MOLECULES HAVING PESTICIDAL UTILITY, AND INTERMEDIATES, COMPOSITIONS, AND PROCESSES, RELATED THERETO

• US 20170208806A1
• Filed: 01/18/2017
• Published: 07/27/2017
• Est. Priority Date: 01/25/2016
• Status: Active Grant

• Current Assignee: Corteva Agriscience LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: Barton, Thomas, Gao, Xin, Hunter, Jim, Boruwa, Joshodeep, Tangirala, Raghuram, Lo, William C., Herbert, John, Watson, Gerald B., LePlae, Paul R.
• Granted Patent: US 10,681,908 B2
• Time in Patent Office: Days
• CPC Class Codes: A01N 37/20 containing the group , wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
• CPC Class Codes: A01N 37/34 Nitriles
• CPC Class Codes: A01N 41/02 containing a sulfur-to-oxygen double bond
• CPC Class Codes: A01N 41/10 Sulfones; Sulfoxides
• CPC Class Codes: A01N 41/12 not containing sulfur-to-oxygen bonds, e.g. polysulfides
• CPC Class Codes: C07C 2601/02 with a three-membered ring
• CPC Class Codes: C07C 317/28 with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
• CPC Class Codes: C07C 321/14 of an acyclic saturated carbon skeleton
• CPC Class Codes: C07C 323/25 the carbon skeleton being acyclic and saturated
• CPC Class Codes: C07C 323/60 with the carbon atom of at least one of the carboxyl groups bound to nitrogen atoms

Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, compositions containing such molecules, and processes of using such molecules and compositions against such pests. These molecules and compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

Claims

1. A molecule having the following formula

2. A molecule according to claim 1 wherein R¹, R³, R⁴, R⁵, R⁶, R⁹, R¹¹, R¹², and R¹³ are H.

3. A molecule according to claim 1 wherein R² is Cl, Br, or CH₃.

4. A molecule according to claim 1 wherein R³ is F, Cl, Br, or CH═

CH₂.

5. A molecule according to claim 1 wherein R⁴ is Cl, Br, or CH₃.

6. A molecule according to claim 1 wherein R², R³, and R⁴ are Cl.

7. A molecule according to claim 1 wherein R⁷ is (C₁-C₆)haloalkyl.

8. A molecule according to claim 1 wherein R⁷ is CF₃ or CF₂CH₃.

9. A molecule according to claim 1 wherein R¹⁰ is Cl, Br, CH₃, or CF₃.

10. A molecule according to claim 1 wherein Q is O.

11. A molecule according to claim 1 wherein L is CH₂CH₂ or CH(CH₃)CH₂.

12. A molecule according to claim 1 wherein n is 0, 1, or 2.

13. A molecule according to claim 1 wherein R¹⁴ is CH₂CH₃ or CH₂CF₃.

14. A molecule according to claim 1 wherein

(A) R¹, R⁵, R⁶, R¹¹, R¹², and R¹³ are H;

(B) R², R³, and R⁴ are each independently selected from the group consisting of H, F, Cl, Br, (C₁-C₄)alkyl, and (C₂-C₄)alkenyl;

(C) R⁷ is (C₁-C₆)haloalkyl;

(D) R⁹ is H;

(E) R¹⁰ is selected from the group consisting of Cl, Br, (C₁-C₄)alkyl, and (C₁-C₄)haloalkyl;

(G) Q is O;

(H) L is (C₁-C₆)alkyl;

(I) n is 0, 1, or 2;

(J) R¹⁴ is selected from the group consisting of (C₁-C₄)alkyl and (C₁-C₄)haloalkyl,

wherein each alkyl or haloalkyl may optionally be substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, I, CN, and OH.

15. A molecule according to claim 1 wherein said molecule is selected from one of the molecules in Table 2.

16. A molecule according to claim 1 wherein said molecule is selected from one of the molecules in Table 1.

17. A pesticidal composition comprising a molecule according to claim 1 further comprising one or more active ingredients.

18. A pesticidal composition according to claim 17 wherein said active ingredient is selected from the group consisting of AI-1, 1,3-dichloropropene, chlorpyrifos, chlorpyrifos-methyl, hexaflumuron, methoxyfenozide, noviflumuron, spinetoram, spinosad, sulfoxaflor, and sulfuryl fluoride.

19. A pesticidal composition comprising a molecule according to claim 1 and a seed.

20. A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a pesticidal composition wherein said pesticidal composition comprises a molecule according to claim 1.