PHOTON EMITTER CHARACTERIZATION USING PHOTOLUMINESCENCE QUENCHING IN NITROGEN VACANCY COLOR CENTERS

• US 20160139048A1
• Filed: 11/14/2014
• Published: 05/19/2016
• Est. Priority Date: 11/14/2014
• Status: Active Grant

• Current Assignee: Infinitum Solutions, Inc.
• Original Assignee: Infinitum Solutions, Inc.
• Inventors: Heidmann, Juergen
• Granted Patent: US 9,482,612 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: G01N 2021/6432 Quenching
• CPC Class Codes: G01N 21/63 optically excited
• CPC Class Codes: G01N 21/6458 Fluorescence microscopy fluorescence microscopes per se G02B21/0076 and G02B21/16
• CPC Class Codes: G01N 21/6489 Photoluminescence of semiconductors
• CPC Class Codes: G01N 2201/06113 Coherent sources; lasers

Abstract

A crystal film with nitrogen vacancy centers is placed in close proximity to a photon emitter. Excitation illumination is produced to cause the nitrogen vacancy centers to produce photoluminescence. Illumination is produced by the photon emitter, which may be near field or far field and which quenches the photoluminescence intensity using an effect known as Stimulated Emission Depletion (STED). The quenching caused by the photon emitter is detected and analyzed to determine characteristics of the photon emitter. The analysis takes into account the characteristic dependence of the STED on the depletion light power, i.e. the photon source, and a spatial distribution of the light intensity. The analysis may be applied to spatially resolved measurements or an integral value of the photoluminescence quenching. The analysis may determine characteristics such as peak power, power scaling factor, and FWHM of the illumination profile of the photon emitter.

Claims

1. A method of determining one or more characteristics of a photon emitter, the method comprising:

producing excitation illumination that is incident on a crystal film with one or more nitrogen vacancy centers, wherein the one or more nitrogen vacancy centers produces photoluminescence with an intensity in response to the excitation illumination;

producing illumination from the photon emitter, the illumination being incident on the crystal film with the one or more nitrogen vacancy centers, wherein the illumination produced by the photon emitter quenches the intensity of the photoluminescence from the one or more nitrogen vacancy centers;

detecting an amount of quenching of the intensity of the photoluminescence from the one or more nitrogen vacancy centers caused by the illumination of the photon emitter; and

analyzing the amount of quenching of the intensity of the photoluminescence to determine the one or more characteristics of the photon emitter.

2. The method of claim 1, wherein analyzing the amount of quenching of the intensity of the photoluminescence comprises fitting the amount of quenching of the intensity of the photoluminescence to a photoluminescence quenching model to determine the one or more characteristics of the photon emitter.

3. The method of claim 1, wherein analyzing the amount of quenching of the intensity of the photoluminescence comprises comparing the amount of quenching of the intensity of the photoluminescence to a library of data to determine the one or more characteristics of the photon emitter.

4. The method of claim 1, wherein the illumination produced by the photon emitter is near field illumination.

5. The method of claim 1, wherein the illumination produced by the photon emitter is far field illumination.

6. The method of claim 1, wherein detecting the amount of quenching of the intensity of the photoluminescence from the one or more nitrogen vacancy centers of the crystal film comprises:

detecting a first photoluminescence intensity from the one or more nitrogen vacancy centers in response to the excitation illumination without the illumination produced by the photon emitter incident on the crystal film;

detecting a second photoluminescence intensity from the one or more nitrogen vacancy centers in response to the excitation illumination with the illumination produced by the photon emitter incident on the crystal film; and

determining the amount of quenching of the intensity of the photoluminescence based on a difference between the first photoluminescence intensity and the second photoluminescence intensity.

7. The method of claim 1, the method further comprising providing different magnitudes of a bias current to the photon emitter, wherein the one or more characteristics of the photon emitter are determined for the different magnitudes of the bias current.

8. The method of claim 1, wherein the photon emitter is an optical device with a near-field aperture on a recording head.

9. The method of claim 1, wherein the crystal film has a patterned surface forming islands with a diameter larger than a maximum dimension of an expected quenching profile for the photon emitter.

10. The method of claim 1, wherein the method further comprises calibrating the photoluminescence quenching model by detecting a quenching scaling factor and a quenching exponent.

11. The method of claim 1, wherein the crystal film is on a probe tip, the method further comprising:

scanning the crystal film on the probe tip over the photon emitter while detecting the quenching of the intensity of the photoluminescence to produce a one-dimensional distribution profile of the quenching of the intensity of the photoluminescence or a two-dimensional distribution profile of the quenching of the intensity of the photoluminescence;

wherein analyzing the quenching of the intensity of the photoluminescence produces a peak power and a width of an illumination profile produced by the photon emitter.

12. The method of claim 11, wherein when the two-dimensional distribution profile of the quenching of the intensity of the photoluminescence is produced, a line extending through a point of greatest quenching of the two-dimensional distribution profile is used as a line profile of the quenching of the intensity of the photoluminescence, and wherein analyzing the quenching of the intensity of the photoluminescence uses the line profile of the quenching of the photoluminescence.

13. The method of claim 1, wherein the crystal film comprises a plurality of nitrogen vacancy centers, wherein an average distance between adjacent nitrogen vacancy centers is equal to or greater than two times a width of an expected quenching profile, the method further comprising:

producing relative movement between the photon emitter and the crystal film thereby scanning the crystal film over the photon emitter while detecting the quenching of the intensity of the photoluminescence to produce a two-dimensional distribution profile of the quenching of the intensity of the photoluminescence;

wherein analyzing the quenching of the intensity of the photoluminescence produces a peak power and a width of an illumination profile produced by the photon emitter.

14. The method of claim 13, wherein the photon emitter is on a recording head and the crystal film is in contact with an air bearing surface (ABS) of the recording head.

15. The method of claim 13, a line extending through a point of greatest quenching of the two-dimensional distribution profile is used as a line profile of the quenching of the intensity of the photoluminescence, and wherein analyzing the quenching of the intensity of the photoluminescence uses the line profile of the quenching of the photoluminescence.

16. The method of claim 1, wherein the crystal film comprises a plurality of nitrogen vacancy centers, wherein an average distance between adjacent nitrogen vacancy centers is less than two times a width of an expected quenching profile, the method further comprising:

producing a Stimulated Emission Depletion (STED) illumination that is coincident on the crystal film with the excitation illumination; and

scanning the excitation illumination and the STED illumination in two dimensions over the crystal film while detecting the quenching of the intensity of the photoluminescence to produce a two-dimensional distribution profile of the quenching of the intensity of the photoluminescence;

wherein analyzing the quenching of the intensity of the photoluminescence produces a peak power and a width of an illumination profile produced by the photon emitter.

17. The method of claim 16, a line extending through a point of greatest quenching of the two-dimensional distribution profile is used as a line profile of the quenching of the intensity of the photoluminescence, and wherein analyzing the quenching of the intensity of the photoluminescence uses the line profile of the quenching of the photoluminescence.

18. The method of claim 1, wherein the crystal film comprises a plurality of nitrogen vacancy centers, wherein an average distance between adjacent nitrogen vacancy centers is less than two times a width of an expected quenching profile, wherein detecting the quenching of the intensity of the photoluminescence comprises collecting the quenching of the intensity of the photoluminescence from an area on the crystal film that is larger than the expected quenching profile, the method further comprising:

providing different magnitudes of a bias current to the photon emitter, wherein the quenching of the intensity of the photoluminescence is detected as a function of the bias current;

wherein analyzing the quenching of the intensity of the photoluminescence produces a bias current to power conversion factor and a width of an illumination profile produced by the photon emitter.

19. A method of determining one or more characteristics of a photon emitter, the method comprising:

producing a first excitation illumination that is incident on a crystal film with one or more nitrogen vacancy centers, wherein the one or more nitrogen vacancy centers produces photoluminescence with an intensity in response to the first excitation illumination;

detecting a first photoluminescence intensity from the one or more nitrogen vacancy centers in response to the first excitation illumination;

producing a second excitation illumination that is incident on the crystal film with the one or more nitrogen vacancy centers;

producing illumination from the photon emitter, the illumination being incident on the crystal film with the one or more nitrogen vacancy centers, wherein the illumination produced by the photon emitter quenches the intensity of the photoluminescence produced by the one or more nitrogen vacancy centers in response to the second excitation illumination;

detecting a second photoluminescence intensity from the one or more nitrogen vacancy centers in response to the second excitation illumination and the illumination produced by the photon emitter;

determining an amount of quenching of photoluminescence intensity based on a difference between the first photoluminescence intensity and the second photoluminescence intensity; and

analyzing the amount of quenching of the intensity of the photoluminescence to determine the one or more characteristics of the photon emitter.

20. The method of claim 19, wherein analyzing the amount of quenching of the intensity of the photoluminescence comprises fitting the amount of quenching of the intensity of the photoluminescence to a photoluminescence quenching model to determine the one or more characteristics of the photon emitter.

21. The method of claim 19, wherein analyzing the amount of quenching of the intensity of the photoluminescence comprises comparing the amount of quenching of the intensity of the photoluminescence to a library of data to determine the one or more characteristics of the photon emitter.

22. The method of claim 19, the method further comprising providing different magnitudes of a bias current to the photon emitter, wherein the one or more characteristics of the photon emitter are determined for the different magnitudes of the bias current.

23. The method of claim 19, wherein the photon emitter is a optical device with a near-field aperture on a recording head.

24. The method of claim 19, wherein analyzing the quenching of the intensity of the photoluminescence produces a peak power and a width of an illumination profile produced by the photon emitter.

25. The method of claim 24, wherein the crystal film is on a probe tip, the method further comprising:

scanning the crystal film on the probe tip over the photon emitter while detecting the quenching of the intensity of the photoluminescence to produce a one-dimensional distribution profile of the quenching of the intensity of the photoluminescence or a two-dimensional distribution profile of the quenching of the intensity of the photoluminescence; and

determining a line extending through a point of greatest quenching of the two-dimensional distribution profile when two-dimensional distribution profile of the quenching of the intensity of the photoluminescence is produced, the line is used as a line profile of the quenching of the intensity of the photoluminescence, and wherein analyzing the quenching of the intensity of the photoluminescence uses the line profile of the quenching of the photoluminescence.

26. The method of claim 24, wherein the crystal film comprises a plurality of nitrogen vacancy centers, wherein an average distance between adjacent nitrogen vacancy centers is equal to or greater than two times a width of an expected quenching profile, the method further comprising:

producing relative movement between the photon emitter and the crystal film thereby scanning the crystal film over the photon emitter while detecting the quenching of the intensity of the photoluminescence to produce a two-dimensional distribution profile of the quenching of the intensity of the photoluminescence; and

determining a line extending through a point of greatest quenching of the two-dimensional distribution profile that is a line profile of the quenching of the intensity of the photoluminescence, and wherein analyzing the quenching of the intensity of the photoluminescence uses the line profile of the quenching of the photoluminescence.

27. The method of claim 24, wherein the crystal film comprises a plurality of nitrogen vacancy centers, wherein an average distance between adjacent nitrogen vacancy centers is less than two times a width of an expected quenching profile, the method further comprising:

producing a Stimulated Emission Depletion (STED) illumination that is coincident on the crystal film with excitation illumination; and

scanning the coincident excitation illumination and the STED illumination in two dimensions over the crystal film while detecting the quenching of the intensity of the photoluminescence to produce a two-dimensional distribution profile of the quenching of the intensity of the photoluminescence; and

determining a line extending through a point of greatest quenching of the two-dimensional distribution profile that is a line profile of the quenching of the intensity of the photoluminescence, and wherein analyzing the quenching of the intensity of the photoluminescence uses the line profile of the quenching of the photoluminescence.

28. The method of claim 19, wherein the crystal film comprises a plurality of nitrogen vacancy centers, wherein an average distance between adjacent nitrogen vacancy centers is less than two times a width of an expected quenching profile, wherein detecting the quenching of the intensity of the photoluminescence comprises collecting the quenching of the intensity of the photoluminescence from an area on the crystal film that is larger than the expected quenching profile, the method further comprising:

providing different magnitudes of a bias current to the photon emitter, wherein the quenching of the intensity of the photoluminescence is detected as a function of the bias current;

wherein analyzing the quenching of the intensity of the photoluminescence produces a bias current to power conversion factor and a width of an illumination profile produced by the photon emitter.

29. An apparatus for determining one or more characteristics of a photon emitter, the apparatus comprising:

a light source that produces excitation illumination that is incident on a crystal film with one or more nitrogen vacancy centers, wherein the one or more nitrogen vacancy centers produces photoluminescence with an intensity in response to the excitation illumination;

a microscope configured to detect the photoluminescence produced by the nitrogen vacancy centers in response to the excitation illumination;

a bias source configured to provide bias signals;

a probe card coupled to the bias source and configured to be connected to a device that includes the photon emitter, the probe card provides a bias signal to the device that causes the photon emitter to emit illumination that is incident on the crystal film with the one or more nitrogen vacancy centers, wherein the illumination produced by the photon emitter quenches the intensity of the photoluminescence from the one or more nitrogen vacancy centers; and

a processor coupled to control the microscope, the light source and the bias source and configured to cause the microscope to detect the photoluminescence produced by the nitrogen vacancy centers in response to the excitation illumination and to determine an amount of quenching of the intensity of the photoluminescence from the one or more nitrogen vacancy centers caused by the illumination produced by the photon emitter, and to analyze the amount of quenching of the intensity of the photoluminescence to determine the one or more characteristics of the photon emitter.

30. The apparatus of claim 29, wherein the processor is configured to analyze the amount of quenching of the intensity of the photoluminescence by being configured to fit the amount of quenching of the intensity of the photoluminescence to a photoluminescence quenching model to determine the one or more characteristics of the photon emitter.

31. The apparatus of claim 29, wherein the processor is configured to analyze the amount of quenching of the intensity of the photoluminescence by being configured to compare the amount of quenching of the intensity of the photoluminescence to a library of data to determine the one or more characteristics of the photon emitter.

32. The apparatus of claim 29, wherein the processor is configured to determine the amount of quenching of the intensity of the photoluminescence from the one or more nitrogen vacancy centers of the crystal film by being configured to:

cause the microscope to detect a first photoluminescence intensity from the one or more nitrogen vacancy centers in response to the excitation illumination without the illumination produced by the photon emitter incident on the crystal film;

cause the microscope to detect a second photoluminescence intensity from the one or more nitrogen vacancy centers in response to the excitation illumination with the illumination produced by the photon emitter incident on the crystal film;

wherein the amount of quenching of the intensity of the photoluminescence is determined based on a difference between the first photoluminescence intensity and the second photoluminescence intensity.

33. The apparatus of claim 29, wherein the processor is configured to cause the bias source to provide different magnitudes of a bias current to the device, wherein the one or more characteristics of the photon emitter are determined for the different magnitudes of the bias current.

34. The apparatus of claim 29, wherein the photon emitter is a optical device with a near-field aperture on a recording head.

35. The apparatus of claim 29, wherein the crystal film has a patterned surface forming islands with a diameter larger than a maximum dimension of an expected quenching profile for the photon emitter.

36. The apparatus of claim 29, wherein the processor is configured to analyze the quenching of the intensity of the photoluminescence to determine a peak power and a width of an illumination profile produced by the photon emitter.

37. The apparatus of claim 36, further comprising:

a probe having a probe tip holding the crystal film;

wherein the processor is coupled to the probe and causes the probe to scan the crystal film on the probe tip over the photon emitter while the microscope detects the photoluminescence to produce a one-dimensional distribution profile of the quenching of the intensity of the photoluminescence or a two-dimensional distribution profile of the quenching of the intensity of the photoluminescence;

wherein the processor is further configured to determine a line extending through a point of greatest quenching of the two-dimensional distribution profile when the two-dimensional distribution profile of the quenching of the intensity of the photoluminescence is produced, the line is used as a line profile of the quenching of the intensity of the photoluminescence, and wherein the processor is configured to analyze the quenching of the intensity of the photoluminescence using the line profile of the quenching of the photoluminescence.

38. The apparatus of claim 36, wherein the crystal film comprises a plurality of nitrogen vacancy centers, wherein an average distance between adjacent nitrogen vacancy centers is equal to or greater than two times a width of an expected quenching profile, the apparatus further comprising:

at least one actuator to produce relative movement between the photon emitter and the crystal film thereby scanning the crystal film over the photon emitter while the microscope detects the photoluminescence to produce a two-dimensional distribution profile of the quenching of the intensity of the photoluminescence; and

wherein the processor is further configured to determine a line extending through a point of greatest quenching of the two-dimensional distribution profile that is a line profile of the quenching of the intensity of the photoluminescence, and wherein the processor is configured to analyze the quenching of the intensity of the photoluminescence using the line profile of the quenching of the photoluminescence.

39. The apparatus of claim 36, wherein the crystal film comprises a plurality of nitrogen vacancy centers, wherein an average distance between adjacent nitrogen vacancy centers is less than two times a width of an expected quenching profile, the apparatus further comprising:

a second light source that produces depletion illumination that is coincident on the crystal film with the excitation illumination;

at least one mirror to scan the coincident excitation illumination and the depletion illumination in two dimensions over the crystal film while the microscope detects the photoluminescence to produce a two-dimensional distribution profile of the quenching of the intensity of the photoluminescence;

wherein the processor is further configured to determine a line extending through a point of greatest quenching of the two-dimensional distribution profile that is a line profile of the quenching of the intensity of the photoluminescence, and wherein the processor is configured to analyze the quenching of the intensity of the photoluminescence using the line profile of the quenching of the photoluminescence.

40. The apparatus of claim 29, wherein the crystal film comprises a plurality of nitrogen vacancy centers, wherein an average distance between adjacent nitrogen vacancy centers is less than two times a width of an expected quenching profile, wherein the microscope detects the photoluminescence from an area on the crystal film that is larger than the expected quenching profile, and wherein the processor is configured to determine the quenching of the intensity of the photoluminescence comprises over the area on the crystal film, wherein the processor is further configured to:

cause the bias source provide different magnitudes of bias currents to the device, wherein the quenching of the intensity of the photoluminescence is determined as a function of bias current;

wherein the processor is configured to analyze the quenching of the intensity of the photoluminescence to determine a bias current to power conversion factor and a width of an illumination profile produced by the photon emitter.