METHOD FOR ORIENTING ONE-DIMENSIONAL OBJECTS AND ARTICLES OBTAINED THEREFROM

• US 20160144401A1
• Filed: 06/08/2015
• Published: 05/26/2016
• Est. Priority Date: 06/06/2014
• Status: Abandoned Application

• Current Assignee: University Of Massachusetts
• Original Assignee: University Of Massachusetts
• Inventors: Carter, Kenneth R., John, Jacob
• Application Number:
  US14/733,259
• Publication Number:
  US 20160144401A1
• Time in Patent Office: Days
• CPC Class Codes: C01B 32/168 After-treatment
• CPC Class Codes: H10K 71/191 characterised by provisions for the orientation or alignment of the layer to be deposited
• CPC Class Codes: H10K 85/221 Carbon nanotubes

Abstract

Disclosed herein is a method comprising dispersing one-dimensional objects in a liquid to form a mixture; and disposing the mixture on a substrate that has channels disposed on it; where the channels are of a width of 4 to 90 percent of the length of the one-dimensional object. Disclosed herein is an article comprising a substrate; where the substrate has channels disposed thereon; each channel being bounded by a wall; and a plurality of one-dimensional objects that are oriented relative to the walls on the substrate; and where the channels are of a width of 4 to 90 percent of the smallest length of the plurality of one-dimensional objects.

Claims

14. An article comprising:

a substrate;

where the substrate has channels disposed thereon;

each channel being bounded by a wall; and

a plurality of one-dimensional objects that are oriented relative to the walls on the substrate; and

where the channels are of a width of 2 to 90 percent of the smallest length of the plurality of one-dimensional objects.

15. The article of claim 14, where the one-dimensional object is a nanotube, nanowire, nanorod, whisker, microtube, microwire, microrod, or combinations thereof.

16. The article of claim 14, where the one-dimensional objects are inorganic materials.

17. The article of claim 14, where the one-dimensional objects are organic materials.

18. The article of claim 16, where the inorganic one-dimensional object is selected from the group consisting of elemental metals, metal alloys, metal oxides, metal sulfides, metal nitrides, metal borides, metal silicides, metal phosphides, metal carbides, or a combination comprising at least one of the foregoing inorganic materials.

19. The article of claim 14, where the one-dimensional object is selected from the group consisting of carbon nanotubes, carbon nanotubes having pendant organic or inorganic substituents, nucleic acids, polymeric fibers, nanotubes or nanowires or nanorods comprising molybdenum, silicon, boron nitride, tungsten disulfide, tin disulfide, vanadium oxide, aluminum oxide, titanium oxide, zinc oxide, manganese oxide, transition metal/chalcogen/halogenides having the formula TM6CyHz, where TM is a transition metal, C is a chalcogen, H is halogen and where 8.2<

(y+z)<

10, polyacetylene nanowires or microwires, polyacrylate nanowires or microwires, polyester nanowires or microwires, polystyrene nanowires or microwires, polycarbonate nanowires or microwires, polyimide nanowires or microwires, polyetherimide nanowires or microwires, polyetheroxide nanowires or microwires, polyether ketone nanowires or microwires, polysiloxane nanowires or microwires, polyfluoroethylene nanowires or microwires, cellulose nanowires or microwires, or combinations thereof.

20. The article of claim 14, where the substrate comprises a polymer.

21. The article of claim 14, where the substrate comprises a silicon wafer, glass, oxides, metal, paper, ceramic, composites, clothes, and the like.

22. The article of claim 14, where the one-dimensional objects are fused together.

23. The article of claim 14, where the one-dimensional objects are fused to the substrate.

24. The article of claim 14, where the one-dimensional objects are oriented approximately perpendicular to the walls.

25. The article of claim 14, where the substrate with the channels disposed thereon is naturally occurring.

26. A method comprising:

dispersing one-dimensional objects in a liquid to form a mixture; and

disposing the mixture on a first substrate that has channels disposed on it;

each channel being bounded by pair of walls that are substantially parallel to each other at a first distance “

x”

;

collecting one-dimensional objects that are not contained in the channels from the first substrate;

disposing the one-dimensional objects so collected onto a second substrate that has channels disposed on it;

each channel being bounded by pair of walls that are substantially parallel to each other at a first distance “

y”

;

where y is greater than x; and

collecting one-dimensional objects that are not contained in the channels from the second substrate.

27. The method of claim 26, further comprising collecting the one-dimensional objects contained in the channels of the first substrate separately from the one-dimensional objects contained in the channels of the second substrate.

28. A method of manufacturing a device comprising:

disposing a first layer on a substrate;

imprinting on the first layer a plurality of channels that are parallel to one another;

each channel being bounded by pair of walls that are substantially parallel to each;

dispersing a one-dimensional object in a liquid to form a mixture; and

disposing the mixture on the first layer in a manner such that the one-dimensional objects are located in precisely desired positions on the first layer;

1. A method comprising:

dispersing one-dimensional objects in a liquid to form a mixture; and

disposing the mixture on a substrate that has channels disposed on it;

where the channels are of a width of 2 to 90 percent of the length of the one-dimensional object.

2. The method of claim 1, further comprising disposing the channels on the substrate;

and where the channels are disposed on the substrate by nanoimprinting, roll-to-roll ultraviolet nanoimprinting, laser printing, embossing, lithography followed by etching, self-assembly of a copolymer followed by etching;

photolithography followed by etching;

surface wrinkling, creasing or buckling, nano-scribing, scratching, shadow deposition, transfer printing, interference lithography, immersion lithography, atomic force microscopy lithography, e-beam lithography, nano-scribing, or a combination thereof.

3. The method of claim 1, where the liquid in the mixture is 50 to 10000 weight percent of the weight of the one-dimensional objects.

4. The method of claim 1, where the liquid is polar.

5. The method of claim 1, where the liquid is non-polar.

6. The method of claim 1, where the one-dimensional object is a nanotube, nanowire, nanorod, whisker, microtube, microwire, microrod, or combinations thereof.

7. The method of claim 1, where the one-dimensional objects are inorganic materials.

8. The method of claim 1, where the one-dimensional objects are organic materials.

9. The method of claim 7, where the inorganic one-dimensional object is selected from the group consisting of elemental metals, metal alloys, metal oxides, metal sulfides, metal nitrides, metal borides, metal silicides, metal phosphides, metal carbides, or a combination comprising at least one of the foregoing inorganic materials.

10. The method of claim 1, where the one-dimensional object is selected from the group consisting of carbon nanotubes, carbon nanotubes having pendant organic or inorganic substituents, nucleic acids, polymeric fibers, nanotubes or nanowires or nanorods comprising molybdenum, silicon, boron nitride, tungsten disulfide, tin disulfide, vanadium oxide, aluminum oxide, titanium oxide, zinc oxide, manganese oxide, transition metal/chalcogen/halogenides having the formula TM₆C_yH_z, where TM is a transition metal, C is a chalcogen, H is halogen and where 8.2<

(y+z)<

10, polyacetylene nanowires or microwires, polyacrylate nanowires or microwires, polyester nanowires or microwires, polystyrene nanowires or microwires, polycarbonate nanowires or microwires, polyimide nanowires or microwires, polyetherimide nanowires or microwires, polyetheroxide nanowires or microwires, polyether ketone nanowires or microwires, polysiloxane nanowires or microwires, polyfluoroethylene nanowires or microwires, cellulose nanowires or microwires, or combinations thereof.

11. The method of claim 1, where the liquid is selected from the group consisting of water, alcohols, ketones, glycol ethers, propylene carbonate, ethylene carbonate, butyrolactone, acetonitrile, benzonitrile, nitromethane, nitrobenzene, sulfolane, dimethylformamide, dimethylacetamide, N-methylpyrrolidone, nitromethane, methanol, ethanol, propanol, isopropanol, butanol, benzene, toluene, methylene chloride, carbon tetrachloride, hexane, diethyl ether, tetrahydrofuran, or combinations thereof.

12. The method of claim 1, further comprising drying the substrate.

13. The method of claim 1, further comprising preheating the substrate and drying the substrate.

29. The method of claim 28, further comprising a second layer that contacts the first layer.

30. The method of claim 29, where the first layer is hydrophobic and the second layer is hydrophilic.

31. The method of claim 29, where the first layer is hydrophilic and the second layer is hydrophobic.

32. The method of claim 28, further disposing a photoresist on the device and etching a portion of the device prior to disposing the mixture on the first layer.

33. The method of claim 28, where the channels are disposed on the first layer by nano imprinting, roll-to-roll ultraviolet nano imprinting, laser printing, embossing, lithography, or a combination thereof.

34. The method of claim 32, where the etching comprises reactive ion etching, chemical etching, plasma etching or a combination thereof.

35. The method of claim 28, where the one-dimensional object is a nanotube, nanowire, nanorod, whisker, microtube, microwire, microrod, or combinations thereof.

36. The method of claim 28, where the one-dimensional objects are inorganic materials.

37. The method of claim 28, where the one-dimensional objects are organic materials.

38. The method of claim 36, where the inorganic one-dimensional object is selected from the group consisting of elemental metals, metal alloys, metal oxides, metal sulfides, metal nitrides, metal borides, metal silicides, metal phosphides, metal carbides, or a combination comprising at least one of the foregoing inorganic materials.

39. The method of claim 29, further comprising a third layer that contacts the second layer.

39-1. The method of claim 28, where the one-dimensional object is selected from the group consisting of carbon nanotubes, carbon nanotubes having pendant organic or inorganic substituents, nucleic acids, polymeric fibers, nanotubes or nanowires or nanorods comprising molybdenum, silicon, boron nitride, tungsten disulfide, tin disulfide, vanadium oxide, aluminum oxide, titanium oxide, zinc oxide, manganese oxide, transition metal/chalcogen/halogenides having the formula TM₆C_yH_z, where TM is a transition metal, C is a chalcogen, H is halogen and where 8.2<

(y+z)<

10, polyacetylene nanowires or microwires, polyacrylate nanowires or microwires, polyester nanowires or microwires, polystyrene nanowires or microwires, polycarbonate nanowires or microwires, polyimide nanowires or microwires, polyetherimide nanowires or microwires, polyetheroxide nanowires or microwires, polyether ketone nanowires or microwires, polysiloxane nanowires or microwires, polyfluoroethylene nanowires or microwires, cellulose nanowires or microwires, or combinations thereof.