Method of Designing Electroluminescent Device, Electroluminescent Device Manufactured with the Design Method, and Method of Manufacturing Electroluminescent Device with the Design Method

• US 20170179443A1
• Filed: 06/02/2015
• Published: 06/22/2017
• Est. Priority Date: 06/20/2014
• Status: Active Grant

• Current Assignee: Merck Patent GmbH (Merck & Co., Inc.)
• Original Assignee: Konica Minolta Inc.
• Inventors: SEKINE, Koujirou, OSAWA, Kou, YOKOYAMA, Mitsuru
• Granted Patent: US 9,893,324 B2
• Time in Patent Office: Days
• CPC Class Codes: G06F 2119/18 Manufacturability analysis or optimisation for manufacturability
• CPC Class Codes: G06F 30/398 Design verification or optimisation, e.g. using design rule check [DRC], layout versus schematics [LVS] or finite element methods [FEM] optical proximity correction [OPC] design processes G03F1/36
• CPC Class Codes: H01L 2933/0025 relating to coatings
• CPC Class Codes: H01L 2933/0058 relating to optical field-shaping elements
• CPC Class Codes: H01L 2933/0091 Scattering means in or on the semiconductor body or semiconductor body package H01L33/22 takes precedence
• CPC Class Codes: H01L 33/44 characterised by the coatings, e.g. passivation layer or anti-reflective coating
• CPC Class Codes: H01L 33/58 Optical field-shaping elements
• CPC Class Codes: H10K 2102/3026 Top emission
• CPC Class Codes: H10K 2102/3031 Two-side emission, e.g. transparent OLEDs [TOLED]
• CPC Class Codes: H10K 2102/351 Thickness
• CPC Class Codes: H10K 50/816 Multilayers, e.g. transparent multilayers
• CPC Class Codes: H10K 50/852 comprising a resonant cavity structure, e.g. Bragg reflector pair
• CPC Class Codes: H10K 50/854 comprising scattering means
• CPC Class Codes: H10K 50/858 comprising refractive means, e.g. lenses
• CPC Class Codes: H10K 71/00 Manufacture or treatment specially adapted for the organic devices covered by this subclass
• CPC Class Codes: H10K 71/70 Testing, e.g. accelerated lifetime tests

Abstract

A method of designing an electroluminescent device allows more accurate computation of an external emission spectrum output to the outside in a current injection state and accurate estimate of a quantity and/or a color of light extracted to the outside, an electroluminescent device manufactured with the design method, and a method of manufacturing an electroluminescent device with the design method.

Claims

1. A method of designing an electroluminescent device having an emissive layer between a first electrode and a second electrode, the first electrode and the second electrode being transparent electrodes, the emissive layer lying between a first functional layer and a second functional layer, the electroluminescent device having a first transparent member on a side of the first electrode opposite to a side where the emissive layer is provided, the method comprising:

preparing a reference device including a construction of the electroluminescent device and a desired analyzed device including a construction of the electroluminescent device;

performing quantum optical analysis, electromagnetic analysis, and ray trace with thicknesses and complex relative permittivities of the first transparent member, the first electrode, the first functional layer, the second functional layer, the emissive layer, and the second electrode as well as a position of a light-emitting point in the emissive layer and a distribution of light-emitting points in the emissive layer being used as design variables;

calculating a “

ratio of light extraction efficiency”

between the reference device and the analyzed device by computing efficiency of light extraction from the emissive layer into the transparent member or air in both of the reference device and the analyzed device;

finding relation of the thickness and the complex relative permittivity of each of the layers with the “

ratio of light extraction efficiency,”

the layers forming the reference device and the analyzed device; and

obtaining the respective thicknesses and the respective complex relative permittivities of the first transparent member, the first electrode, the first functional layer, the second functional layer, the emissive layer, and the second electrode as the design variables, based on the relation and an electroluminescence spectrum in air or the first transparent member measured by feeding a current to the reference device.

2. The method of designing an electroluminescent device according to claim 1, wherein

the second electrode is a transparent electrode, a second transparent member is provided on a side of the second electrode opposite to a side where the emissive layer is provided, and a complex relative permittivity and a thickness of the second transparent member are further included as design variables.

3. The method of designing an electroluminescent device according to claim 2, wherein

an optical buffer layer is further provided between the second electrode and the first transparent member and/or between the second electrode and the second transparent member, and

the method further comprises designing a thickness, a complex relative permittivity, and a structure constant of each film forming the optical buffer film as design variables.

4. The method of designing an electroluminescent device according to claim 1, wherein

a first optical microstructure disturbing amplitude and a phase condition of light is further provided in any region between the transparent member and the emissive layer, and

the method further comprises designing a structure constant and a complex relative permittivity of the first optical microstructure as design variables.

5. The method of designing an electroluminescent device according to claim 1, wherein

a second optical microstructure disturbing amplitude and a phase condition of light is provided at an interface between the first transparent member and outside, and

a structure constant and a complex relative permittivity of the second optical microstructure are included as design variables.

6. An electroluminescent device designed with the method of designing an electroluminescent device according to claim 1.

7. A method of manufacturing an electroluminescent device comprising:

inspecting an electroluminescent device manufactured based on the design variables obtained with the method of designing an electroluminescent device according to claim 1 and measuring and analyzing current drive characteristics; and

obtaining the design variables with the method of designing an electroluminescent device according to claim 1 with the measured and analyzed electroluminescent device being defined as the reference device and manufacturing an electroluminescent device based on the design variables.