PROCESS OF FORMING ELECTRODES AND PRODUCTS THEREOF FROM BIOMASS

• US 20170084924A1
• Filed: 09/23/2016
• Published: 03/23/2017
• Est. Priority Date: 09/23/2015
• Status: Active Grant

• Current Assignee: University of Virginia Patent Foundation (University of Virginia)
• Original Assignee: University of Virginia Patent Foundation (University of Virginia)
• Inventors: Li, Xiaodong, Gao, Zan, Zhang, Yunya
• Granted Patent: US 10,446,329 B2
• Time in Patent Office: Days
• CPC Class Codes: B05D 1/18 performed by dipping
• CPC Class Codes: B05D 3/007 After-treatment
• CPC Class Codes: B05D 7/54 No clear coat specified
• CPC Class Codes: H01G 11/26 characterised by their structure, e.g. multi-layered, porosity or surface features
• CPC Class Codes: H01G 11/36 Nanostructures, e.g. nanofibres, nanotubes or fullerenes
• CPC Class Codes: H01G 11/40 Fibres
• CPC Class Codes: H01G 11/46 Metal oxides
• CPC Class Codes: H01G 11/86 specially adapted for electrodes carbonisation or activation of carbon for the manufacture of electrodes H01G11/34
• CPC Class Codes: H01M 4/0416 involving impregnation with a solution, dispersion, paste or dry powder H01M4/0438 takes precedence
• CPC Class Codes: H01M 4/0471 involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: H01M 4/5815 Sulfides
• CPC Class Codes: H01M 4/5825 Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
• CPC Class Codes: H01M 4/625 Carbon or graphite
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

A flexible electrode comprises an activated cotton textile composite comprising activated carbon fibers, nickel sulfide nanoparticles and graphene and a process for making the flexible electrode. The process may comprise preparing a cotton textile containing Ni(NO₃)₂. Then, the cotton textile containing Ni(NO₃)₂ may be heated at a first temperature to produce an activated cotton textile composite comprising activated carbon fibers, nickel nanoparticles and graphene. The activated cotton textile composite may be then treated with sulfur to produce an activated cotton textile composite comprising activated carbon fibers, nickel sulfide nanoparticles and graphene. The nickel sulfide particles may be NiS₂ nanoparticles in a form of nanobowls, and distributed on a surface and inside the activated carbon fibers. The activated carbon fibers and the nickel sulfide nanoparticles may be coated with graphene. Banana peels may be activated and treated with the similar processes to form electrodes for both supercapacitor and battery applications.

Claims

1. A process for making a flexible electrode, comprising

preparing a cotton textile containing Ni(NO₃)₂;

heating the cotton textile containing Ni(NO₃)₂ at a first temperature to produce an activated cotton textile composite comprising activated carbon fibers, nickel nanoparticles and graphene; and

treating the activated cotton textile composite comprising activated carbon fibers, nickel nanoparticles and graphene with sulfur to produce an activated cotton textile composite comprising activated carbon fibers, nickel sulfide nanoparticles and graphene.

2. The process of claim 1, wherein the activated carbon fibers have a tubular structure.

3. The process of claim 1, wherein the cotton textile containing Ni(NO₃)₂ is prepared by dipping a cotton textile into a Ni(NO₃)₂ solution.

4. The process of claim 3, wherein a concentration of the Ni(NO₃)₂ solution is in a range of 0.01 M to 1M.

5. The process of claim 3, wherein the cotton textile is dipped into the Ni(NO₃)₂ solution for at least 10 minutes.

6. The process of claim 1, wherein the cotton textile containing Ni(NO₃)₂ is heated at the first temperature within a range of 900 to 1000°

C. .

7. The process of claim 4, wherein the cotton textile containing Ni(NO₃)₂ is heated at the first temperature under an inert environment for a time within a range of 60 to 90 minutes.

8. The process of claim 1, wherein the treating step comprises:

coating the activated cotton textile composite comprising activated carbon fibers, nickel nanoparticles and graphene with a layer of sulfur;

heating the activated carbon textile composite at a second temperature to produce the activated cotton textile composite comprising activated carbon fibers, nickel sulfide nanoparticles and graphene.

9. The process of claim 8, wherein the coating of the cotton textile composite is performed by dropping a solution comprising sulfur onto a surface of the activated cotton textile composite comprising activated carbon fibers, nickel nanoparticles and graphene.

10. The process of claim 8, wherein an amount of the sulfur is at least two times of an amount of nickel by weight on the coated activated cotton textile composite comprising activated carbon fibers, nickel nanoparticles and graphene.

11. The process of claim 8, wherein the activated carbon textile composite is heated at the second temperature within a range of 900 to 1000°

C. for a time within a range of 60 to 90 minutes.

12. The process of claim 1, wherein the nickel sulfide particles are NiS₂ nanoparticles.

13. The process of claim 11, wherein the NiS₂ particles are in a form of nanobowls.

14. An activated cotton textile composite, comprising

an activated cotton textile composed of activated carbon fibers;

nickel sulfide nanoparticles;

and graphene.

15. The activated cotton textile composite of claim 14, wherein the nickel sulfide nanoparticles are distributed on a surface and inside the activated carbon fibers, and the activated carbon fibers and the nickel sulfide nanoparticles are coated with graphene.

16. The activated cotton textile composite of claim 14, wherein the activated carbon fibers have a tubular structure.

17. The activated cotton textile composite of claim 14, wherein the nickel sulfide nanoparticles are NiS₂ nanoparticles.

18. The activated cotton textile composite of claim 17, wherein the NiS₂ nanoparticles are in a form of nanobowls.

19. The activated cotton textile composite of claim 17, wherein the NiS₂ particles have an average size of about 50 to 200 nm.

20. The activated cotton textile composite rode of claim 14, wherein the activated cotton textile composite has a BET surface area of at least 528 m²g⁻

1.

21. The activated cotton textile composite of claim 14, wherein the activated cotton textile composite has pores having a size distribution ranging from 2 to 32 nm, and an average pore radius of about 5 to 15 nm.

22. The activated cotton textile composite of claim 14, wherein an amount of the nickel sulfide nanoparticles and the graphene on the activated cotton textile composite is in a range of 25 to 30 percent by weight.

23. A flexible electrode comprising the activated cotton textile composite of claim 14.

24. The flexible electrode of claim 23, wherein the flexible electrode has an initial discharge capacity of at least 1710 mAh g⁻

1 at a rate of 0.01 C, a discharge capacitance of at least 608 mAh g<sup>−

1</sup> after 100 cycles at a rate of 1 C, and a recovered discharge capacitance of at least 1016 mAh g<sup>−

1</sup> after 400 cycles at a rate of 0.1 C.

25. A flexible battery employing the flexible electrode of claim 23.