FUEL CELL SYSTEM AND METHOD OF CONTROLLING OPERATION OF FUEL CELL

• US 20160190613A1
• Filed: 12/21/2015
• Published: 06/30/2016
• Est. Priority Date: 12/26/2014
• Status: Active Grant

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Inventors: SHIOKAWA, Satoshi, BONO, Tetsuya, HAMANOI, Osamu
• Granted Patent: US 10,122,030 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: H01M 8/04067 Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
• CPC Class Codes: H01M 8/04126 Humidifying
• CPC Class Codes: H01M 8/04201 Reactant storage and supply, e.g. means for feeding, pipes
• CPC Class Codes: H01M 8/0432 Temperature; Ambient temperature
• CPC Class Codes: H01M 8/04634 Other electric variables, e.g. resistance or impedance
• CPC Class Codes: H01M 8/04641 of the individual fuel cell
• CPC Class Codes: H01M 8/04753 of fuel cell reactants
• CPC Class Codes: H01M 8/04761 of fuel cell exhausts
• CPC Class Codes: H01M 8/04828 Humidity; Water content
• CPC Class Codes: H01M 8/04835 of fuel cell reactants
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cell system includes a fuel cell including an electrolyte membrane, a sensor configured to measure a temperature of the fuel cell, and a controller. The controller is configured to cause the fuel cell to perform a wet operation to increase a water balance at a cathode of the fuel cell to a value higher than a water balance at the cathode during a normal operation of the fuel cell, when the temperature of the fuel cell measured by the sensor is maintained at a first threshold temperature or higher for a prescribed period of time or longer and then the temperature of the fuel cell decreases to below a second threshold temperature that is equal to or lower than the first threshold temperature.

Claims

1. A fuel cell system comprising:

a fuel cell including an electrolyte membrane;

a sensor configured to measure a temperature of the fuel cell; and

a controller configured to cause the fuel cell to perform a wet operation to increase a water balance at a cathode of the fuel cell to a value higher than a water balance at the cathode during a normal operation of the fuel cell, when the temperature of the fuel cell measured by the sensor is maintained at a first threshold temperature or higher for a prescribed period of time or longer and then the temperature of the fuel cell decreases to below a second threshold temperature that is equal to or lower than the first threshold temperature.

2. The fuel cell system according to claim 1, further comprising:

a cathode off-gas discharging passage disposed in the fuel cell; and

a pressure regulator configured to regulate a pressure in the cathode off-gas discharging passage,

wherein the controller is configured to cause the fuel cell to perform the wet operation by controlling the pressure regulator such that the pressure in the cathode off-gas discharging passage is increased to a value higher than a pressure in the cathode off-gas discharging passage during the normal operation of the fuel cell.

3. The fuel cell system according to claim 1, further comprising:

a cathode reactant gas supplier configured to supply a cathode reactant gas to the fuel cell,

wherein the controller is configured to cause the fuel cell to perform the wet operation by controlling the cathode reactant gas supplier such that a flow rate of the cathode reactant gas to be supplied to the fuel cell is decreased to a value lower than a flow rate of the cathode reactant gas to be supplied to the fuel cell during the normal operation of the fuel cell.

4. The fuel cell system according to claim 1, further comprising:

an anode reactant gas supplying passage through which an anode reactant gas is supplied to the fuel cell;

an anode off-gas discharging passage through which an anode off-gas from the fuel cell is discharged;

a circulation passage that connects the anode reactant gas supplying passage and the anode off-gas discharging passage to each other,

a pump disposed on the circulation passage, the pump being configured to supply at least a portion of the anode off-gas to the anode reactant gas supplying passage;

a cathode reactant gas supplying passage through which a cathode reactant gas is supplied to the fuel cell; and

a cathode off-gas discharging passage through which a cathode off-gas from the fuel cell is discharged,

wherein the cathode reactant gas is supplied to one side of the electrolyte membrane of the fuel cell and the anode reactant gas is supplied to the other side of the electrolyte membrane of the fuel cell, and a direction in which the cathode reactant gas is supplied to the fuel cell is opposite to a direction in which the anode reactant gas is supplied to the fuel cell, and

wherein the controller is configured to cause the fuel cell to perform the wet operation by controlling the pump such that a flow rate of the anode off-gas in the circulation passage is increased to a value higher than a flow rate of the anode off-gas in the circulation passage during the normal operation of the fuel cell.

5. The fuel cell system according to claim 1, further comprising:

an impedance meter configured to measure an impedance of the fuel cell,

wherein the controller is configured to start control for causing the fuel cell to perform the wet operation when the impedance measured by the impedance meter is a prescribed value or lower and the temperature of the fuel cell measured by the sensor is decreased from a temperature equal to or higher than the second threshold temperature to a temperature lower than the second threshold temperature.

6. The fuel cell system according to claim 1, wherein the first threshold temperature is a temperature at a boundary between a temperature range in which the water balance is a positive value and a temperature range in which the water balance is a negative value, under the same operation conditions other than the temperature of the fuel cell.

7. The fuel cell system according to claim 1, further comprising:

an impedance meter configured to measure an impedance of the fuel cell, wherein

the controller is configured to start control for causing the fuel cell to perform the wet operation when the temperature of the fuel cell measured by the sensor is decreased from a temperature equal to or higher than the second threshold temperature to a temperature lower than the second threshold temperature, and

the controller is configured to terminate the control for causing the fuel cell to perform the wet operation when any one of three conditions i) to iii) is satisfied;

i) the temperature of the fuel cell re-increases to the first threshold temperature or higher;

ii) the impedance of the fuel cell measured by the impedance meter increases to a value equal to or higher than a prescribed threshold that indicates a dry state of the fuel cell and then decreases to below the threshold, after the fuel cell starts to perform the wet operation; and

iii) a prescribed period of time has elapsed after the fuel cell starts to perform the wet operation.

8. A method of controlling an operation of a fuel cell including an electrolyte membrane, the method comprising:

measuring a temperature of the fuel cell; and

causing the fuel cell to perform a wet operation to increase a water balance at a cathode of the fuel cell to a value higher than a water balance at the cathode during a normal operation of the fuel cell, when the temperature of the fuel cell is maintained at a first threshold temperature or higher for a prescribed period of time or longer and then the temperature of the fuel cell decreases to below a second threshold temperature that is equal to or lower than the first threshold temperature.