CIRCUITS AND METHODS FOR IMPEDANCE DETERMINATION USING ACTIVE MEASUREMENT CANCELATION

• US 20150168500A1
• Filed: 12/16/2013
• Published: 06/18/2015
• Est. Priority Date: 12/16/2013
• Status: Active Grant

• Current Assignee: Battelle Energy Alliance LLC (Battelle Memorial Institute)
• Original Assignee: Battelle Energy Alliance LLC (Battelle Memorial Institute)
• Inventors: JAMISON, DAVID K.
• Granted Patent: US 9,519,031 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: G01R 27/02 Measuring real or complex resistance, reactance, impedance, or other two-pole characteristics derived therefrom, e.g. time constant by measuring phase angle only G01R25/00
• CPC Class Codes: G01R 31/389 Measuring internal impedance, internal conductance or related variables
• CPC Class Codes: G01R 31/392 Determining battery ageing or deterioration, e.g. state of health

Abstract

A delta signal and opposite delta signal are generated such that a sum of the two signals is substantially zero. The delta signal is applied across a first set of electrochemical cells. The opposite delta signal is applied across a second set of electrochemical cells series connected to the first set. A first held voltage is established as the voltage across the first set. A second held voltage is established as the voltage across the second set. A first delta signal is added to the first held voltage and applied to the first set. A second delta signal is added to the second held voltage and applied to the second set. The current responses due to the added delta voltages travel only into the set associated with its delta voltage. The delta voltages and the current responses are used to calculate the impedances of their associated cells.

Claims

1. An impedance measurement circuit, comprising:

a signal creator configured to generate a delta signal and an opposite delta signal such that a sum of the delta signal and the opposite delta signal are substantially zero at any instant of time;

a first application circuit configured to apply the delta signal across a first set of cells comprising one or more electrochemical cells of a plurality of electrochemical cells operably coupled together;

a second application circuit configured to apply the opposite delta signal across a second set of cells comprising one or more electrochemical cells of the plurality of electrochemical cells, wherein the second set of cells is different from the first set of cells; and

a measurement unit configured to measure a response signal across the second set of cells when the delta signal and the opposite delta signal are being applied.

2. The impedance measurement circuit of claim 1, wherein the measurement unit is further configured to measure a held voltage across the second set of cells when the delta signal and the opposite delta signal are not being applied and further comprising an analysis module configured for analyzing the response signal relative to the held voltage to determine an impedance of the second set of cells.

3. The impedance measurement circuit of claim 1, wherein:

the plurality of electrochemical cells comprises electrochemical cells operably coupled in series;

the first set of cells comprises a first cell of the plurality of electrochemical cells; and

the second set of cells comprises a second cell of the plurality of electrochemical cells that is different from the first cell.

4. The impedance measurement circuit of claim 3, wherein the first application circuit and the measurement unit are operably coupled to form an active measurement unit, and the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the first cell.

5. The impedance measurement circuit of claim 3, wherein the second application circuit is configured to be selectively coupled to each of the plurality of electrochemical cells as the second cell.

6. The impedance measurement circuit of claim 1, wherein:

the plurality of electrochemical cells comprises electrochemical cells operably coupled in series;

the second set of cells comprises all of the plurality of electrochemical cells; and

the first set of cells comprises fewer than all of the plurality of electrochemical cells.

7. The impedance measurement circuit of claim 6, wherein the first set of cells comprises a single electrochemical cell of the plurality of electrochemical cells.

8. The impedance measurement circuit of claim 7, wherein the first application circuit and the measurement unit are operably coupled to form an active measurement unit and the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the first set of cells.

9. The impedance measurement circuit of claim 1, further comprising:

a source/load unit for respectively supplying charge pulses and discharge pulses to the plurality of electrochemical cells, wherein the charge pulses and discharge pulses include a transition rate; and

wherein the first application circuit includes a transition modifying circuit operably coupled between the source/load unit and a terminal of the plurality if plurality of electrochemical cells, the transition modifying circuit comprising at least one circuit element configured to generate an adjusted transition rate on the terminal that is slower than the transition rate and sufficient to reduce degradation of one or more charge capacity characteristics of the plurality of electrochemical cells.

10. An impedance measurement circuit, comprising:

an active measurement unit configured to;

generate a delta signal;

apply the delta signal across a first set of cells comprising one or more electrochemical cells of a plurality of electrochemical cells operably coupled together; and

measure a response signal across the first set of cells when the delta signal is being applied;

an inverter unit configured to generate an opposite delta signal such that a sum of the delta signal and the opposite delta signal are substantially zero at any instant of time; and

a cancelation unit configured to apply the opposite delta signal across a second set of cells comprising one or more electrochemical cells of the plurality of electrochemical cells at least while the response signal is being measured, wherein the second set of cells is different from the first set of cells.

11. The impedance measurement circuit of claim 10, wherein the active measurement unit is further configured to measure a held voltage across the first set of cells when the delta signal and the opposite delta signal are not being applied and further comprising an analysis module configured for analyzing the response signal as a current when the delta signal is applied to determine an impedance of the first set of cells.

12. The impedance measurement circuit of claim 10, wherein:

the plurality of electrochemical cells comprises electrochemical cells operably coupled in series;

the first set of cells comprises a first cell of the plurality of electrochemical cells; and

the second set of cells comprises a second cell of the plurality of electrochemical cells that is different from the first cell.

13. The impedance measurement circuit of claim 10, wherein the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the first set of cells.

14. The impedance measurement circuit of claim 10, wherein the cancelation unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the second set of cells.

15. The impedance measurement circuit of claim 10, wherein:

the plurality of electrochemical cells comprises electrochemical cells operably coupled in series;

the second set of cells comprises all of the plurality of electrochemical cells; and

the first set of cells comprises fewer than all of the plurality of electrochemical cells.

16. The impedance measurement circuit of claim 15, wherein the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the first set of cells.

17. An impedance measurement circuit, comprising:

a signal creator configured to generate a delta signal;

an application unit configured to apply the delta signal across at least one electrochemical cell of a plurality of electrochemical cells operably coupled together;

an inverter unit configured to generate an opposite delta signal such that a sum of the delta signal and the opposite delta signal are substantially zero at any instant of time;

a plurality of cancelation circuits, each cancelation circuit configured to apply a portion of the opposite delta signal across a corresponding electrochemical cell of the plurality of electrochemical cells; and

a measurement unit configured to measure a response signal across the at least one electrochemical cell when the delta signal and the opposite delta signal are being applied.

18. The impedance measurement circuit of claim 17, wherein the measurement unit is further configured to measure a held voltage across the at least one electrochemical cell when the delta signal and the opposite delta signal are not being applied and further comprising an analysis module configured for analyzing the response signal as a current relative to the held voltage to determine an impedance of the at least one electrochemical cell.

19. The impedance measurement circuit of claim 17, wherein:

the signal creator, the application unit, and the measurement unit are operably coupled to form an active measurement unit and the active measurement unit is configured to be selectively coupled to each of the plurality of electrochemical cells as the at least one electrochemical cell; and

each cancelation circuit of the plurality of cancelation circuits is configured to apply a portion of the delta signal across a corresponding electrochemical cell, wherein the corresponding electrochemical cells comprise all the electrochemical cells in the plurality except the at least one electrochemical cell.

20. The impedance measurement circuit of claim 19, wherein the portion of the delta signal is substantially equal for each cancelation circuit of the plurality of cancelation circuits.

21. The impedance measurement circuit of claim 19, wherein the portion of the delta signal is different for each cancelation circuit of the plurality of cancelation circuits.

22. A method of measuring impedance, comprising:

generating a delta signal;

generating an opposite delta signal such that a sum of the delta signal and the opposite delta signal are substantially zero at any instant of time during an application period for the delta signal and the opposite delta signal;

applying the delta signal across a first set of cells comprising one or more electrochemical cells of a plurality of electrochemical cells operably coupled together;

applying the opposite delta signal across a second set of cells comprising one or more electrochemical cells of the plurality of electrochemical cells, wherein the second set of cells is different from the first set of cells; and

measuring a current response signal into the second set of cells when the delta signal and the opposite delta signal are being applied.

23. The method of claim 22, wherein the plurality of electrochemical cells comprises electrochemical cells operably coupled in series and wherein:

applying the delta signal across the first set of cells comprises applying the delta signal across a first cell of the plurality of electrochemical cells; and

applying the opposite delta signal across the second set of cells comprises applying the opposite delta signal across a second cell of the plurality of electrochemical cells that is different from the first cell.

24. The method of claim 23, wherein generating the delta signal, applying the delta signal, and measuring the response signal are performed by an active measurement unit and further comprising sequentially and selectively coupling the active measurement unit to each of the plurality of electrochemical cells as the first cell.

25. The method of claim 23, wherein applying the opposite delta signal comprises sequentially and selectively applying the opposite delta signal to each of the plurality of electrochemical cells as the second cell.

26. The method of claim 22, wherein the plurality of electrochemical cells comprises electrochemical cells operably coupled in series and wherein:

applying the opposite delta signal across the second set of cells comprises applying the opposite delta signal across all of the plurality of electrochemical cells; and

applying the delta signal across the first set of cells comprises applying the delta signal across fewer than all of the plurality of electrochemical cells.

27. The method of claim 26, wherein applying the delta signal across the first set of cells comprises applying the delta signal across a single electrochemical cell of the plurality of electrochemical cells.

28. The method of claim 27, wherein generating the delta signal, applying the delta signal, and measuring the response signal are performed by an active measurement unit and further comprising sequentially and selectively coupling the active measurement unit to each of the plurality of electrochemical cells as the first set of cells.

29. The method of claim 22, wherein applying the delta signal and applying the opposite delta signal comprise applying DC signals.

30. The method of claim 22, wherein applying the delta signal and applying the opposite delta signal comprise applying time-varying signals.