Combination of Novel Nitrification Inhibitors and Biopesticides as Well as Combination of (Thio)Phosphoric Acid Triamides and Biopesticides

• US 20170181435A1
• Filed: 04/16/2015
• Published: 06/29/2017
• Est. Priority Date: 04/17/2014
• Status: Active Grant

• Current Assignee: BASF SE
• Original Assignee: BASF SE
• Inventors: Wissemeier, Alexander, Sisay, Mihiret Tekeste, Dickhaut, Joachim, Nave, Barbara, Zerulla, Wolfram, Pasda, Gregor, Schmid, Markus
• Granted Patent: US 9,968,092 B2
• Time in Patent Office: Days
• CPC Class Codes: A01N 31/14 Ethers
• CPC Class Codes: A01N 57/28 containing acyclic or cycloaliphatic radicals
• CPC Class Codes: A01N 63/20 Bacteria; Substances produced thereby or obtained therefrom
• CPC Class Codes: A01N 63/22 Bacillus
• CPC Class Codes: A01N 63/23 B. thuringiensis
• CPC Class Codes: A01N 63/25 Paenibacillus
• CPC Class Codes: A01N 63/27 Pseudomonas
• CPC Class Codes: A01N 63/28 Streptomyces
• CPC Class Codes: A01N 63/30 Microbial fungi; Substances produced thereby or obtained therefrom
• CPC Class Codes: A01N 63/32 Yeast
• CPC Class Codes: A01N 63/34 Aspergillus
• CPC Class Codes: A01N 63/36 Penicillium
• CPC Class Codes: A01N 63/38 Trichoderma
• CPC Class Codes: A01N 63/40 Viruses, e.g. bacteriophages
• CPC Class Codes: Y02P 60/21 Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

Abstract

A composition including (a) at least one (thio)phosphoric acid triamide (T) according to the general formula (Ia)

R^a1R^a2N—P(X)(NH₂)₂  (Ia)

wherein X is oxygen or sulfur; R^a1 is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl, or dialkylaminocarbonyl group; R^a2 is H, or R^a1 and R^a2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur; and (b) at least one biopesticide.

Claims

1. A composition comprising:

a) at least one (thio)phosphoric acid triamide (T) according to the general formula (Ia)

R^a1R^a2N—

P(X)(NH₂)₂ 

 

(Ia)

wherein

X is oxygen or sulfur;

R^a1 is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl, or dialkylaminocarbonyl group;

R^a2 is H, or

R^a1 and R^a2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur,

and

b) at least one biopesticide.

2. The composition according to claim 1, wherein the biopesticide (L) is selected from the group consisting of (L1), (L3), (L5), (L7) and (L8), wherein:

(L1) comprises microbial pesticides having at least one of fungicidal, bactericidal, viricidal and plant defense activator activity selected from the group consisting of;

(L11) Ampelomyces quisqualis,

(L12) Aspergillus flavus,

(L13) Aureobasidium pullulans,

(L14) Bacillus amyloliquefaciens,

(L15) Bacillus mojavensis,

(L16) Bacillus pumilus,

(L17) Bacillus simplex,

(L18) Bacillus solisalsi,

(L19) Bacillus subtilis,

(L20) Bacillus subtilis var. amyloliquefaciens,

(L21) Candida oleophila, or C. saitoana,

(L22) Clavibacter michiganensis (bacteriophages),

(L23) Coniothyrium minitans,

(L24) Cryphonectria parasitica,

(L25) Cryptococcus albidus,

(L26) Dilophosphora alopecuri,

(L27) Fusarium oxysporum,

(L28) Clonostachys rosea f. catenulate (also named Gliocladium catenulatum),

(L29) Gliocladium roseum,

(L30) Lysobacter antibioticus, or L. enzymogenes,

(L31) Metschnikowia fructicola,

(L32) Microdochium dimerum,

(L33) Microsphaeropsis ochracea,

(L34) Muscodor albus,

(L35) Paenibacillus polymyxa,

(L36) Pantoea vagans,

(L37) Phlebiopsis gigantea,

(L38) Pseudomonas sp., or Pseudomonas chloraphis,

(L39) Pseudozyma flocculosa,

(L40) Pichia anomala,

(L41) Pythium oligandrum,

(L42) Sphaerodes mycoparasitica,

(L43) Streptomyces griseoviridis, S. lydicus, or S.violaceusniger,

(L44) Talaromyces flavus,

(L45) Trichoderma asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum, T. harzianum, T. stromaticum, T. virens (also named Gliocladium virens), T. viride, or mixture of T. harzianum and T. viride, or mixture of T. polysporum and T. harzianum,

(L46) Typhula phacorrhiza,

(L47) Ulocladium oudemansii,

(L48) Verticillium dahlia, and

(L49) zucchini yellow mosaic virus (avirulent strain);

(L3) comprises microbial pesticides with at least one of insecticidal, acaricidal, molluscidal and nematicidal activity selected from the group consisting of;

(L51) Agrobacterium radiobacter,

(L52) Bacillus cereus,

(L53) Bacillus firmus,

(L54) Bacillus thuringiensis, B. t. ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, or B. t. ssp. tenebrionis,

(L55) Beauveria bassiana, or B. brongniartii,

(L56) Burkholderia sp.,

(L57) Chromobacterium subtsugae,

(L58) Cydia pomonella granulosis virus,

(L59) Cryptophlebia leucotreta granulovirus (CrleGV),

(L60) Isaria fumosorosea,

(L61) Heterorhabditis bacteriophora,

(L62) Lecanicillium longisporum, or L. muscarium (formerly Verticillium lecanii),

(L63) Metarhizium anisopliae, or M. anisopliae var. acridum,

(L64) Nomuraea rileyi,

(L65) Paecilomyces fumosoroseus, or P. lilacinus,

(L66) Paenibacillus popilliae,

(L67) Pasteuria spp., P. nishizawae, P. penetrans, P. ramose, P. reneformis, P. thornea, or P. usgae,

(L68) Pseudomonas fluorescens, and

(L69) Steinernema carpocapsae, S. feltiae, or S. kraussei;

(L5) comprises microbial pesticides with at least one of plant stress reducing, plant growth regulator, plant growth promoting and yield enhancing activity selected from the group consisting of;

(L81) Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, or A. halopraeferens,

(L82) Bradyrhizobium sp., B. elkanii, B. japonicum, B. liaoningense, or B. lupini,

(L83) Delftia acidovorans,

(L84) VA mycorrhiza selected from the genera Glomus, Acaulospora, Entrophosphora, Gigaspora, Scutellospora and Sclerocytis,

(L85) VA mycorrhiza selected from the group consisting of Glomus fasciculatum, G. caledonium, G. mosseae, G. versiforme, G. intraradices and G. etunicatum,

(L86) Mesorhizobium sp.,

(L87) Paenibacillus alvei,

(L88) Penicillium bilaiae,

(L89) Rhizobium leguminosarum by. phaseoli, R. I. trifolii, R. I. by. viciae, or R. tropici,

(L90) Sinorhizobium meliloti,

(L91) Enterobacter spp., E. ludwigii, E. aerogenes, E. amnigenus, E. agglomerans, E. arachidis, E. asburiae, E. cancerogenous, E. cloacae, E. cowanii, E. dissolvens, E. gergoviae, E. helveticus, E. hormaechei, E. intermedius, E. kobei, E. mori, E. nimipressuralis, E. oryzae, E. pulveris, E. pyrinus, E. radicincitans, E. taylorae, E. turicensis, or E. sakazakii, and

(L92) Oxalobacteraceae spp., Herbaspirillum seropedicae (DSM No.;

     6445) (free-living nitrogen fixing bacterium), Janthinobacterium lividum (DSM No.;

     1522) (violacein-producing bacterium), or Pseudoduganella violaceinigra (DSM No.;

     15887) (violacein-producing bacterium);

(L7) comprises metabolites produced by the microbial pesticides selected from the group consisting of;

(L93) siderophores, bacillibactin

(L94) antibiotiics such as zwittermicin-A, kanosamine, polyoxine, bacilysin, violacein

(L95) enzymes such as alpha-amylase, chitinases, pektinases, phosphatase (acid and alkaline) and phytase

(L96) phytohormones and precursors thereof and volatile compounds, such as auxines, gibberellin-like substances, cytokinin-like compounds, acetoin, 2,3-butanediol, ethylene, indole acetic acid,

(L97) lipopeptides such as iturins, plipastatins, surfactins, agrastatin, agrastatin A, bacillomycin, bacillomycin D, fengycin,

(L98) antibacterial polyketides such as difficidin, macrolactin and bacilaene, and

(L99) antifungal metabolites such as pyrones, cytosporone, 6-pentyl-2H-pyran-2-one (also termed 6-pentyl-a-pyrone), koninginins (complex pyranes), in particular those metabolites produced by Trichoderma species, and

(L8) comprises biochemical pesticides with at least one of insecticidal, acaricidal, molluscidal, pheromone and nematicidal activity selected from the group consisting of;

L-carvone, citral, (E,Z)-7,9-dodecadien-1-yl acetate, ethyl formate, (E,Z)-2,4-ethyl decadienoate (pear ester), (Z,Z,E)-7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulyl senecioate, cis-jasmone (B.27), 2-methyl 1-butanol, methyl eugenol, methyl jasmonate (B.28), (E,Z)-2,13-octadecadien-1-ol, (E,Z)-2,13-octadecadien-1-ol acetate, (E,Z)-3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E,Z,Z)-3,8,11-tetradecatrienyl acetate, (Z,E)-9,12-tetradecadien-1-yl acetate, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecen-1-ol, Acacia negra extract, extract of grapefruit seeds and pulp, extract of Chenopodium ambrosiodes, Catnip oil, Neem oil (B.29), Quillay extract (B.30), and Tagetes oil.

3. The composition according to claim 1, wherein in the general formula (Ia) of (T) X is sulfur and wherein in the general formula (Ia) of (T) R^a1 is C₁-C₂₀ alkyl and R^a2 is H.

4. The composition according to claim 1, wherein the (thio)phosphoric acid triamide (T) is one of N-n-butylthiophosphoric acid triamide (NBPT) and N-n-propylthiophosphoric acid triamide (NPPT).

5. The composition according to claim 1, wherein the biopesticide is selected from the group consisting of Azospirillum brasilense XOH (B.1), A. brasilense BR 11002 (B.2), A. brasilense BR 11005 (B.3), A. brasilense strains Ab-V5 and Ab-V6 (B.4), Bacillus amyloliquefaciens FZB42 (B.5), B. amyloliquefaciens IN937a (B.6), B. amyloliquefaciens IT-45 (B.7), B. amyloliquefaciens TJ1000 (B.8), B. amyloliquefaciens ssp. plantarum MBI600 (B.9), B. cereus CNCM I1562 (B.10), B. firmus CNCM 1-1582 (B.11), Bacillus pumilus KFP9F (B.12), B. pumilus QST 2808 (B.13), Bradyrhizobium japonicum (B.14), Coniothyrium minitans CON/M/91-08 (B.15), Pasteuria nishizawae Pn1 (B.16), Penicillium bilaiae (B.17), P. fluorescens CL 145A (B.18), Rhizobium leguminosarum by. Phaseoli (B.19), R. I. by. trifolii RP113-7 (B.20), R. I. by. viciae P1NP3Cst (B.21), R. I. by. viciae SU303 (B.22), R. I. by. viciae WSM1455 (B.23), R. tropici SEMIA 4080 (B.24), Sinorhizobium meliloti MSDJ0848 (B.25), Trichoderma fertile JM41R (B.26), cis-jasmone (B.27), methyl jasmonate (B.28), and Neem oil (B.29).

6. The composition according to claim 1, wherein the biopesticide is selected from the group consisting of:

(L14) Bacillus amyloliquefaciens,

(L16) Bacillus pumilus,

(L17) Bacillus simplex,

(L19) Bacillus subtilis, and

(L20) Bacillus subtilis var. amyloliquefaciens.

10. A method for at least one of increasing the health of a plant and increasing the biopesticidal activity of the biopesticide, the method comprising using the composition of claim 1.

26. The composition according to claim 1, wherein in the general formula (Ia) of (T) X is sulfur.

27. The composition according to claim 1, wherein in the general formula (Ia) of (T) R^a1 is C₁-C₂₀ alkyl and R^a2 is H.

7. A method for increasing the health of a plant, comprising treating at least one of (a) a plant growing on at least one of soil and soil substituents and (b) at least one of the locus, soil, and soil substituents where the plant is at least one of growing or is intended to grow, with

a) at least one (thio)phosphoric acid triamide (T) according to the general formula (Ia)

R^a1R^a2N-P(X)(NH₂)₂ 

 

(Ia)

wherein

X is oxygen or sulfur;

R^a1 is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl, or dialkylaminocarbonyl group;

R^a2 is H, or

R^a1 and R^a2 together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur,

and

b) at least one biopesticide.

8. The method according to claim 7, wherein the biopesticide is selected from the group consisting of:

Azospirillum brasilense XOH (B.1), A. brasilense BR 11002 (B.2), A. brasilense BR 11005 (B.3), A. brasilense strains Ab-V5 and Ab-V6 (B.4), Bacillus amyloliquefaciens FZB42 (B.5), B. amyloliquefaciens IN937a (B.6), B. amyloliquefaciens IT-45 (B.7), B. amyloliquefaciens TJ1000 (B.8), B. amyloliquefaciens ssp. plantarum MBI600 (B.9), B. cereus CNCM 1-1562 (B.10), B. firmus CNCM 1-1582 (B.11), Bacillus pumilus KFP9F (B.12), B. pumilus QST 2808 (B.13), Bradyrhizobium japonicum (B.14), Coniothyrium minitans CON/M/91-08 (B.15), Pasteuria nishizawae Pn1 (B.16), Penicillium bilaiae (B.17), P. fluorescens CL 145A (B.18), Rhizobium leguminosarum by. Phaseoli (B.19), R. I. by. trifolii RP113-7 (B.20), R. I. by. viciae P1NP3Cst (B.21), R. I. by. viciae SU303 (B.22), R. I. by. viciae WSM1455 (B.23), R. tropici SEMIA 4080 (B.24), Sinorhizobium meliloti MSDJ0848 (B.25), Trichoderma fertile JM41R (B.26), cis-jasmone (B.27), methyl jasmonate (B.28), and Neem oil (B.29).

9. The method according to claim 7, wherein the application of the (thio)phosphoric acid triamide (T) and of the biopesticide is carried out simultaneously or with a time lag.

28. The method according to claim 7 further comprising providing the plant with a urea containing fertilizer.

29. The method according to claim 7, wherein the application of the (thio)phosphoric acid triamide (T), of the biopesticide, and of the urea-containing fertilizer is carried out simultaneously or with a time lag.

30. The method according to claim 29, wherein the time lag is an interval selected from the group consisting of 1 day, 2 days, 3 days, 1 week, 2 weeks or 3 weeks.

31. The method according to claim 9, wherein the time lag is an interval selected from the group consisting of 1 day, 2 days, 3 days, 1 week, 2 weeks or 3 weeks.

11-25. -25. (canceled)