Process and Apparatus for the Production of Para-xylene

• US 20170050899A1
• Filed: 11/08/2016
• Published: 02/23/2017
• Est. Priority Date: 04/30/2015
• Status: Active Grant

• Current Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Chemical Patents Inc. (Exxon Mobil Corporation)
• Inventors: Tinger, Robert G., Pilliod, Dana L., Molinier, Michel
• Granted Patent: US 10,059,644 B2
• Time in Patent Office: Days
• US Class Current: 1/1
• CPC Class Codes: B01D 15/185 characterized by the components to be separated
• CPC Class Codes: B01D 3/14 Fractional distillation or use of a fractionation or rectification column
• CPC Class Codes: B01D 3/141 where at least one distillation column contains at least one dividing wall
• CPC Class Codes: B01D 3/143 by two or more of a fractionation, separation or rectification step
• CPC Class Codes: B01J 19/2445 placed in parallel
• CPC Class Codes: B01J 2219/00006 Large-scale industrial plants
• CPC Class Codes: B01J 2219/24 Stationary reactors without moving elements inside
• CPC Class Codes: C07C 5/2729 Changing the branching point of an open chain or the point of substitution on a ring
• CPC Class Codes: C07C 5/2767 Changing the number of side-chains

Abstract

The present invention is an improved process and apparatus for producing para-xylene, particularly with respect to a process that involves the methylation of toluene and/or benzene to selectively produce para-xylene, wherein streams having differing amounts of ethylbenzene are separately treated in the recovery of para-xylene. A first hydrocarbon feed comprising xylenes and ethylbenzene is provided to a first para-xylene adsorption section, and a second hydrocarbon feed comprising xylenes and less EB than the first hydrocarbon feed is provided to a second para-xylene adsorption section. Segregating the feeds with differing ethylbenzene contents increases the overall efficiency of the adsorption of para-xylene by the adsorption units. Efficiency and energy savings may be further improved by subjecting the lower-content ethylbenzene stream to liquid phase isomerization.

Claims

1-15. -15. (canceled)

16. An apparatus for the production of para-xylene comprising:

a first para-xylene adsorption section, which produces a first para-xylene-rich stream and a first para-xylene-depleted stream from a first hydrocarbon feed, and a second para-xylene adsorption section, which produces a second para-xylene-rich stream and a second para-xylene-depleted stream from a second hydrocarbon feed, the first and second para-xylene adsorption sections fluidly connected to a divided wall raffinate column in which the first and second para-xylene-depleted streams are provided to opposite sides of the dividing wall and separated into an ethylbenzene-rich stream, which contains a majority portion of the ethylbenzene from the first and second para-xylene-depleted streams, and an ethylbenzene-depleted stream, which contains a minor portion of the ethylbenzene from the first and second para-xylene-depleted streams;

a vapor phase isomerization unit fluidly connected to the divided wall raffinate column to isomerize meta-xylene, ortho-xylene, and ethylbenzene in the ethylbenzene-rich stream at least partially in the vapor phase back towards to an equilibrium concentration of xylene isomers and produce a first isomerized stream having a higher para-xylene concentration than the first and second para-xylene-depleted streams; and

a liquid phase isomerization unit fluidly connected to the divided wall raffinate column to isomerize the ethylbenzene-depleted stream back towards an equilibrium concentration of the xylenes isomers and produce a second isomerized stream having a higher para-xylene concentration than the first and second para-xylene-depleted streams.

17. The apparatus of claim 16, wherein the first and second para-xylene adsorption sections each comprise two simulated moving bed adsorption towers.

18. The apparatus of claim 16, wherein the first and second para-xylene adsorption sections each comprise one simulated moving bed adsorption tower.

19. The apparatus of claim 16, further comprising:

a first xylenes fractionation column fluidly connected to the vapor phase isomerization unit and the first para-xylene adsorption section, wherein the first xylenes fractionation column is downstream of the vapor phase isomerization unit and upstream of the first para-xylene adsorption section; and

a second xylenes fractionation column fluidly connected to the liquid phase isomerization unit and the second para-xylene adsorption section, wherein the second xylenes fractionation column is downstream of the liquid phase isomerization unit and upstream of the second para-xylene adsorption section.

20. The apparatus of claim 19, further comprising a detoluenizing fractionation column fluidly connected to the vapor phase isomerization unit and the first xylenes fractionation column, wherein the detoluenizing fractionation column is downstream of the vapor phase isomerization unit and upstream of the first xylenes fractionation column.