METHOD OF DEACIDIZING A GASEOUS EFFLUENT BY AN ABSORBENT SOLUTION WITH VAPOR INJECTION INTO THE REGENERATED ABSORBENT SOLUTION AND DEVICE FOR IMPLEMENTING SAME

• US 20160250590A1
• Filed: 11/02/2015
• Published: 09/01/2016
• Est. Priority Date: 11/04/2014
• Status: Active Grant

• Current Assignee: IFP Energies Nouvelles
• Original Assignee: IFP Energies Nouvelles
• Inventors: DREILLARD, Matthieu, RAYNAL, Ludovic
• Granted Patent: US 10,137,410 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: B01D 2252/204 Amines
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1462 Removing mixtures of hydrogen sulfide and carbon dioxide
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/18 Absorbing units; Liquid distributors therefor B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/78 with gas-liquid contact

Abstract

The invention is a method for deacidizing a gaseous effluent comprising acid compounds, such as CO₂ and/or H₂S, and a device for implementing the method, through contact with a demixing absorbent solution. Regeneration is performed by vapor injection into the liquid guard (202) formed by the regenerated absorbent solution in the bottom of regeneration column (G). The vapor is generated within a reboiler (203) from a fraction of the regenerated absorbent solution withdrawn from the regeneration column. Vapor injection enables convective movement of the liquid for preventing any decantation phenomenon in the bottom of the regeneration column bottom which is harmful to the smooth operation of the deacidizing process.

Claims

16. ) A method of deacidizing a gaseous effluent containing acid compounds, comprising:

a) contacting the gaseous effluent with an absorbent solution in an absorption column to obtain a gaseous effluent depleted of acid compounds and an absorbent solution laden with acid compounds, the absorbent solution forming two separable liquid phases when an amount of acid compounds have been absorbed and is heated;

b) separating the absorbent solution laden with acid compounds into a first liquid fraction depleted of acid compounds and a second liquid fraction enriched with acid compounds;

c) regenerating the second liquid fraction in a regeneration column to release part of the acid compounds and to obtain a regenerated absorbent solution, by injecting vapor resulting from a partial vaporization in a reboiler of a first part of the regenerated absorbent solution withdrawn from the regeneration column, the vapor injection being in a liquid reserve including a second part of the regenerated absorbent solution located in a bottom of the regeneration column to provide stirring of the second part of the regenerated absorbent solution; and

d) recycling the first liquid fraction obtained in b) and the regenerated absorbent solution obtained in c) as the absorbent solution to in a).

17. ) A method as claimed in claim 16, wherein the vapor is injected in a bottom of the liquid reserve.

18. ) A method as claimed in claim 16, wherein the first part of the regenerated absorbent solution is withdrawn from a tray located above the liquid reserve.

19. ) A method as claimed in claim 17, wherein the first part of the regenerated absorbent solution is withdrawn from a tray located above the liquid reserve.

20. ) A method as claimed in claim 16, wherein the vapor is injected into the liquid reserve at a superficial velocity ranging between 1 cm/s and 1 m/s.

21. ) A method as claimed in claim 17, wherein the vapor is injected into the liquid reserve at a superficial velocity ranging between 1 cm/s and 1 m/s.

22. ) A method as claimed in claim 18, wherein the vapor is injected into the liquid reserve at a superficial velocity ranging between 1 cm/s and 1 m/s.

23. ) A method as claimed in claim 19, wherein the vapor is injected into the liquid reserve at a superficial velocity ranging between 1 cm/s and 1 m/s.

24. ) A method as claimed in claim 16, wherein the vapor is injected into the liquid reserve at a superficial velocity and the superficial velocity is controlled by separating the partly vaporized absorbent solution from the reboiler into a first stream forming the vapor injected into the liquid reserve and into a second vapor stream injected above the liquid reserve, and by controlling the first and second streams.

25. ) A method as claimed in claim 17, wherein the vapor is injected into the liquid reserve at a superficial velocity and the superficial velocity is controlled by separating the partly vaporized absorbent solution from the reboiler into a first stream forming the vapor injected into the liquid reserve and into a second vapor stream injected above the liquid reserve, and by controlling the first and second streams.

26. ) A method as claimed in claim 18, wherein the vapor is injected into the liquid reserve at a superficial velocity and the superficial velocity is controlled by separating the partly vaporized absorbent solution from the reboiler into a first stream forming the vapor injected into the liquid reserve and into a second vapor stream injected above the liquid reserve, and by controlling the first and second streams.

28. ) A method as claimed in claim 16, wherein circulation of the regenerated absorbent solution located between the regeneration column and the reboiler is provided by a thermosiphon effect.

29. ) A method as claimed in claim 17, wherein circulation of the regenerated absorbent solution located between the regeneration column and the reboiler is provided by a thermosiphon effect.

30. ) A method as claimed in claim 20, wherein circulation of the regenerated absorbent solution located between the regeneration column and the reboiler is provided by a thermosiphon effect.

31. ) A method as claimed in claim 24, wherein circulation of the regenerated absorbent solution located between the regeneration column and the reboiler is provided by a thermosiphon effect.

32. ) A method as claimed in claim 28, wherein the thermosiphon effect is controlled by varying a first height defined by a difference in level between a draw-off tray from which the first part of the regenerated absorbent solution is withdrawn and a top of the liquid reserve, and/or by varying a second height defined by the difference in level between a point of injection of the vapor into the liquid reserve and the point of injection of the first part of the regenerated absorbent solution into the reboiler.

33. ) A method as claimed in claim 16 wherein, prior to separation b), the absorbent solution laden with acid compounds is heated, to a temperature ranging between 60°

C. and 140°

C., so that the absorbent solution forms two separable liquid fractions.

34. ) A method as claimed in claim 18 wherein, prior to separation b), the absorbent solution laden with acid compounds is heated, to a temperature ranging between 60°

C. and 140°

C., so that the absorbent solution forms two separable liquid fractions.

35. ) A method as claimed in claim 20 wherein, prior to separation b), the absorbent solution laden with acid compounds is heated, to a temperature ranging between 60°

C. and 140°

C., so that the absorbent solution forms two separable liquid fractions.

36. ) A method as claimed in claim 24 wherein, prior to separation b), the absorbent solution laden with acid compounds is heated, to a temperature ranging between 60°

C. and 140°

C., so that the absorbent solution forms two separable liquid fractions.

37. ) A method as claimed in claim 28 wherein, prior to separation b), the absorbent solution laden with acid compounds is heated, to a temperature ranging between 60°

C. and 140°

C., so that the absorbent solution forms two separable liquid fractions.

38. ) A method as claimed in claim 16, wherein the absorbent solution comprises between 10 wt. % and 90 wt. % of at least one reactive compound reacting with at least one of the acid compounds, and between 10 wt. % and 90 wt. % water.

39. ) A method as claimed in claim 18, wherein the absorbent solution comprises between 10 wt. % and 90 wt. % of at least one reactive compound reacting with at least one of the acid compounds, and between 10 wt. % and 90 wt. % water.

40. ) A method as claimed in claim 20, wherein the absorbent solution comprises between 10 wt. % and 90 wt. % of at least one reactive compound reacting with at least one of the acid compounds, and between 10 wt. % and 90 wt. % water.

41. ) A method as claimed in claim 24, wherein the absorbent solution comprises between 10 wt. % and 90 wt. % of at least one reactive compound reacting with at least one of the acid compounds, and between 10 wt. % and 90 wt. % water.

42. ) A method as claimed in claim 28, wherein the absorbent solution comprises between 10 wt. % and 90 wt. % of at least one reactive compound reacting with at least one of the acid compounds, and between 10 wt. % and 90 wt. % water.

43. ) A method as claimed in claim 32, wherein the absorbent solution comprises between 10 wt. % and 90 wt. % of at least one reactive compound reacting with at least one of the acid compounds, and between 10 wt. % and 90 wt. % water.

44. ) A method as claimed in claim 33, wherein the absorbent solution comprises between 10 wt. % and 90 wt. % of at least one reactive compound reacting with at least one of the acid compounds, and between 10 wt. % and 90 wt. % water.

45. ) A method as claimed in claim 33, wherein the reactive compound is an amine, selected from a group made up of N,N,N′

,N′

-TetraMethylHexane-1,6-DiAmine (TMHDA), N,N-DiEthylEthanolAmine (DEEA), N,N,N′

,N′

-TetraEthyl-DiEthyleneTriAmine (TEDETA), N,N,N′

-TriEthylEthyleneDiAmine (TEEDA), N-DilsoPropy-lEthyleneDiAmine (DIPEDA), N,N,N′

,N′

-TetraMethylDiPropyleneTriAmine (TMDPTA), N,N,N′

,N′

,N″

-PentaMethylDiPropyleneTriAmine (PMDPTA).

46. ) A method as claimed in claim 16, wherein the gaseous effluent is selected from among natural gas, syngas, combustion fumes, blast furnace fumes, refinery gas such as syngas, cracked gas, fuel gas, acid gas from amine units, Claus tail gas, biomass fermentation gas, cement plant gas and incinerator fumes.

47. ) A method as claimed in claim 16, comprising capturing CO₂ contained in combustion fumes.

48. ) A method for deacidizing a gaseous effluent comprising acid compounds as claimed in claim 16 wherein:

the absorption column is used for contacting the gaseous effluent with an absorbent solution;

a separation means is used for separating the absorbent solution laden with acid compounds into a first liquid fraction of absorbent solution depleted of acid compounds and a second liquid fraction of absorbent solution enriched with acid compounds;

the regeneration column is used for releasing the acid compounds contained in the second liquid fraction and for producing a regenerated absorbent solution, the regeneration column being equipped with at least one reboiler for forming vapor through partial vaporization of a first part of the regenerated absorbent solution withdrawn from regeneration column, and the regeneration column comprises a liquid reserve in a bottom of the column bottom having at least a second part of the regenerated absorbent solution, and a vapor injector immersed in the liquid reserve for injecting the vapor into the reserve;

means for recycling recycles the first liquid fraction from the separation means and the regenerated absorbent solution from the regeneration column as the absorbent solution to the absorption column.

49. ) A method as claimed in claim 48, wherein a draw-off tray is positioned above the liquid reserve for collecting the first part of the regenerated absorbent solution, and a line with an inlet opening into a tray sends the first part of the solution to the reboiler.

50. ) A method as claimed in claim 48, wherein a main line connects the reboiler to the vapor injector for sending a first vapor stream into the liquid reserve, and a bypass line including a valve is disposed in a main line for sending a second vapor stream above the liquid reserve.

27. ) A method as claimed in 20, wherein the vapor is injected into the liquid reserve at a superficial velocity and the superficial velocity is controlled by separating the partly vaporized absorbent solution from the reboiler into a first stream forming the vapor injected into the liquid reserve and into a second vapor stream injected above the liquid reserve, and by controlling the first and second streams.