BULK NICKEL-BASED GLASSES BEARING CHROMIUM, NIOBIUM, PHOSPHORUS AND SILICON

• US 20150159242A1
• Filed: 12/09/2014
• Published: 06/11/2015
• Est. Priority Date: 12/09/2013
• Status: Active Grant

• Current Assignee: Apple Inc.
• Original Assignee: Glassimetal Technology Inc.
• Inventors: Na, Jong Hyun, Floyd, Michael, Duggins, Danielle, Garrett, Glenn, Demetriou, Marios D., Johnson, William L.
• Granted Patent: US 9,920,400 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: C22C 1/11 Making amorphous alloys
• CPC Class Codes: C22C 19/05 with chromium
• CPC Class Codes: C22C 19/056 with the maximum Cr content being at least 10% but less than 20%
• CPC Class Codes: C22C 19/058 without Mo and W
• CPC Class Codes: C22C 45/04 with nickel or cobalt as the major constituent

Abstract

The disclosure is directed to Ni—Cr—P eutectic alloys bearing Nb as substitution for Cr that are capable of forming metallic glasses with critical rod diameter of at least 1 mm or more. With further minority addition of Si as replacement for P, such alloys are capable of forming metallic glasses with critical rod diameters as high as 10 mm or more. Specifically, Ni-based compositions with a Cr content of between 5 and 14 atomic percent, Nb content of between 3 and 4 atomic percent, P content of between 17.5 and 19 atomic percent, and Si content of between 1 and 2 atomic percent, were capable of forming bulk metallic glass rods with diameters as large as 6 mm or larger.

Claims

1. An alloy capable of forming a metallic glass represented by the following formula (subscripts a, b, c, and d denote atomic percentages):

Ni_{(100-a-b-c-d)}Cr_aNb_bP_cSi_d,

where a is between 2 and 18, b is between 1 and 6, c is between 16 and 20, d is up to 4, and wherein the critical rod diameter of the alloy is at least 1 mm.

2. The alloy according to claim 1 where a is between 3 and 16, b is between 2 and 5, c is between 16.5 and 19.5, d is between 0 and 3, wherein the critical rod diameter of the alloy is at least 3 mm.

3. The alloy according to claim 1 where a is between 4 and 14, b is between 2.5 and 4.5, c is between 17.5 and 19, d is between 0.5 and 2.5, wherein the critical rod diameter of the alloy is at least 5 mm.

4. The alloy according to claim 1 where a is between 5 and 7, b is between 2.5 and 4.5, c is between 17.5 and 19, d is between 0.5 and 2.5, wherein the critical rod diameter of the alloy is at least 6 mm.

5. The alloy according to claim 1 where a is between 8 and 13, b is between 2.5 and 4.5, c is between 17.5 and 19, d is between 0.5 and 2.5, wherein the critical rod diameter of the alloy is at least 6 mm.

6. The alloy according to claim 1 where a is between 9 and 12, b is between 3 and 4, c is between 17.5 and 18.5, d is between 1 and 2, wherein the critical rod diameter of the alloy is at least 8 mm.

7. The alloy according to claim 1 where the sum of c and d is between 18.5 and 21, wherein the critical rod diameter of the alloy is at least 3 mm.

8. The alloy according to claim 1 where the sum of c and d is between 19 and 20, wherein the critical rod diameter of the alloy is at least 6 mm.

9. The alloy according to claim 1 where up to 30 atomic percent of Ni is substituted by Co.

10. The alloy according to claim 1 where up to 10 atomic percent of Ni is substituted by Fe.

11. The alloy according to claim 1 where up to 5 atomic percent of Ni is substituted by Cu.

12. The alloy according to claim 1 where up to 2 atomic percent of Cr is substituted by Mo, Mn, Fe, Co, W, Ru, Re, Cu, Pd, Pt, or combinations thereof.

13. The alloy according to claim 1 where up to 1 atomic percent of Nb is substituted by Mo, Mn, Ta, V, or combinations thereof.

14. A metallic glass comprising the alloy according to claim 1.

15. The metallic glass of claim 14 wherein the notch toughness is at least 60 MPa m^1/2.

16. A method of producing the metallic glass of claim 14 comprising:

melting the alloy into a molten state; and

quenching the melt at a cooling rate sufficiently rapid to prevent crystallization of the alloy.

17. The method of claim 16, further comprising fluxing the melt with a reducing agent prior to quenching.

18. The method of claim 17, wherein the reducing agent is boron oxide.

19. The method of claim 16, wherein the temperature of the melt prior to quenching is at least 1200°

C.

20. The method of claim 16, wherein the temperature of the melt prior to quenching is at least 200°

above the liquidus temperature of the alloy.