Hydrothermal Conversion Process
First Claim
1. A hydrothermal conversion process wherein a particulate solid organic feedstock is reacted with water at a temperature of at least 160°
- at a superatmospheric pressure sufficient to maintain the water in subcooled liquid state to produce one or more hydrothermal conversion products selected from a) a carbonized solid and b) at least one liquefaction product, wherein1) an aqueous slurry of particles of the organic feedstock in liquid water and having a temperature of up to 100°
C. is mixed under elevated pressure with a steam stream, under conditions such that upon mixing all or a portion of the steam condenses and a reaction mixture having a temperature of at least 160°
C. is formed at a pressure such that water including the condensed steam remains as a subcooled liquid;
2) the reaction mixture is maintained at a temperature of at least 160°
C. and at a temperature sufficient to maintain water including the condensed steam as a subcooled liquid for a period of time sufficient to produce the one or more hydrothermal conversion products; and
then3) recovering the one or more hydrothermal conversion products.
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Abstract
A hydrothermal conversion process includes a mixing step wherein an aqueous slurry of a solid feedstock material with a steam stream to produce a reaction mixture having a temperature of at least 160° C. and which is at a pressure sufficient to keep water as a subcooled liquid. The process is fast and effective, requires only simple equipment and is highly energy-efficient. The process is also readily scalable, can be operated continuously or semi-continuously and can be tailored to produce carbonized solids or liquefaction products, all of which typically have increased economic value compared with the starting materials.
7 Citations
20 Claims
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1. A hydrothermal conversion process wherein a particulate solid organic feedstock is reacted with water at a temperature of at least 160°
- at a superatmospheric pressure sufficient to maintain the water in subcooled liquid state to produce one or more hydrothermal conversion products selected from a) a carbonized solid and b) at least one liquefaction product, wherein
1) an aqueous slurry of particles of the organic feedstock in liquid water and having a temperature of up to 100°
C. is mixed under elevated pressure with a steam stream, under conditions such that upon mixing all or a portion of the steam condenses and a reaction mixture having a temperature of at least 160°
C. is formed at a pressure such that water including the condensed steam remains as a subcooled liquid;2) the reaction mixture is maintained at a temperature of at least 160°
C. and at a temperature sufficient to maintain water including the condensed steam as a subcooled liquid for a period of time sufficient to produce the one or more hydrothermal conversion products; and
then3) recovering the one or more hydrothermal conversion products. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19)
- at a superatmospheric pressure sufficient to maintain the water in subcooled liquid state to produce one or more hydrothermal conversion products selected from a) a carbonized solid and b) at least one liquefaction product, wherein
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20. A hydrothermal conversion process wherein a particulate solid organic feedstock is reacted with water at a temperature of at least 160°
- at a superatmospheric pressure sufficient to maintain the water as a subcooled liquid to produce one or more hydrothermal conversion products selected from a) a carbonized solid and b) at least one liquefaction product, wherein
1) an aqueous slurry of particles of the organic feedstock in liquid water is preheated in a heat exchanger to a temperature of up to 140°
under sufficient pressure to keep the water in the liquid aggregate state;2) the preheated aqueous slurry is introduced into a reactor in which the slurry is heated to a temperature of at least 160°
C. under sufficient pressure to keep the water as a subcooled liquid and then maintained under such conditions of temperature and pressure for a period of time sufficient to produce a reaction product mixture containing water and the one or more hydrothermal conversion products;3) withdrawing the reaction product mixture from the reactor; 4) passing at least a portion of the reaction product mixture through the heat exchanger to provide energy for heating the aqueous slurry in step
1), whereby such portion of the reaction product mixture is cooled;5) prior to or after step
4), depressurizing the reaction product mixture such that at least a portion of the liquid water becomes converted to a gas and the reaction mixture separates into a gas phase and a liquid phase that may include at least one dispersed solid hydrothermal conversion product;6) recovering one or more hydrothermal conversion products from the liquid phase.
- at a superatmospheric pressure sufficient to maintain the water as a subcooled liquid to produce one or more hydrothermal conversion products selected from a) a carbonized solid and b) at least one liquefaction product, wherein
Specification