ELECTRON BEAM-CURABLE INKJET INKS AND USE THEREOF IN INKJET PRINTING METHODS

• US 20150225585A1
• Filed: 08/21/2013
• Published: 08/13/2015
• Est. Priority Date: 08/24/2012
• Status: Active Grant

• Current Assignee: Mankiewicz Gebr. & Co. GmbH & Co. KG
• Original Assignee: Mankiewicz Gebr. & Co. GmbH & Co. KG
• Inventors: De Rossi, Umberto, Bolender, Oliver
• Granted Patent: US 9,458,339 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: B41M 7/0081 using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
• CPC Class Codes: C09D 11/101 Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
• CPC Class Codes: C09D 11/107 from unsaturated acids or derivatives thereof
• CPC Class Codes: C09D 11/322 Pigment inks
• CPC Class Codes: C09D 11/36 based on non-aqueous solvents

Abstract

An inkjet ink which is electron beam curable includes 10 to 40 wt.-% of at least one oligomer based on a total weight of the inkjet ink, 5 to 25 wt.-% of at least one reactive thinner based on the total weight of the inkjet ink, 25 to 84 wt.-% of a solvent mixture comprising at least two solvents based on the total weight of the inkjet ink, and 1 to 15 wt.-% of at least one pigment based on the total weight of the inkjet ink. The at least two solvents have a boiling point of from 50 to 300° C., a dielectricity constant of from 5 to 20, and an evaporation rate of 3 to 5000. The evaporation rate of the at least two solvents differs by a factor of from 2 to 10. The inkjet ink is free from photoinitiators.

Claims

1-15. -15. (canceled)

16. An inkjet ink which is electron beam curable, the inkjet ink comprising:

10 to 40 wt.-% of at least one oligomer based on a total weight of the inkjet ink;

5 to 25 wt.-% of at least one reactive thinner based on the total weight of the inkjet ink;

25 to 84 wt.-% of a solvent mixture comprising at least two solvents based on the total weight of the inkjet ink, the at least two solvents having a boiling point of from 50 to 300°

C., a dielectricity constant of from 5 to 20, and an evaporation rate of 3 to 5000, wherein the evaporation rate of the at least two solvents differs by a factor of from 2 to 10; and

1 to 15 wt.-% of at least one pigment based on the total weight of the inkjet ink;

wherein, the inkjet ink is free from photoinitiators.

17. The inkjet ink as recited in claim 16, wherein the inkjet ink comprises the at least two solvents in a proportion of from 0.25:

1 to 1;

2.5.

18. The inkjet ink as recited in claim 16, wherein the at least one oligomer is selected from aliphatic urethane acrylates, aromatic urethane acrylates, polyether acrylates, and epoxy acrylates, wherein the aliphatic urethane acrylates, the aromatic urethane acrylates, the polyether acrylates, and the epoxy acrylates acrylates are monofunctional or polyfunctional.

19. The inkjet ink as recited in claim 16, wherein the at least one reactive thinner is selected from dipropylene glycol diacrylate, tripropylene glycol diacrylate, tetra hydrofurfuryl acrylate, isobornyl acrylate, isodecyl acrylate, ethylene ethyl acrylate, hexandiol diacrylate, tricyclodecane dimethanol diacrylate, propoxylated neopentyl glycol diacrylate, and proxylated trimethylol propane triacrylate.

20. The inkjet ink as recited in claim 16, wherein the at least two solvents are selected from methyl isobutyl ketone, cyclohexanone, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-n-butyl ether, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol mono-n-butyl ether, dipropylene glycol monomethyl ether, dipropylene glycol dimethyl ether, dipropylene glycol mono-n-butylether, diethylene glycol monomethyl ether, diethylene glycol mono-n-butyl ether, tripropylene glycol monomethyl ether, butoxy ethyl acetate, methoxy propyl acetate, ethyl glycol acetate, butyl diglycol acetate, ethyl diglycol acetate, dipropylene glycol methyl ether acetate, ethyl acetate, n-propyl acetate, iso-propyl acetate, n-butyl acetate, methyl lactate, ethyl lactate, and ethylene glycol diacetate.

21. The inkjet ink as recited in claim 16, wherein the at least one pigment has a particle size in the range of from 10 to 1000 nm

22. The inkjet ink as recited in claim 21, wherein the at least one pigment has a particle size range of from 50 to 600 nm.

23. A method of using the inkjet ink as recited in claim 16 to print a food package and a toy, the method comprising:

providing the inkjet ink as recited in claim 16; and

using the inkjet ink to print at least one of the food package and the toy.

24. A method for producing a color coat on a substrate surface, the method comprising:

providing at least one inkjet ink which is free of photoinitiators, the at least one inkjet ink comprising,

10 to 40 wt.-% of at least one oligomer based on a total weight of the inkjet ink,

5 to 25 wt.-% of at least one reactive thinner based on the total weight of the inkjet ink,

25 to 84 wt.-% of a solvent mixture comprising at least two solvents based on the total weight of the inkjet ink, the at least two solvents having a boiling point of from 50 to 300°

C., a dielectricity constant of from 5 to 20, and an evaporation rate of 3 to 5000, wherein the evaporation rate of the at least two solvents differs by a factor of from 2 to 10, and

1 to 15 wt.-% of at least one pigment based on the total weight of the inkjet ink,

applying the at least one inkjet ink on the substrate surface with an inkjet technology; and

hardening the at least one inkjet ink by exposing the at least one inkjet ink applied to a dose of an electron radiation in the range of 10 to 200 kGy.

25. The method as recited in claim 24, wherein the at least one inkjet ink comprises the at least two solvents in a proportion of from 0.25:

1 to 1;

2.5.

26. The method as recited in claim 24, wherein the applying of the at least one inkjet ink is performed in a single-pass method or in a multi-pass method.

27. The method as recited in claim 24, wherein the substrate surface comprises a three-dimensionally structured surface.

28. The method as recited in claim 24, wherein the substrate surface comprises at least one of a porous surface, an open-cell surface, and an absorbent material.

29. The method as recited in claim 24, wherein a time span between the applying of the at least one inkjet ink and the hardening of the at least one inkjet ink ranges from 0.001 to 10 seconds.

30. The method as recited in claim 24, the method further comprising:

providing an ink comprising a white ink; and

applying a first coat comprising the ink comprising the white ink before the applying of the at least one inkjet ink.

31. The method as recited in claim 30, wherein a time span between the applying of the first coat comprising the ink comprising the white ink and the applying of the at least one inkjet ink ranges from 0.001 to 10 seconds.