PROCESSES FOR HOLDING CHAR IN A CATALYIC FAST PYROLYSIS PROCESS AND CHAR COMPOSITIONS

• US 20160137924A1
• Filed: 11/17/2015
• Published: 05/19/2016
• Est. Priority Date: 11/17/2014
• Status: Abandoned Application

• Current Assignee: Anellotech, Inc.
• Original Assignee: Anellotech, Inc.
• Inventors: Igoe, William F. Jr., Rappas, Alkis, Goud, Sandeep K., Mazanec, Terry J., Tanzio, Michael, Sorensen, Charles M. Jr., Song, Ruozhi, Shi, Jian, Cheng, Yu-Ting
• Application Number:
  US14/944,102
• Publication Number:
  US 20160137924A1
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: B01J 29/40 of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
• CPC Class Codes: C05D 9/00 Other inorganic fertilisers
• CPC Class Codes: C05F 11/00 Other organic fertilisers
• CPC Class Codes: C10B 49/22 according to the "fluidised bed" technique
• CPC Class Codes: C10B 53/02 of cellulose-containing material production of pyroligneous acid C10C5/00
• CPC Class Codes: C10B 57/06 containing additives
• CPC Class Codes: C10G 1/002 in combination with oil conversion- or refining processes
• CPC Class Codes: C10G 1/08 with moving catalysts
• CPC Class Codes: C10G 1/086 Characterised by the catalyst used
• CPC Class Codes: C10G 2300/1011 Biomass
• CPC Class Codes: C10G 2400/20 C2-C4 olefins
• CPC Class Codes: C10G 2400/22 Higher olefins
• CPC Class Codes: C10G 2400/30 Aromatics
• CPC Class Codes: C10G 31/10 with the aid of centrifugal force
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 20/145 the feedstock being materials of biological origin
• CPC Class Codes: Y02P 30/20 using bio-feedstock

Abstract

Methods of separating and utilizing char produced by the catalytic fast pyrolysis of biomass are described. In a preferred method, a portion of the char from a catalytic pyrolysis reactor is recovered and treated and combusted to provide heat to the catalytic pyrolysis reactor. A novel char and methods of amending soil with a char composition are also described.

Claims

1. A method for producing aromatic chemicals or olefins, comprising:

reacting solid biomass in the presence of a catalyst in a reaction zone;

producing a product stream or product streams that exits from the reaction zone;

withdrawing a solid mixture from the reaction zone;

wherein the solid mixture that is removed is separate from the product stream or streams;

separating at least a portion of char from the solid mixture prior to a catalyst regeneration step; and

recovering aromatics or olefins from the product stream.

2. The method of claim 1 wherein at least a portion of the separated char is added to the reaction zone and the separated char added to the reaction zone is not contacted with biomass prior to the reaction zone.

3. The method of claim 1 wherein aromatics are recovered from the product stream and the recovered aromatics comprise benzene, toluene, and xylenes in an amount of at least 10%, preferably at least 15% yield based on carbon in the biomass where the yield is the sum of the carbon in the benzene, toluene, and xylenes divided by the carbon in the biomass feed.

4. The method of any of the previous claims wherein the separation of the solid mixture is conducted in a cyclone or series of cyclones or by solids flotation or elutriation, preferably comprising a bubbling bed of gas and solid particles, or by a screen, a set of screens with various hole openings, or another size exclusion device where separation of solids occurs based on particle size differences or by elutriation to provide char-enriched and char-depleted streams.

9. The method of claim 1 wherein at least a portion of the char is comminuted before it is separated from the other solids.

12. The method of claim 1 wherein a portion of the char separated from the catalyst is subjected to combustion with an excess of oxygen greater than or equal to the minimum required for complete conversion of the char into carbon dioxide and water.

13. The method of claim 12 wherein heat is recovered from the combustion of the char and transferred to the catalytic biomass conversion reactor, or heat is utilized to generate steam, or heat is utilized to generate electricity, or some combination of these.

16. The method of claim 1 wherein the catalyst comprises a zeolite, and wherein the catalyst regeneration is operated at a temperature of less than 750 C, or less than 700 C, or less than 650 C, or less than 625 C, or from 550 C to 750 C, or from 575 C to 700 C, or from 600 C to 650 C.

22. The method of claim 2 wherein at least a portion of the char is chemically reacted and a portion of the reacted char is returned to the catalytic biomass reactor.

24. The method of claim 2 wherein the char is partially oxidized by reaction with ozone, oxygen, diluted air, hydrogen peroxide, peracetic acid (CH₃C(O)OOH), performic acid (HC(O)OOH), isobutyl peroxide, NO₂, NO, or other gaseous or liquid oxidizing agents.

28. The method of claim 1 wherein the char is treated with an acidic solution;

preferably the acidic solution comprises acetic, formic, nitric, sulfuric, propionic, or carbonic acid, or a portion of the water produced in the CFP process, or combinations of these.

30. A char-based composition (char) produced by the method of claim 4.

37. The char-based composition of claim 30 wherein the sum of alkali and alkaline earth elements comprises at least 0.1%, or at least 0.2%, or at least 0.5%, or at least 1.0%, or at least 2.0% by weight of the char.

49. The method of claim 12 wherein the combustion of char is conducted in a circulating fluid bed reactor, riser reactor, gasifier, counter-current gasifier, co-current gasifier, cross-draught gasifier, fluid bed gasifier, double fired gasifier, entrained bed gasifier, molten bath gasifier, heat exchange reactor, circulating loop reactor, staged combustion reactor, or any other combustion reactor.

50. The method of claim 1 wherein the heat release in the catalyst regenerator is at least 20%, or at least 33%, or at least 50%, or at least 60%, or at least 66%, or at least 75% less when the char has been removed compared to the heat release when the char and coked catalyst are combusted together in the regenerator without separation.

5-8. -8. (canceled)

10-11. -11. (canceled)

14-15. -15. (canceled)

17-21. -21. (canceled)

23. (canceled)

25-27. -27. (canceled)

29. (canceled)

31. A char-based composition (char) comprising at least 1 wt % zeolite or zeolite-containing catalyst and 10 to 99 wt % carbon.

42. The char-based composition of claim 31 wherein the char comprises less than 0.1 wt %, or less than 0.01%, or less than 0.001 wt %, of each of V, Ni, and As.

45. The char-based composition of claim 31, as measured by mercury intrusion porosimetry,

has a bulk density less than 1.0 g/ml, or less than 0.75 g/ml, or less than 0.5 g/ml, or less than 0.35 g/ml, or less than 0.3 g/ml, or less than 0.2 g/ml, or from 0.05 to 1.0 g/ml, or from 0.1 to 0.75 g/ml, or from 0.18 to 0.5 g/ml,

or a particle density less than 1.5, or less than 1.1, or less than 1.0, or less than 0.9, or less than 0.8, or less than 0.7, or less than 0.6, or less than 0.5, or less than 0.4 g/ml, or from 0.1 to 1.1 g/ml, or from 0.2 to 1.0 g/ml, or from 0.3 to 0.9 g/ml, or from 0.5 to 0.7 g/ml,

or a skeletal density less than 2.0 g/ml, or less than 1.9 g/ml, or less than 1.85 g/ml, or less than 1.7 g/ml, or less than 1.55 g/ml, or less than 1.4 g/ml, or from 1.0 to 2.0 g/ml, or from 1.3 to 1.9 g/ml, or from 1.4 to 1.85 g/ml.

32-36. -36. (canceled)

38-41. -41. (canceled)

43-44. -44. (canceled)

46. A method of amending soil comprising:

providing char comprising at least 1% by weight zeolite; and

mixing the char into soil.

47-48. -48. (canceled)

51. (canceled)