GAS ABSORPTION SPECTROSCOPIC SYSTEM AND GAS ABSORPTION SPECTROSCOPIC METHOD

• US 20150338342A1
• Filed: 12/25/2013
• Published: 11/26/2015
• Est. Priority Date: 01/07/2013
• Status: Active Grant

• Current Assignee: Naamloze Vennootschap Reynaers Aluminim, Shimadzu Corporation
• Original Assignee: Shimadzu Corporation
• Inventors: MATSUDA, Naoki, MURAMATSU, Takashi, MORIYA, Naoji
• Granted Patent: US 9,772,277 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: G01J 3/027 Control of working procedures of a spectrometer; Failure detection; Bandwidth calculation
• CPC Class Codes: G01J 3/10 Arrangements of light sources specially adapted for spectrometry or colorimetry
• CPC Class Codes: G01J 3/42 Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry beam switching arrangements G01J3/08
• CPC Class Codes: G01J 3/4338 Frequency modulated spectrometry
• CPC Class Codes: G01N 21/3103 Atomic absorption analysis
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 21/39 using tunable lasers
• CPC Class Codes: G01N 2201/0612 Laser diodes

Abstract

Provided is a gas absorption spectroscopic system and gas absorption spectroscopic method capable of accurately measuring the concentration or other properties of gas even in high-speed measurements. Laser light with a varying wavelength is cast into target gas. A spectrum profile representing a change in the intensity of the laser light transmitted through the target gas with respect to wavelength is determined. For this spectrum profile, polynomial approximation is performed at each wavelength point within a predetermined wavelength width, using an approximate polynomial. Based on the coefficients of the terms in the approximate polynomial at each point, an nth order derivative curve, where n is an integer of zero or larger, of the spectrum profile is created. A physical quantity of the target gas is determined based on the thus created nth order derivative curve.

Claims

1. A gas absorption spectroscopic system, comprising:

a) a wavelength-variable light source;

b) a light source controller for varying a wavelength of light generated by the light source;

c) a photodetector for detecting an intensity of light generated by the light source and transmitted through target gas;

d) a polynomial approximator for creating a curve approximating a change in the intensity of the light detected by the photodetector with a change in the wavelength varied by the light source controller, using an approximate polynomial at each wavelength point and within a predetermined wavelength width;

e) a derivative curve creator for creating an nth order derivative curve, where n is an integer of zero or larger, based on a coefficient of each term of the approximate polynomial at each of the wavelength points; and

f) a physical quantity determiner for determining at least one among the temperature, concentration and pressure of the target gas, based on the nth order derivative curve.

2. The gas absorption spectroscopic system according to claim 1, wherein the approximate polynomial used in the polynomial approximator is a second order polynomial.

3. The gas absorption spectroscopic system according to claim 1, wherein a zeroth order derivative curve is used in the polynomial approximator and the derivative curve creator, and the concentration of the target gas is determined from a peak area of the zeroth order derivative curve in the physical quantity determiner.

4. The gas absorption spectroscopic system according to claim 1, wherein a second order derivative curve is used in the polynomial approximator and the derivative curve creator, and the concentration of the target gas is determined from a peak height of the second order derivative curve in the physical quantity determiner.

6. The gas absorption spectroscopic system according to claim 2, wherein a zeroth order derivative curve is used in the polynomial approximator and the derivative curve creator, and the concentration of the target gas is determined from a peak area of the zeroth order derivative curve in the physical quantity determiner.

7. The gas absorption spectroscopic system according to claim 2, wherein a second order derivative curve is used in the polynomial approximator and the derivative curve creator, and the concentration of the target gas is determined from a peak height of the second order derivative curve in the physical quantity determiner.

8. The gas absorption spectroscopic system according to claim 1, wherein a normalization for correcting a fluctuation in an amount of light is performed in the derivative curve creator by dividing the coefficient of the second order term of the approximate polynomial at each of the wavelength points by the coefficient of the first order term or the coefficient of the zeroth order term.

9. The gas absorption spectroscopic system according to claim 2, wherein a normalization for correcting a fluctuation in an amount of light is performed in the derivative curve creator by dividing the coefficient of the second order term of the approximate polynomial at each of the wavelength points by the coefficient of the first order term or the coefficient of the zeroth order term.

10. The gas absorption spectroscopic system according to claim 4, wherein a normalization for correcting a fluctuation in an amount of light is performed in the derivative curve creator by dividing the coefficient of the second order term of the approximate polynomial at each of the wavelength points by the coefficient of the first order term or the coefficient of the zeroth order term.

11. The gas absorption spectroscopic system according to claim 7, wherein a normalization for correcting a fluctuation in an amount of light is performed in the derivative curve creator by dividing the coefficient of the second order term of the approximate polynomial at each of the wavelength points by the coefficient of the first order term or the coefficient of the zeroth order term.

5. A gas absorption spectroscopic method, comprising steps of:

a) casting light with a varying wavelength into target gas;

b) performing a polynomial approximation of creating a curve approximating a change in an intensity of the light transmitted through the target gas with respect to the wavelength, using an approximate polynomial at each wavelength point and within a predetermined wavelength width;

c) creating an nth order derivative curve, where n is an integer of zero or larger, based on a coefficient of each term of the approximate polynomial at each of the wavelength points; and

d) determining a physical quantity of the target gas based on the nth order derivative curve.

12. The gas absorption spectroscopic method according to claim 5, further comprising a step of performing a normalization process for correcting a fluctuation in an amount of light by dividing the coefficient of the second order term of the approximate polynomial at each of the wavelength points by the coefficient of the first order term or the coefficient of the zeroth order term.