SOUND ABSORBING AND INSULATING MATERIAL WITH SUPERIOR MOLDABILITY AND APPEARANCE AND METHOD FOR MANUFACTURING THE SAME

• US 20160297174A1
• Filed: 06/17/2016
• Published: 10/13/2016
• Est. Priority Date: 12/19/2013
• Status: Active Grant

• Current Assignee: Hyundai Motor Company (Hyundai Motor Group)
• Original Assignee: Hyundai Motor Company (Hyundai Motor Group)
• Inventors: Kim, Keun Young
• Granted Patent: US 10,304,437 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: B32B 1/00 Layered products having a non-planar shape
• CPC Class Codes: B32B 2250/20 All layers being fibrous or filamentary
• CPC Class Codes: B32B 2250/40 Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
• CPC Class Codes: B32B 2260/021 Fibrous or filamentary layer layers of natural mineral fibres or particles being impregnated in a plastic substance B32B19/02
• CPC Class Codes: B32B 2260/023 Two or more layers
• CPC Class Codes: B32B 2260/046 Synthetic resin
• CPC Class Codes: B32B 2262/0269 Aromatic polyamide fibres
• CPC Class Codes: B32B 2262/0276 Polyester fibres
• CPC Class Codes: B32B 2262/10 Inorganic fibres layered products comprising a layer of natural mineral fibres B32B19/00
• CPC Class Codes: B32B 2262/101 Glass fibres
• CPC Class Codes: B32B 2262/103 Metal fibres
• CPC Class Codes: B32B 2262/105 Ceramic fibres
• CPC Class Codes: B32B 2262/106 Carbon fibres, e.g. graphite fibres
• CPC Class Codes: B32B 2305/20 in the form of a non-woven mat
• CPC Class Codes: B32B 2307/102 Insulating
• CPC Class Codes: B32B 2307/304 Insulating
• CPC Class Codes: B32B 2307/3065 Flame resistant or retardant, fire resistant or retardant
• CPC Class Codes: B32B 2307/718 Weight, e.g. weight per square meter
• CPC Class Codes: B32B 2307/738 Thermoformability
• CPC Class Codes: B32B 2605/00 Vehicles
• CPC Class Codes: B32B 37/06 : characterised by the heating method
• CPC Class Codes: B32B 37/10 : characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
• CPC Class Codes: B32B 37/12 : characterised by using adhesives
• CPC Class Codes: B32B 37/14 : characterised by the properties of the layers
• CPC Class Codes: B32B 38/12 : Deep-drawing
• CPC Class Codes: B32B 5/022 : Non-woven fabric
• CPC Class Codes: B32B 5/26 : another layer next to it also being fibrous or filamentary relative arrangement of fibres or filaments of different layers B32B5/12
• CPC Class Codes: B32B 7/12 : using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: B60R 13/08 : Insulating elements, e.g. for sound insulation sound insulating linings for trains B61D17/185; drivers' cabs for load-carrying vehicles insulated against vibrations or noise B62D33/0604; thermal or acoustic insulation of engines F02B77/11; damping of sounds using compensation by electro-acoustic methods G10K11/178
• CPC Class Codes: D04H 1/4374 : using different kinds of webs, e.g. by layering webs
• CPC Class Codes: F16L 59/02 : Shape or form of insulating materials, with or without coverings integral with the insulating materials
• CPC Class Codes: G10K 11/168 : Plural layers of different materials, e.g. sandwiches

Abstract

The present invention relates to a sound absorbing and insulating material with superior moldability and appearance and a method for manufacturing the same, more particularly to a sound absorbing and insulating material consisting of an inner layer 1 formed of a first nonwoven fabric mainly formed of a heat-resistant fiber and a binder uniformly distributed inside the first nonwoven fabric and maintaining the three-dimensional structure inside the first nonwoven fabric and an outer layer 2′, 2″ formed of a second nonwoven fabric mainly formed of a heat-resistant fiber, wherein the outer layer is stacked on one or both sides of the inner layer, and a method for manufacturing the same. The sound absorbing and insulating material of the present invention has superior sound-absorbing property, flame retardancy, heat resistance, heat-insulating property and high-temperature moldability. In addition, there is no concern of deterioration of surface appearance caused by leakage of the binder due to the presence of the outer layer.

Claims

1. A sound absorbing and insulating material comprising:

an inner layer comprising a first nonwoven fabric comprising an amount of about 30 to 100 wt % of a heat-resistant fiber based on the total weight of the first nonwoven fabric and a binder present in the same layer as the first nonwoven fabric and maintaining a three-dimensional structure in the inner layer; and

an outer layer comprising a second nonwoven fabric comprising an amount of about 30 to 100 wt % of a heat-resistant fiber based on the total weight of the second nonwoven fabric,

wherein the outer layer is stacked on one or both sides of the inner layer.

2. The sound absorbing and insulating material according to claim 1, wherein the inner layer and the outer layer is stacked by an adhesive, heat or pressure.

3. The sound absorbing and insulating material according to claim 1, wherein an adhesive is coated on one side of the outer layer and then the outer layer is stacked by contacting the adhesive-coated side with the inner layer.

4. The sound absorbing and insulating material according to claim 3, wherein the adhesive used for the stacking between the inner layer and the outer layer is the same binder included in the first nonwoven fabric.

5. The sound absorbing and insulating material according to claim 4, wherein the adhesive is a thermosetting resin.

6. The sound absorbing and insulating material according to claim 1, wherein the heat-resistant fiber constituting the first nonwoven fabric or the second nonwoven fabric has a limiting oxygen index (LOI) of about 25% or greater and a heat resistance temperature of about 150°

C. or greater.

7. The sound absorbing and insulating material according to claim 6, wherein the heat-resistant fiber is one or more selected from a group consisting of an aramid fiber, a polyphenylene sulfide (PPS) fiber, an oxidized polyacrylonitrile (oxi-PAN) fiber, a polyimide (PI) fiber, a polybenzimidazole (PBI) fiber, a polybenzoxazole (PBO) fiber, a polytetrafluoroethylene (PTFE) fiber, a polyketone (PK) fiber, a metallic fiber, a carbon fiber, a glass fiber, a basalt fiber, a silica fiber and a ceramic fiber.

8. The sound absorbing and insulating material according to claim 7, wherein the heat-resistant fiber is an aramid fiber.

9. The sound absorbing and insulating material according to claim 1, wherein the first nonwoven fabric or the second nonwoven fabric comprises an aramid fiber having a fineness of about 1 to 15 denier and is a single-layered nonwoven fabric having a thickness of about 3 to 20 mm.

10. The sound absorbing and insulating material according to claim 1, wherein the first nonwoven fabric or the second nonwoven fabric has a density of about 100 to 2000 g/m².

11. The sound absorbing and insulating material according to claim 10, wherein the first nonwoven fabric or the second nonwoven fabric has a density of about 200 to 1200 g/m².

12. The sound absorbing and insulating material according to claim 1, wherein the inner layer is formed in a single layer or multiple layers.

13. The sound absorbing and insulating material according to claim 1, wherein the binder included in the inner layer is a thermosetting resin.

14. The sound absorbing and insulating material according to claim 5, wherein the thermosetting resin is an epoxy resin.

15. The sound absorbing and insulating material according to claim 14, wherein the epoxy resin is one or more epoxy resin selected from a group consisting of bisphenol A diglycidyl ether, bisphenol B diglycidyl ether, bisphenol AD diglycidyl ether, bisphenol F diglycidyl ether, bisphenol S diglycidyl ether, polyoxypropylene diglycidyl ether, a bisphenol A diglycidyl ether polymer, phosphazene diglycidyl ether, bisphenol A novolac epoxy, a phenol novolac epoxy resin and an o-cresol novolac epoxy resin.

16. The sound absorbing and insulating material according to claim 1, wherein the sound absorbing and insulating material is molded to have a three-dimensional shape corresponding to that to which the sound absorbing and insulating material is applied.

17. The sound absorbing and insulating material according to claim 16, wherein the sound absorbing and insulating material is for a vehicle.

18. A method for manufacturing the sound absorbing and insulating material according to claim 1, comprising:

a) immersing a first nonwoven fabric comprising an amount of about 30 to 100 wt % of a heat-resistant fiber based on the total weight of the first nonwoven fabric in a binder solution;

b) forming an inner layer by drying the first nonwoven fabric; and

c) preparing an outer layer by stacking a second nonwoven fabric comprising an amount about 30 to 100 wt % of a heat-resistant fiber based on the total weight of the first nonwoven fabric

d) stacking the outer layer on one or both sides of the inner layer.

19. The method for manufacturing the sound absorbing and insulating material according to claim 18, wherein which further comprises, after the step d), a step of e) molding the sound absorbing and insulating material at a temperature of about 150 to 300°

C.

20. The method for manufacturing the sound absorbing and insulating material according to claim 18, wherein in the step b), the first nonwoven fabric is dried at a temperature of about 70 to 200°

C. and the inner layer formed by the drying comprises an amount of about 1 to 300 parts by weight of a binder based on 100 parts by weight of the nonwoven fabric.

21. The method for manufacturing the sound absorbing and insulating material according to claim 18, wherein in the step d), the outer layer is stacked on the inner layer by an adhesive, heat or pressure.

22. The method for manufacturing the sound absorbing and insulating material according to claim 21, wherein in the step d), an adhesive is coated on one side of the second nonwoven fabric and the side on which the adhesive has been coated is contacted with the inner layer.

23. The method for manufacturing the sound absorbing and insulating material according to claim 22, wherein the adhesive is the same binder included in the first nonwoven fabric.

24. The method for manufacturing the sound absorbing and insulating material according to claim 23, wherein the adhesive is a thermosetting resin.

25. The method for manufacturing the sound absorbing and insulating material according to claim 18, wherein the heat-resistant fiber constituting the first nonwoven fabric or the second nonwoven fabric has a limiting oxygen index (LOI) of about 25% or greater and a heat resistance temperature of 150°

C. or greater.

26. The method for manufacturing the sound absorbing and insulating material according to claim 25, wherein the heat-resistant fiber is one or more selected from a group consisting of an aramid fiber, a polyphenylene sulfide (PPS) fiber, an oxidized polyacrylonitrile (oxi-PAN) fiber, a polyimide (PI) fiber, a polybenzimidazole (PBI) fiber, a polybenzoxazole (PBO) fiber, a polytetrafluoroethylene (PTFE) fiber, a polyketone (PK) fiber, a metallic fiber, a carbon fiber, a glass fiber, basalt fiber, a silica fiber and a ceramic fiber.

27. The method for manufacturing the sound absorbing and insulating material according to claim 25, wherein the heat-resistant fiber is an aramid fiber having a fineness of about 1 to 15 denier and a yarn length of about 20 to 100 mm.

28. The method for manufacturing the sound absorbing and insulating material according to claim 18, wherein the first nonwoven fabric or the second nonwoven fabric has a thickness of about 3 to 20 mm and a density of about 100 to 2000 g/m².

29. The method for manufacturing the sound absorbing and insulating material according to claim 28, wherein the first nonwoven fabric or the second nonwoven fabric is an aramid nonwoven fabric having a thickness of about 3 to 20 mm, formed by needle punching of a heat-resistant aramid fiber having a fineness of about 1 to 15 denier.

30. The method for manufacturing the sound absorbing and insulating material according to claim 29, wherein the nonwoven fabric is formed by continuously performing up-down needling, down-up needling and up-down needling.

31. The method for manufacturing the sound absorbing and insulating material according to claim 29, wherein the nonwoven fabric is formed with a needle stroke of about 30 to 350 times/m².

32. The method for manufacturing the sound absorbing and insulating material according to claim 18, wherein the binder solution comprises an amount of about 1 to 60 wt % of a binder, an amount of about 0.1 to 10 wt % of a curing agent, an amount of about 0.01 to 5 wt % of a catalyst, an amount of about 1 to 40 wt % of an additive and a solvent constituting the remaining balance of the binder solution, all the wt % based on the total weight of the binder solution.

33. The method for manufacturing the sound absorbing and insulating material according to claim 18, wherein the binder solution comprises an amount of about 1 to 30 wt % of a binder, an amount of about 0.1 to 10 wt % of a curing agent, an amount of about 0.01 to 5 wt % of a catalyst, an amount of about 1 to 30 wt % of a flame retardant and an amount of about 40 to 95 wt % of a solvent constituting the remaining balance of the binder solution, all the wt % based on the total weight of the binder solution.

34. The method for manufacturing the sound absorbing and insulating material according to claim 33, wherein the binder is a thermosetting resin.

35. The method for manufacturing the sound absorbing and insulating material according to claim 24, wherein the thermosetting resin is an epoxy resin.

36. The method for manufacturing the sound absorbing and insulating material according to claim 35, wherein the epoxy resin is one or more selected from a group consisting of bisphenol A diglycidyl ether, bisphenol B diglycidyl ether, bisphenol AD diglycidyl ether, bisphenol F diglycidyl ether, bisphenol S diglycidyl ether, polyoxypropylene diglycidyl ether, a bisphenol A diglycidyl ether polymer, phosphazene diglycidyl ether, bisphenol A novolac epoxy, a phenol novolac epoxy resin and an o-cresol novolac epoxy resin.

37. The method for manufacturing the sound absorbing and insulating material according claim 18, wherein the sound absorbing and insulating material is for a vehicle.

38. A method for reducing noise of a noise-generating device, comprising:

i) checking a three-dimensional shape of a noise-generating device;

ii) preparing and molding the sound absorbing and insulating material according to any of claim 1 so as to correspond to the three-dimensional shape of the device partially or entirely; and

iii) bringing the sound absorbing and insulating material adjacent to the noise-generating device.

39. The method for reducing noise of a noise-generating device according to claim 38, wherein the device is a motor, an engine or an exhaust system.

40. The method for reducing noise of a noise-generating device according to claim 39, wherein the sound absorbing and insulating material is brought adjacent to the noise-generating device by attaching the sound absorbing and insulating material to the noise-generating device, providing the sound absorbing and insulating material with a distance from the noise-generating device, or molding the sound absorbing and insulating material as a part of the noise-generating device.

41. A vehicle that comprises a sound absorbing and insulating material of claim 1.