METHOD FOR REDUCING BOW IN LAMINATE STRUCTURE

• US 20160193812A1
• Filed: 12/30/2015
• Published: 07/07/2016
• Est. Priority Date: 01/06/2015
• Status: Abandoned Application

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Couillard, James Gregory
• Application Number:
  US14/984,009
• Publication Number:
  US 20160193812A1
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/101 having a predetermined coefficient of thermal expansion [CTE]
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/10871 in combination with particular heat treatment
• CPC Class Codes: B32B 17/1099 After-treatment of the layered product, e.g. cooling
• CPC Class Codes: B32B 2038/0048 Annealing, relaxing
• CPC Class Codes: B32B 2038/006 Relieving internal or residual stresses
• CPC Class Codes: B32B 2315/08 Glass
• CPC Class Codes: B32B 2419/00 Buildings or parts thereof walls, panels B32B2607/00
• CPC Class Codes: B32B 2551/00 Optical elements
• CPC Class Codes: B32B 2605/08 Cars
• CPC Class Codes: B32B 37/0015 to avoid warp or curl
• CPC Class Codes: B32B 37/06 characterised by the heating method
• CPC Class Codes: B32B 37/144 using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding constructional features for tensioning B32B38/1825
• CPC Class Codes: B32B 38/0036 Heat treatment for heating or cooling of layers during lamination B32B37/06, B32B37/08
• CPC Class Codes: B32B 7/027 Thermal properties

Abstract

Disclosed herein are methods for making asymmetric laminate structures and methods for reducing bow in asymmetric laminate structures, the methods comprising subjecting the laminate structures to at least one thermal cycle comprising cooling the laminate structures to a first temperature near or below room temperature and heating the laminate structures to a second temperature near or below the lamination temperature. Also disclosed herein are laminate structures made according to such methods.

Claims

1. A method for making a laminate structure, comprising:

positioning an interlayer between a first substrate and a second substrate to form a stack;

heating the stack to a lamination temperature to form a laminate structure; and

subjecting the laminate structure to at least one thermal cycle,

wherein the thermal cycle comprises cooling the laminate structure to a first temperature ranging from about −

20°

C. to about 35°

C., and heating the laminate structure to a second temperature below the lamination temperature, the second temperature ranging from about 50°

C. to about 120°

C., and wherein a coefficient of thermal expansion of the first substrate is different than a coefficient of thermal expansion of the second substrate.

2. The method of claim 1, wherein the interlayer is chosen from polyvinyl butyral, ethylene-vinyl acetate, thermoplastic polyurethane, and ionomers.

3. The method of claim 1, wherein the first and second substrates are independently chosen from glass, glass-ceramics, ceramics, polymers, and metals.

4. The method of claim 1, wherein the lamination temperature ranges from about 120°

C. to about 160°

C.

5. The method of claim 4, wherein the stack is heated to the lamination temperature at a pressure ranging from about 0.1 MPa to about 1.5 MPa.

6. The method of claim 1, further comprising heating the stack to a conditioning temperature ranging from about 75°

C. to about 100°

C.

7. The method of claim 1, wherein the thermal cycle comprises a ramp rate between the first and second temperatures ranging from about 0.1°

C./min to about 2°

C./min.

8. The method of claim 7, wherein the thermal cycle further comprises holding the laminate structure at the first temperature for a first time period ranging from about 30 minutes to about 4 hours, and holding the laminate structure at the second temperature for a second time period ranging from about 30 minutes to about 4 hours.

9. The method of claim 8, wherein the thermal cycle further comprises holding the laminate structure at one or more intermediate temperatures between the first and second temperatures.

10. The method of claim 1, wherein the coefficient of thermal expansion of the first substrate is at least 0.1% greater than the coefficient of thermal expansion of the second substrate.

11. The method of claim 1, wherein the coefficient of thermal expansion of the first substrate is at least 30% greater than the coefficient of thermal expansion of the second substrate.

12. The method of claim 1, wherein the stack further comprises an additional layer chosen from polymer layers, additional glass layers, reflective layers, and electrochromic layers.

13. A laminate structure comprising a first glass substrate, a second glass substrate, and an interlayer attaching the first and second glass substrates,

wherein a minimum radius of curvature of the laminate structure at a temperature ranging from about −

20°

C. to about 90°

C. is at least about 30 times greater than a maximum dimension of the laminate structure, and

wherein a coefficient of thermal expansion of the first glass substrate is at least about 30% greater than a coefficient of thermal expansion of the second glass substrate.

14. The laminate structure of claim 13, wherein the minimum radius of curvature is at least about 40 times greater than the maximum dimension of the laminate structure.

15. The laminate structure of claim 13, wherein the minimum radius of curvature is at least about 50 times greater than the maximum dimension of the laminate structure.

16. The laminate structure of claim 13, wherein the difference between the coefficient of thermal expansion of the first glass substrate and the coefficient of thermal expansion of the second glass substrate ranges from about 1×

10<sup>−

6</sup>PC to about 10×

10<sup>−

6</sup>/°

C.

17. The laminate structure of claim 13, wherein the first glass substrate has a thickness ranging from about 3 mm to about 10 mm, and wherein the second glass substrate has a thickness ranging from about 0.3 mm to about 2 mm.

18. The laminate structure of claim 13, wherein the coefficient of thermal expansion of the first glass substrate ranges from about 8×

10<sup>−

6</sup>PC to about 10×

10<sup>−

6</sup>/°

C.

19. The laminate structure of claim 13, wherein the coefficient of thermal expansion of the second glass substrate ranges from about 3×

10<sup>−

6</sup>PC to about 4×

10<sup>−

6</sup>/°

C.

20. The laminate structure of claim 13, further comprising at least one electrochromic layer.

21. The laminate structure of claim 20, wherein the electrochromic layer is inorganic.

22. A method for reducing bow in a laminate structure, comprising:

subjecting the laminate structure to at least one thermal cycle comprising cooling the laminate structure to a first temperature ranging from about −

20°

C. to about 35°

C. and heating the laminate structure to a second temperature ranging from about 50°

C. to about 120°

C.;

wherein the laminate comprises a first substrate and second substrate attached with an interlayer, and wherein a coefficient of thermal expansion of the first substrate is different than a coefficient of thermal expansion of the second substrate.

23. The method of claim 22, wherein the interlayer is chosen from polyvinyl butyral ethylene-vinyl acetate, thermoplastic polyurethane, and ionomers.

24. The method of claim 22, wherein the first and second substrates are independently chosen from glass, glass-ceramics, ceramics, polymers, and metals.

25. The method of claim 22, wherein the thermal cycle comprises a ramp rate between the first and second temperatures ranging from about 0.1°

C./min to about 2°

C./min.

26. The method of claim 25, wherein the thermal cycle further comprises holding the laminate structure at the first temperature for a first time period ranging from about 30 minutes to about 4 hours, and holding the laminate structure at the second temperature for a second time period ranging from about 30 minutes to about 4 hours.

27. The method of claim 26, wherein the thermal cycle further comprises holding the laminate structure at one or more intermediate temperatures between the first and second temperatures.

28. The method of claim 22, wherein the coefficient of thermal expansion of the first substrate is at least 0.1% greater than the coefficient of thermal expansion of the second substrate.