HYDROPHOBIC AND OLEOPHOBIC SURFACES AND USES THEREOF

• US 20150322272A1
• Filed: 12/12/2013
• Published: 11/12/2015
• Est. Priority Date: 12/13/2012
• Status: Abandoned Application

• Current Assignee: Agricultural Research Organization, Volcani Center (Government of Israel), TECHNION RESEARCH AND DEVELOPMENT FOUNDATION, LTD. (Technion-Israel Institute Of Technology)
• Original Assignee: TECHNION RESEARCH AND DEVELOPMENT FOUNDATION, LTD. (Technion-Israel Institute Of Technology)
• Inventors: POKROY, Boaz, PECHOOK, Sasha
• Application Number:
  US14/652,119
• Publication Number:
  US 20150322272A1
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: A01N 29/02 Acyclic compounds or compounds containing halogen attached to an aliphatic side-chain of a cycloaliphatic ring system
• CPC Class Codes: B05D 1/02 performed by spraying
• CPC Class Codes: B05D 1/18 performed by dipping
• CPC Class Codes: B05D 1/60 Deposition of organic layers from vapour phase vapour phase deposition in general C23C14/00, C23C16/00
• CPC Class Codes: C09D 191/06 Waxes
• CPC Class Codes: C09D 5/14 Paints containing biocides, e.g. fungicides, insecticides or pesticides C09D5/16 takes precedence
• CPC Class Codes: C09D 5/1681 Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]

Abstract

A methodology is provided for generating hydrophobic superhydrophobic, oleophobic and/or superoleophobic surfaces. Compositions of matter made of a substrate having deposited on a surface thereof (e.g., by thermal evaporation) hydrocarbon waxes, including fluorinated waxes, are disclosed. Process of preparing such compositions of matter and articles of manufacturing incorporating such compositions are also disclosed. Further disclosed are articles of manufacturing and methods which are useful in inhibiting, reducing and/or retarding biofilm formation, and which include applying waxes (e.g., by thermal evaporation) on a surface of the articles.

Claims

1. A composition of matter comprising a substrate having applied on a surface thereof a fluorinated wax having at least 21 carbon atoms in its backbone chain, at least 10 percents of said carbon atoms being independently substituted by one or more fluoride substituents.

2. The composition of matter of claim 1, wherein said fluorinated wax is perfluorotetracosane (CF₃(CF₂)₂₂CF₃).

3. The composition of matter of claim 1, characterized by at least one of:

a static liquid contact angle for a hydrophobic liquid of at least 50°

; and

an RMS roughness which is at least 5-folds the RMS roughness of said surface prior to applying thereon said fluorinated wax.

4. The composition of matter of claim 1, wherein said fluorinated wax is a thermally-evaporated fluorinated wax.

8. The composition of matter of claim 1, being characterized by an XRPD which exhibits a preferred orientation.

9. The composition of matter of claim 1, being characterized by a time-dependent and/or temperature-dependent RMS roughness.

10. The composition of matter of claim 1, being characterized by a RMS roughness of at least 100 nm.

11. The composition of matter of claim 10, being characterized by a RMS roughness of at least 100 microns.

13. The composition of matter of claim 1, characterized by a static liquid contact angle of at least 100°

.

14. The composition of matter of claim 13, wherein said liquid is water and said static contact angle is at least 150°

.

15. The composition of matter of claim 13, wherein said liquid is ethylene glycol and said static contact angle is at least 150°

.

16. The composition of matter of claim 13, wherein said liquid is a hydrophobic liquid.

17. A process of preparing the composition of matter of claim 1, the process comprising thermally evaporating said fluorinated wax onto said surface of said substrate, thereby obtaining the composition of matter.

18. The process of claim 17, wherein said evaporating is effected under reduced pressure.

19. The process of claim 18, wherein said evaporating is effected at a temperature that ranges from 100°

C. to 300°

C.

20. The process of claim 17, further comprising, subsequent to said evaporating, maintaining the composition of matter at a temperature that ranges from −

30°

C. to 90°

C.

21. The process of claim 20, wherein said maintaining at said temperature is for a time period that ranges from 10 hours to several months.

22. An article of manufacturing comprising the composition of matter of claim 1.

31. A process of preparing the composition of matter of claim 1, the process comprising applying said fluorinated wax onto said surface of said substrate, thereby obtaining the composition of matter, wherein said applying is performed by spraying a mixture of said fluorinated wax and a fluorinated organic solvent onto said surface or by dipping said surface in a mixture of said fluorinated wax and a fluorinated organic solvent.

5-7. -7. (canceled)

12. (canceled)

23-30. -30. (canceled)

32-35. -35. (canceled)

36. An article of manufacturing comprising a substrate having applied on a surface thereof a hydrocarbon wax, the article of manufacturing being identified as capable of inhibiting, reducing or retarding a formation of a biofilm on said surface.

46. The article of manufacturing of claim 36, wherein said wax is a fluorinated wax.

47. The article of manufacturing of claim 46, wherein said fluorinated wax comprises a carbon backbone chain having at least 21 carbon atoms.

48. The article of manufacturing of claim 47, wherein at least 10 percents of said carbon atoms are independently substituted by one or more fluoride substituents.

49. The article of manufacturing of claim 46, wherein said fluorinated wax is perfluorotetracosane (CF₃(CF₂)₂₂CF₃).

50. The article of manufacturing of claim 36, wherein said wax comprises a hydrocarbon having at least 40 carbon atoms in its backbone chain.

51. The article of manufacturing of claim 36, wherein said biofilm is a bacterial biofilm.

37-39. -39. (canceled)

40. A method of inhibiting, reducing and/or retarding a biofilm formation on a surface of a substrate, the method comprising applying onto the surface a hydrocarbon wax.

41. The method of claim 40, wherein said applying is effected by thermally evaporating said hydrocarbon wax onto said surface.

42. The method of claim 40, wherein said applying is effected by spraying a mixture of said hydrocarbon wax and an organic solvent onto said surface.

43. The method of claim 40, wherein said applying is effected by dipping said portion of said surface in a mixture of said hydrocarbon wax and an organic solvent.

45. The method of claim 40, wherein said substrate forms a part of an article of manufacture.

63. The method of claim 40, wherein said substrate forms a part of an article of manufacture.

64. The method of claim 40, wherein said wax is a fluorinated wax.

65. The method of claim 64, wherein said fluorinated wax comprises a carbon backbone chain having at least 21 carbon atoms.

66. The method of claim 65, wherein at least 10 percents of said carbon atoms are independently substituted by one or more fluoride substituents.

67. The method of claim 64, wherein said fluorinated wax is perfluorotetracosane (CF₃(CF₂)₂₂CF₃).

68. The method of claim 40, wherein said wax comprises a hydrocarbon having at least 40 carbon atoms in its backbone chain.

69. The method of claim 40, wherein said biofilm is a bacterial biofilm.

44. (canceled)

52-62. -62. (canceled)

70. A method of inhibiting, reducing and/or retarding a biofilm formation on a surface of a substrate, the method comprising applying onto the surface a fluorinated wax having at least 21 carbon atoms in its backbone chain, at least 10 percents of said carbon atoms being independently substituted by one or more fluoride substituents.

71. The method of claim 70, wherein said applying is effected by thermally evaporating said hydrocarbon wax onto said surface.

72. The method of claim 70, wherein said applying is effected by spraying a mixture of said hydrocarbon wax and an organic solvent onto said surface.

73. The method of claim 70, wherein said applying is effected by dipping said portion of said surface in a mixture of said hydrocarbon wax and an organic solvent.

74. The method of claim 70, wherein said substrate forms a part of an article of manufacture.