LIQUID ACTIVATED DEVICES POWERED BY HYDROGEL BATTERIES AND METHODS THEREFORE

• US 20150303489A1
• Filed: 11/07/2012
• Published: 10/22/2015
• Est. Priority Date: 11/07/2012
• Status: Active Application

• Current Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Original Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC), James Y. Wang, Qingyue Chen, Shunichiro Kuroki
• Inventors: BUNTEL, Christopher John, WANG, James Y., CHEN, Qingyue, KUROKI, Shunichiro
• Application Number:
  US14/441,468
• Publication Number:
  US 20150303489A1
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: H01M 2220/10 Batteries in stationary systems, e.g. emergency power source in plant
• CPC Class Codes: H01M 2300/0005 Acid electrolytes
• CPC Class Codes: H01M 2300/0014 Alkaline electrolytes
• CPC Class Codes: H01M 2300/0025 Organic electrolyte
• CPC Class Codes: H01M 2300/0085 Immobilising or gelification of electrolyte
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: H01M 4/381 Alkaline or alkaline earth metals elements H01M4/40 takes precedence
• CPC Class Codes: H01M 4/382 Lithium H01M4/405 takes precedence
• CPC Class Codes: H01M 4/48 of inorganic oxides or hydroxides
• CPC Class Codes: H01M 4/583 Carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: H01M 4/602 Polymers
• CPC Class Codes: H01M 6/045 characterised by aqueous electrolyte
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence
• CPC Class Codes: H01M 6/162 characterised by the electrolyte
• CPC Class Codes: H01M 6/22 Immobilising of electrolyte
• CPC Class Codes: H01M 6/32 activated through external addition of electrolyte or of electrolyte components
• CPC Class Codes: H01M 6/34 Immersion cells, e.g. sea-water cells
• CPC Class Codes: H01M 6/5044 Cells or batteries structurally combined with cell condition indicating means

Abstract

Liquid detection devices and perspiration-activated materials powered by liquid-activated hydrogel batteries are disclosed. A liquid detection device and a perspiration-activated material may be powered by a liquid-activated hydrogel battery comprising hydrogel permeated with electrolyte and an anode and a cathode in contact with the hydrogel. The hydrogel may become hydrated responsive to contact with a liquid, supporting ionic communication between the anode and the cathode via the electrolyte. The ionic communication may generate a voltage operative to power the liquid detection device or the perspiration-activated material connected thereto. The liquid detection device may operate to detect a liquid in contact therewith when powered by the hydrated liquid-activated hydrogel battery and to generate a detection event responsive to detecting the liquid. The perspiration-activated material may operate to evaporate and to eliminate odor associated with perspiration in contact therewith.

Claims

1. A liquid detection device comprising:

at least one liquid-activated hydrogel battery configured to generate an electric current responsive to contact with a liquid, the at least one liquid-activated hydrogel battery comprising;

at least one hydrogel comprising at least one hydrophilic polymer and at least one electrolyte; and

at least one anode and at least one cathode in contact with the at least one hydrogel;

wherein the at least one electrolyte supports ionic communication between the at least one anode and the at least one cathode responsive to the hydrogel being hydrated with the liquid and does not support the ionic communication responsive to the hydrogel being dehydrated by an effective absence of the liquid, the ionic communication generating an electric current for the at least one liquid-activated hydrogel battery; and

at least one circuit in operative communication with the at least one liquid-activated hydrogel battery and configured to be energized by the electric current, wherein a detection event is initiated responsive to the at least one circuit being energized.

2. The liquid detection device of claim 1, wherein the at least one circuit is in communication with at least one detection event device configured to generate the detection event.

3. The liquid detection device of claim 2, wherein the at least one detection event device comprises at least one of the following:

an actuator, an alarm device, a switch, a signal transmitter, a transponder, a receiver, a transceiver, a radio-frequency identification device, and combinations thereof.

9. The liquid detection device of claim 1, wherein the liquid comprises water selected from ground water, industrial water effluent, drinking water, rain water, brackish water, surface water, mineral water, salt water, substantially fresh water, distilled water, deionized water, and combinations thereof.

10. The liquid detection device of claim 1, wherein the at least one hydrophilic polymer is selected from polymethacrylate, polyacrylate, polymethacrylamide, polyacrylamide, polyvinyl alcohol, polyvinyl acetate, cellulose or modified cellulose, collagen or modified collagen, polysaccharide, modified polysaccharide, polynucleotide, polyhydroxyethyl methacrylate (pHEMA), and combinations thereof.

11. The liquid detection device of claim 1, wherein the at least one anode comprises an anode material selected from zinc, magnesium, aluminum, calcium, lithium, conducting polymers, iron, nickel, metal oxides, and combinations thereof.

12. The liquid detection device of claim 1, wherein the at least one cathode comprises a cathode material selected from copper, carbon, silver, metal oxides, conducting polymers, carbon nanotubes, graphite, graphene, and combinations thereof.

13. The liquid detection device of claim 1, wherein the at least one electrolyte is selected from a salt, an acid, and a base.

14. The liquid detection device of claim 13, wherein the salt is selected from ammonium sulfate, ammonium hydrogen sulfate, ammonium nitrate, ammonium phosphate, ammonium hydrogen phosphate, ammonium dihydrogen phosphate, ammonium chloride, sodium hydrogen sulfate, potassium hydrogen sulfate, sodium dihydrogen phosphate, potassium dihydrogen phosphate, sodium phosphate, potassium phosphate, sodium carbonate, potassium carbonate, and combinations thereof.

15. The liquid detection device of claim 13, wherein the acid is selected from citric acid, glutaric acid, lactic acid, boric acid, acetic acid, propionic acid, phosphoric acid, phosphorous acid, hydrochloric acid, sulfuric acid, amino acids, sulfonic acids, and combinations thereof.

16. The liquid detection device of claim 13, wherein the base is selected from sodium hydroxide, potassium hydroxide, calcium hydroxide, lithium hydroxide, and combinations thereof.

18. The liquid detection device of claim 1, wherein the liquid comprises a biological fluid selected from blood, plasma, vomit, serum, urine, sweat, saliva, and combinations thereof.

4-8. -8. (canceled)

17. (canceled)

19-28. -28. (canceled)

29. A method of preparing a liquid detection device, the method comprising:

providing at least one liquid-activated hydrogel battery configured to generate an electric current responsive to contact with a liquid, the at least one liquid-activated hydrogel battery comprising;

at least one hydrogel comprising at least one hydrophilic polymer and at least one electrolyte; and

at least one anode and at least one cathode in contact with the at least one hydrogel;

wherein the at least one electrolyte supports ionic communication between the at least one anode and the at least one cathode responsive to the hydrogel being hydrated with the liquid and does not support the ionic communication responsive to the hydrogel being dehydrated by an effective absence of the liquid, the ionic communication generating an electric current for the at least one liquid-activated hydrogel battery; and

arranging at least one circuit in operative communication with the at least one liquid-activated hydrogel battery, the at least one circuit being configured to be energized responsive to the electric current;

wherein a detection event is initiated responsive to the at least one circuit being energized.

30. The method of claim 29, further comprising arranging the at least one liquid-activated hydrogel battery in a case configured to facilitate entry and exit of the liquid from the case.

31. The method of claim 30, wherein exit of the liquid from the case comprises evaporation of the liquid.

32. The method of claim 29, further comprising configuring the at least one circuit to be in communication with at least one detection event device configured to generate the detection event.

33. The method of claim 32, wherein the at least one detection event device comprises at least one of the following:

an actuator, an alarm, a transceiver, a light emitting device, a processor, a transponder, a radio-frequency identification device, a computing device, and combinations thereof.

34-39. -39. (canceled)

40. A method of detecting liquid using at least one liquid detection device, the method comprising:

providing the at least one liquid detection device comprising;

at least one liquid-activated hydrogel battery configured to generate an electric current responsive to contact with a liquid, the at least one liquid-activated hydrogel battery comprising;

at least one hydrogel comprising at least one hydrophilic polymer and at least one electrolyte; and

at least one anode and at least one cathode in contact with the at least one hydrogel;

wherein the at least one electrolyte supports ionic communication between the at least one anode and the at least one cathode responsive to the hydrogel being hydrated with the liquid and does not support the ionic communication responsive to the hydrogel being dehydrated by an effective absence of the liquid, the ionic communication generating an electric current for the at least one liquid-activated hydrogel battery; and

at least one circuit in operable communication with the at least one liquid-activated hydrogel battery and configured to be energized by the electric current, wherein a detection event is initiated responsive to the at least one circuit being energized; and

exposing the at least one liquid detection device to liquid such that the liquid hydrates the at least one hydrogel of the at least one liquid-activated hydrogel battery.

41. The method of claim 40, wherein the at least one circuit is in communication with at least one detection event device configured to generate the detection event.

42. The method of claim 40, further comprising positioning the at least one liquid detection device in an environment sensitive to the liquid, the environment comprising at least one of the following:

an electronic device, dry goods, a wooden structure, moisture sensitive equipment, and combinations thereof.

43. The method of claim 42, wherein the electronic device comprises at least one of the following:

a computing device, a computer, a tablet computing device, a telephone, a cell phone, an air conditioner, electronic laboratory equipment, and combinations thereof.

44. The method of claim 40, wherein the at least one liquid detection device is operative to detect thawing of a liquid in a frozen state.

49. The method of claim 40, wherein the at least one liquid detection device is operative to detect a plumbing leak.

52. The method of claim 40, wherein the at least one liquid detection device is operative to detect a roof leak.

45-48. -48. (canceled)

50-51. -51. (canceled)

53-97. -97. (canceled)