DEGRADING AND REMOVING CURED RESINS FROM SUBSTRATES

• US 20160347987A1
• Filed: 02/27/2014
• Published: 12/01/2016
• Est. Priority Date: 02/27/2014
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Nguyen, Philip D., Sparks, Bradley J., Vo, Loan K.
• Granted Patent: US 10,150,906 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: C09K 8/524 organic depositions, e.g. paraffins or asphaltenes
• CPC Class Codes: E21B 37/00 Methods or apparatus for cleaning boreholes or wells E21B21/00 takes precedence
• CPC Class Codes: E21B 43/267 reinforcing fractures by propping

Abstract

Methods are provided for chemically removing cured resin product from surfaces and subterranean formations in case of inappropriate consolidation, plugging of screens or tubing, and equipment damage. A chemical solvent is introduced to a wellbore where a resin has cured. The resin is contacted with the chemical solvent until the resin at least partially dissolves. At least a portion of the dissolved resin is then removed from the wellbore.

Claims

1. A method comprising:

introducing a chemical solvent into a wellbore penetrating a portion of a subterranean formation wherein a resin has been at least partially cured;

wherein the chemical solvent is selected from the group consisting of β

-lactam, γ

-lactam, δ

-lactam, and ε

-lactam, 2-pyrrolidone, N-methylpyrrolidone (NMP), 1,3-dimethyl-2-imidazolidinone (DMI), caprolactam, cyclohexanone, cyclopentanone, any combination thereof, and any derivative thereof;

contacting the resin with the chemical solvent to at least partially dissolve the resin; and

circulating a fluid in the wellbore to remove at least a portion of the resin from the wellbore.

2. The method of claim 1 wherein the chemical solvent comprises N-methylpyrrolidone.

3. The method of claim 1 wherein the resin comprises a two-component epoxy resin.

4. The method of claim 1 wherein the resin is contacted with the chemical solvent for at least 30 minutes.

5. The method of claim 1 wherein the chemical solvent is introduced into the wellbore using a carrier fluid, wherein the chemical solvent is present in the carrier fluid in a range of about 0.5% to about 99%.

6. The method of claim 5 wherein the carrier fluid further comprises a pH-adjusting agent.

7. The method of claim 1 wherein the chemical solvent is introduced into the wellbore using one or more pumps.

8. A method comprising:

introducing a chemical solvent into a wellbore penetrating a consolidated portion of a subterranean formation that has been at least partially consolidated with a resin;

wherein the chemical solvent is selected from the group consisting of β

-lactam, γ

-lactam, δ

-lactam, and ε

-lactam, 2-pyrrolidone, N-methylpyrrolidone (NMP), 1,3-dimethyl-2-imidazolidinone (DMI), caprolactam, cyclohexanone, cyclopentanone, any combination thereof, and any derivative thereof;

contacting the consolidated portion of the subterranean formation with the chemical solvent to at least partially unconsolidate the consolidated portion of the subterranean formation.

9. The method of claim 8 wherein the chemical solvent comprises N-methylpyrrolidone.

10. The method of claim 8 wherein the resin comprises a two-component epoxy resin.

11. The method of claim 8 wherein the formation is contacted with the chemical solvent for at least 30 minutes.

12. The method of claim 8 wherein the chemical solvent is introduced into the wellbore using a carrier fluid, wherein the chemical solvent is present in the carrier fluid in a range of about 0.5% to about 99%.

13. The method of claim 12 wherein the carrier fluid further comprises a pH-adjusting agent.

14. The method of claim 8 wherein the chemical solvent is introduced into the wellbore using one or more pumps.

15. A method comprising:

introducing a chemical solvent into a subterranean formation containing a consolidated proppant pack;

wherein the consolidated proppant pack comprises a plurality of proppant particles and a resin, and wherein the resin has at least partially consolidated the proppant pack;

wherein the chemical solvent is selected from the group consisting of β

-lactam, γ

-lactam, δ

-lactam, and ε

-lactam, 2-pyrrolidone, N-methylpyrrolidone (NMP), 1,3-dimethyl-2-imidazolidinone (DMI), caprolactam, cyclohexanone, cyclopentanone, any combination thereof, and any derivative thereof; and

contacting the consolidated proppant pack with the chemical solvent to at least partially unconsolidate the consolidated proppant pack.

16. The method of claim 15 wherein the consolidated proppant pack comprises an excess of resin that restricts a flow path between the proppant particulates.

17. The method of claim 15 wherein the chemical solvent comprises N-methylpyrrolidone.

18. The method of claim 15 wherein the resin comprises a two-component epoxy resin.

19. The method of claim 15 wherein the chemical solvent is introduced into the subterranean formation using a carrier fluid, wherein the chemical solvent is present in the carrier fluid in a range of about 0.5% to about 99%.

20. The method of claim 19 wherein the carrier fluid further comprises a pH-adjusting agent.