Gas Purification Method

• US 20160272908A1
• Filed: 03/18/2014
• Published: 09/22/2016
• Est. Priority Date: 03/19/2013
• Status: Active Grant

• Current Assignee: Osaka Gas Company Limited
• Original Assignee: Osaka Gas Company Limited
• Inventors: Seki, Kenji, Morita, Yuhei, Utaki, Takahisa, Kawashima, Shota
• Granted Patent: US 9,732,297 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/116 Molecular sieves other than zeolites
• CPC Class Codes: B01D 2256/245 Methane
• CPC Class Codes: B01D 2258/05 Biogas
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: B01J 20/28011 Other properties, e.g. density, crush strength
• CPC Class Codes: B01J 20/28069 Pore volume, e.g. total pore volume, mesopore volume, micropore volume
• CPC Class Codes: B01J 20/28071 being less than 0.5 ml/g
• CPC Class Codes: B01J 20/28078 Pore diameter
• CPC Class Codes: B01J 20/2808 being less than 2 nm, i.e. micropores or nanopores
• CPC Class Codes: B01J 20/3416 of sorbents or filter aids comprising free carbon, e.g. activated carbon
• CPC Class Codes: B01J 20/3491 by pressure treatment
• CPC Class Codes: C01B 32/306 with molecular sieve properties
• CPC Class Codes: C10L 2290/12 Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel
• CPC Class Codes: C10L 2290/542 Adsorption of impurities during preparation or upgrading of a fuel
• CPC Class Codes: C10L 3/101 Removal of contaminants
• CPC Class Codes: C10L 3/102 of acid contaminants

Abstract

The rate of recovery of a purification target gas from a gas purification apparatus that uses a PSA device is improved, and both a high purity and a high recovery rate are achieved with good power efficiency. The present invention is directed to a gas purification method using the PSA method, in which a carbon molecular sieve having a pore volume, at a pore diameter of 0.38 nm or more, of not exceeding 0.05 cm³/g and a pore volume, at a pore diameter of 0.34 nm, of 0.15 cm³/g or more, in a pore diameter distribution measured by the MP method is used as an adsorbent, and, in an adsorption step, a miscellaneous gas is adsorbed from a source gas by bringing the source gas into contact with the adsorbent for 10 seconds or more and 6000 seconds or less so as to obtain a concentrated methane.

Claims

1. A gas purification method comprising:

providing an adsorption tower filled with an adsorbent that adsorbs a miscellaneous gas other than methane from a source gas containing methane;

providing a source gas supply line for supplying the source gas to the adsorption tower;

providing a product gas recovery line for discharging methane that has not been adsorbed on the adsorbent as a product gas;

providing a miscellaneous gas discharge line for discharging desorbed miscellaneous gas that has been adsorbed on the adsorbent; and

alternately performing, with the adsorption tower, the source gas supply line, the product gas recovery line, and the miscellaneous gas discharge line,

an adsorption step of receiving the source gas into the adsorption tower from the source gas supply line, adsorbing the miscellaneous gas onto the adsorbent, and recovering the product gas into the product gas recovery line, and

a desorption step of depressurizing-desorbing the miscellaneous gas adsorbed on the adsorbent and discharging said miscellaneous gas from the miscellaneous gas discharge line in a state in which the source gas supply line and the product gas recovery line are closed,

wherein a carbon molecular sieve having

a pore volume (V_0.38), at a pore diameter of 0.38 nm or more, of not exceeding 0.05 cm³/g and

a pore volume (V_0.34), at a pore diameter of 0.34 nm, of 0.15 cm³/g or more, in a pore diameter distribution measured by the MP method is used as the adsorbent, and,

in the adsorption step, the miscellaneous gas is adsorbed from the source gas by bringing the source gas into contact with the adsorbent for 10 seconds or more and 6000 seconds or less so as to obtain a concentrated methane.

2. The gas purification method according to claim 1, wherein the adsorbent has a pore volume (V_0.38), at a pore diameter of 0.38 nm or more, of not exceeding 0.01 cm³/g and a pore volume (V_0.34), at a pore diameter of 0.34 nm, of 0.20 cm³/g or more.

3. The gas purification method according to claim 1, wherein the adsorbent has a particle diameter of 0.5 mmφ

to 3.0 mmφ

, and a packing density of the adsorbent for the adsorption tower is 0.60 g/mL to 0.75 g/mL.

4. The gas purification method according to claim 1, comprising:

prior to performing said gas purification method,

using a low-concentration methane-containing gas having a methane concentration of less than 50% as an upstream source gas;

providing an upstream adsorption tower filled with a methane adsorbent that adsorbs methane from the upstream source gas;

providing an upstream source gas supply line for supplying the upstream source gas to the upstream adsorption tower;

providing an upstream miscellaneous gas discharge line for discharging an upstream miscellaneous gas that has not been adsorbed on the methane adsorbent;

providing an upstream gas recovery line for recovering desorbed methane that has been adsorbed on the methane adsorbent; and

alternately performing, with the upstream adsorption tower, the upstream source gas supply line, the upstream miscellaneous gas discharge line, and the upstream gas recovery line,

an upstream adsorption step of receiving the upstream source gas from the upstream source gas supply line, adsorbing methane onto the methane adsorbent, and discharging the upstream miscellaneous gas that has not been adsorbed on the methane adsorbent; and

an upstream desorption step of desorbing methane adsorbed on the methane adsorbent and recovering said methane from the upstream gas recovery line, with the upstream source gas supply line and the upstream miscellaneous gas discharge line being closed,

thereby obtaining a gas recovered from the upstream gas recovery line as a source gas having a methane concentration of 50% or more.