METHOD FOR ANALYZING NITROGEN IN METAL SAMPLE, APPARATUS FOR ANALYZING NITROGEN IN METAL SAMPLE, METHOD FOR ADJUSTING NITROGEN CONCENTRATION IN MOLTEN STEEL, AND METHOD FOR MANUFACTURING STEEL

• US 20170199129A1
• Filed: 05/14/2015
• Published: 07/13/2017
• Est. Priority Date: 07/09/2014
• Status: Active Grant

• Current Assignee: JFE Steel Corporation (JFE Holdings Incorporated)
• Original Assignee: JFE Steel Corporation (JFE Holdings Incorporated)
• Inventors: Inose, Masao, Kinoshiro, Satoshi
• Granted Patent: US 10,641,711 B2
• Time in Patent Office: Days
• CPC Class Codes: B22D 11/001 of specific alloys
• CPC Class Codes: B22D 11/108 Feeding additives, powders, or the like
• CPC Class Codes: B22D 11/11 Treating the molten metal
• CPC Class Codes: B22D 11/16 Controlling or regulating processes or operations
• CPC Class Codes: C21C 7/10 Handling in a vacuum
• CPC Class Codes: C22C 38/002 containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
• CPC Class Codes: C22C 38/02 containing silicon
• CPC Class Codes: C22C 38/04 containing manganese
• CPC Class Codes: G01N 21/67 using electric arcs or discharges
• CPC Class Codes: G01N 21/73 using plasma burners or torches
• CPC Class Codes: G01N 33/0036 Specially adapted to detect a particular component all the other sub-groups of G01N33/0004 take precedence
• CPC Class Codes: G01N 33/2025 Gaseous constituents
• CPC Class Codes: G01N 33/205 in liquid state, e.g. molten metals

Abstract

Provided are a method for analyzing nitrogen in a metal sample, an apparatus for analyzing nitrogen in a metal sample, a method for adjusting nitrogen concentration in molten steel, and a method for manufacturing steel. The method includes: a melting process in which a metal sample containing a nitrogen component is melted in an argon gas atmosphere by performing impulse heating to gasify the nitrogen component; and an analyzing process in which nitrogen content in the metal sample is determined by analyzing nitrogen gas generated in the melting process and the argon gas by using a gas discharge optical emission method. By analyzing the nitrogen concentration of a sample taken from molten steel by using the analysis method described above, and by determining treatment conditions for adjusting nitrogen concentration on the basis of the nitrogen analysis value derived by the analysis, nitrogen concentration in molten steel is adjusted.

Claims

1. A method for analyzing nitrogen in a metal sample containing a nitrogen component, the method comprising:

performing impulse heating on the metal sample in an argon atmosphere to melt the metal sample and gasify the nitrogen component, and

determining the amount of nitrogen gas present in the argon gas by using a gas discharge optical emission method.

2. The method for analyzing nitrogen in a metal sample according to claim 1, wherein the gas discharge optical emission method uses optical emission of the nitrogen gas at one or more of wavelengths 337 nm, 357 nm, 380 nm, and 406 nm.

3. The method for analyzing nitrogen in a metal sample according to claim 1, wherein,

an emission intensity of nitrogen gas is corrected in accordance with an emission intensity of argon gas that is determined either at the same time as determining the emission intensity of the nitrogen gas, using the argon gas that contains the nitrogen gas, or using only flowing argon gas when not determining the emission intensity of the nitrogen gas.

4. The method for analyzing nitrogen in a metal sample according to claim 3, wherein,

optical emission of the argon gas at one or more of wavelengths 697 nm, 727 nm, 751 nm, 764 nm, 772 nm, 795 nm, 801 nm, 812 nm, and 826 nm is used.

9. The method for analyzing nitrogen in a metal sample according to claim 1, wherein,

when the nitrogen component is gasified by the impulse heating, the metal sample is heated to a temperature of 2500°

C. or higher.

10. A method for adjusting nitrogen concentration in molten steel, the method comprising:

analyzing the nitrogen concentration of a sample of the molten steel by using the method for analyzing nitrogen in a metal sample according to claim 1; and

determining treatment conditions for adjusting nitrogen concentration on the basis of the nitrogen analysis value obtained through the analyzing.

11. A method for manufacturing steel, the method comprising

manufacturing steel by performing continuous casting on molten steel whose nitrogen concentration has been adjusted by using the method for adjusting nitrogen concentration in molten steel according to claim 10.

12. The method for analyzing nitrogen in a metal sample according to claim 2, wherein,

an emission intensity of nitrogen gas is corrected in accordance with an emission intensity of argon gas that is determined either at the same time as determining the emission intensity of the nitrogen gas, using the argon gas that contains the nitrogen gas, or using only flowing argon gas when not determining the emission intensity of the nitrogen gas.

13. The method for analyzing nitrogen in a metal sample according to claim 12, wherein,

optical emission of the argon gas at one or more of wavelengths 697 nm, 727 nm, 751 nm, 764 nm, 772 nm, 795 nm, 801 nm, 812 nm, and 826 nm is used.

14. The method for analyzing nitrogen in a metal sample according to claim 3, wherein,

when the nitrogen component is gasified by the impulse heating, the metal sample is heated to a temperature of 2500°

C. or higher.

17. A method for adjusting nitrogen concentration in molten steel, the method comprising:

analyzing the nitrogen concentration of a sample of the molten steel by using the method for analyzing nitrogen in a metal sample according to claim 3; and

determining treatment conditions for adjusting nitrogen concentration on the basis of the nitrogen analysis value obtained through the analyzing.

18. A method for adjusting nitrogen concentration in molten steel, the method comprising:

analyzing the nitrogen concentration of a sample of the molten steel by using the method for analyzing nitrogen in a metal sample according to claim 9; and

determining treatment conditions for adjusting nitrogen concentration on the basis of the nitrogen analysis value obtained through the analyzing.

19. A method for manufacturing steel, the method comprising

manufacturing steel by performing continuous casting on molten steel whose nitrogen concentration has been adjusted by using the method for adjusting nitrogen concentration in molten steel according to claim 17.

20. A method for manufacturing steel, the method comprising

manufacturing steel by performing continuous casting on molten steel whose nitrogen concentration has been adjusted by using the method for adjusting nitrogen concentration in molten steel according to claim 18.

5. An apparatus for analyzing nitrogen in a metal sample containing a nitrogen component, the apparatus comprising:

an impulse furnace in which the metal sample is melted in an argon gas atmosphere to gasify the nitrogen component;

an argon gas feeding system through which argon gas is fed into the impulse furnace;

a discharge optical emission system that induces the discharge optical emission of nitrogen gas generated in the impulse furnace and of argon gas in the impulse furnace by using a gas discharge optical emission method; and

a photometrical analysis system that determines the intensity of emission induced by the discharge optical emission system to determine nitrogen content in the metal sample.

6. The apparatus for analyzing nitrogen in a metal sample according to claim 5, wherein

the photometrical analysis system further includes a device that determines emission intensity of the argon gas.

7. The apparatus for analyzing nitrogen in a metal sample according to claim 5, the apparatus further comprising

a carbon dioxide measuring device of an infrared absorption type for determining carbon dioxide content between the impulse furnace and the discharge optical emission system.

8. The apparatus for analyzing nitrogen in a metal sample according to claim 5, the apparatus further comprising

a buffer for diluting the nitrogen in the argon gas between the impulse furnace and the discharge optical emission system.

15. The apparatus for analyzing nitrogen in a metal sample according to claim 6, the apparatus further comprising

a carbon dioxide measuring device of an infrared absorption type for determining carbon dioxide content between the impulse furnace and the discharge optical emission system.

16. The apparatus for analyzing nitrogen in a metal sample according to claim 6, the apparatus further comprising

a buffer for diluting the nitrogen in the argon gas between the impulse furnace and the discharge optical emission system.