits a temperature resistance of at least 140° C. The additives are dispersed in a matrix material, which is applied as a coating material onto the substrate in one coating step.

Claims

1. A transparent electrical conductor, comprising:

a transparent substrate formed from a material selected from the group consisting of glass, glass-ceramic, a composite material glass, a composite material having glass ceramic, and combinations thereof; and

an electrically conductive layer on the transparent substrate, the electrically conductive layer having a plurality of electrically conductive, nanoscale additives, the additives being in electrically conductive contact with one another in order to form the electrically conductive layer, the additives being embedded in a matrix layer at least in some regions, the matrix layer being formed by a transparent matrix material, wherein the transparent electrical conductor has a temperature resistance of at least 140°

C.

2. The transparent electrical conductor according to claim 1, wherein the electrically conductive layer has a scratch resistance of at least 500 g and/or a sheet resistance of less than 500 ohm/sq.

3. The transparent electrical conductor according to claim 1, further comprising a light transmission (λ

) of at least 75% for a substrate thickness of 4 mm and at wavelengths greater than 450 nm and/or a haze value of less than 15%.

4. The transparent electrical conductor according to claim 1, wherein the transparent matrix material comprises a material selected from the group consisting of UV-curable polymers, thermally curable polymers, silicone, UV-crosslinkable or thermally organically crosslinkable hybrid-polymeric sol-gel materials, hybrid-polymeric sol-gel materials, nanoparticle-functionalized sol-gel materials, sol-gel materials containing nanoparticle fillers, and inorganic sol-gel materials exhibiting a temperature resistance of at least 140°

C.

5. The transparent electrical conductor according to claim 4, wherein the transparent matrix material comprises at least one condensed and/or hydrolyzed monomer of metal alkoxides.

6. The transparent electrical conductor according to claim 5, wherein the metal alkoxides are selected from the group consisting of silicon, zirconium, titanium, aluminum, organometallic alkoxides, and combinations thereof.

7. The transparent electrical conductor according to claim 5, wherein the transparent matrix material further comprises a tetraalkoxysilane Si(OR¹)₄ with R¹=methyl, ethyl, propyl, iso-propyl, butyl, sec. butyl, phenyl, or another metal alkoxide.

8. The transparent electrical conductor according to claim 7, wherein the transparent matrix material further comprises another alkoxysilane Si(OR¹)₃R², which has an organically crosslinkable functionality (with R²=alkyl chain functionalized with glycidoxy, methacryloxy, acryl, vinyl, allyl, amino, mercapto, isocyanato) and/or another metal alkoxide and/or another organoalkoxy silane Si(OR¹)₃R³ or Si(OR¹)₂R³₂ or Si(OR¹)R³₃ with R³:

methyl, phenyl, ethyl, iso-propyl, butyl, sec. butyl.

9. The transparent electrical conductor according to claim 1, wherein the transparent matrix material has a zeta potential of adjusted to a zeta potential of the additives.

10. The transparent electrical conductor according to claim 9, wherein the transparent matrix material further comprises, as zeta potential adjustors, materials selected from the group consisting of sol-gel starting materials, doping with another sol-gel starting material, and a suitable dispersant.

11. The transparent electrical conductor according to claim 10, wherein the doping with another sol-gel starting material comprises dopants selected from the group consisting of metal alkoxide, a metal hydroxide, a metal halide, a metal nitrate, a metal acetylacetonate, a metal acetate, a metal carbonate, a metal oxide, and combinations thereof.

12. The transparent electrical conductor according to claim 9, wherein the additive further comprises, as zeta potential adjustors, an acidic dispersant or a basic dispersant.

13. The transparent electrical conductor according to claim 12, wherein the acidic dispersant comprises an acid selected from the group consisting of paratoluenesulfonic acid, polyvalent acid, citric acid, and polyacrylic acid, and wherein the basic dispersant comprises polyethylenimine.

14. The transparent electrical conductor according to claim 1, wherein the transparent matrix material comprises a volume percentage of alkoxysilane with organically crosslinkable functionality sufficient such that the additives are sterically dispersed in a liquid state, but are in contact with one another in a cured state.

15. The transparent electrical conductor according to claim 1, wherein the additives have a fiber-like morphology having an aspect ratio of length to diameter that lies in a range of 10 to 100,000.

16. The transparent electrical conductor according to claim 1, wherein the additives comprise a material having an electrical conductivity of greater than 10⁴ S/m.

17. The transparent electrical conductor according to claim 1, wherein the additives comprise silver, copper, gold, and alloys thereof.

18. The transparent electrical conductor according to claim 1, wherein the additives have a mean diameter that lies in a range of 40 to 150 nm.

19. The transparent electrical conductor according to claim 1, wherein the additives further comprise a coating layer having a low oxidation tendency.

20. The transparent electrical conductor according to claim 1, wherein the material of the transparent substrate is selected from the group consisting of single colored glass ceramic, lithium aluminosilicate (LAS) glass ceramic, magnesium aluminosilicate glass ceramic, silicate glass, boroaluminosilicate glass, aluminosilicate glass, alkali-free glass, soda-lime glass, and any composites thereof.

21. The transparent electrical conductor according to claim 1, wherein the transparent substrate has a coefficient of thermal expansion of less than 4.0×

10<sup>−

6</sup>/K.

22. A method for the production of a transparent electrical conductor, comprising:

dispersing and embedding a plurality of electrically conductive nanoscale additives in a transparent matrix material; and

applying the transparent matrix material directly or indirectly onto a substrate to form an electrically conductive layer.

23. The method according to claim 22, wherein, prior to the step of dispersing and embedding, the additives and/or the transparent matrix material are both present in a solvent selected from the group consisting of a low-boiling solvent, a high-boiling solvent, and a solvent mixture composed of at least one low-boiling solvent and at least one high-boiling solvent.

24. The method according to claim 22, further comprising curing the electrically conductive layer and, after curing, subjecting the electrically conductive layer to a thermal post-treatment at 150 to 500°

C. for 5 minutes to 4 hours.

25. The method according to claim 22, the transparent matrix material comprises at least one condensed and/or hydrolyzed monomer of metal alkoxides, preferably silicon, zirconium, titanium, aluminum, and/or organometallic alkoxides, preferably Si(OR)₄, SiR(OR)₃, or SiR₂(OR)₂, with R=organic functionality and OR=alkoxide functionality.

26. The method according to claim 22, wherein the step of applying the transparent matrix material comprises a process selected from the group consisting of screen-printing, doctor-blade lacquering, ink-jetting, spray lacquering, roll-coating lacquering, spin-coating lacquering, and pad lacquering.

27. The method according to claim 22, further comprising dispersing metallic nanowires or nanotubes as the additives in the transparent matrix material.

28. The method according to claim 22, wherein the step of applying the transparent matrix material comprises applying two or more layers onto the substrate.

29. The method according to claim 28, further comprising introducing a layer having a dielectric material and/or an antireflection layer between the two or more layers.

30. The method according to claim 22, wherein the step of applying the transparent matrix material comprises applying the transparent matrix material to the substrate in one or more subregions in a laterally structured manner.

31. The method according to claim 22, further comprising increasing connectivity between the additives by a process selected from the group consisting of a thermal post-treatment at 150 to 500°

C. for 10 minutes to 3 hours, a treatment under pressure, exploiting matrix shrinkage during curing, utilizing a conductive polymer as matrix or sheath material for the additives.