MOLECULES HAVING PESTICIDAL UTILITY, AND INTERMEDIATES, COMPOSITIONS, AND PROCESSES, RELATED THERETO

• US 20170210723A1
• Filed: 01/18/2017
• Published: 07/27/2017
• Est. Priority Date: 01/25/2016
• Status: Abandoned Application

• Current Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: LePlae, JR., Paul R., Barton, Thomas, Boruwa, Joshodeep, Lo, William C., Herbert, John, Watson, Gerald B., Gao, Xin, Hunter, Jim, Tangirala, Raghuram
• Application Number:
  US15/408,503
• Publication Number:
  US 20170210723A1
• Time in Patent Office: Days
• CPC Class Codes: A01N 37/20 containing the group , wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
• CPC Class Codes: A01N 37/34 Nitriles
• CPC Class Codes: A01N 41/10 Sulfones; Sulfoxides
• CPC Class Codes: A01N 43/20 three- or four-membered rings
• CPC Class Codes: A01N 43/30 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
• CPC Class Codes: C07C 255/57 containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton
• CPC Class Codes: C07C 2601/02 with a three-membered ring
• CPC Class Codes: C07C 317/28 with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
• CPC Class Codes: C07C 317/50 at least one of the nitrogen atoms being part of any of the groups , X being a hetero atom, Y being any atom
• CPC Class Codes: C07C 323/42 Y being a carbon atom of a six-membered aromatic ring
• CPC Class Codes: C07C 323/60 with the carbon atom of at least one of the carboxyl groups bound to nitrogen atoms
• CPC Class Codes: C07D 305/08 with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring atoms
• CPC Class Codes: C07D 317/62 with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to atoms of the carbocyclic ring

Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, compositions containing such molecules, and processes of using such molecules and compositions against such pests. These molecules and compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

Claims

1. A molecule having the following formula

2. A molecule according to claim 1 wherein R¹, R⁵, R⁶, R⁹, and R¹² are H.

3. A molecule according to claim 1 wherein R² is Cl or Br.

4. A molecule according to claim 1 wherein R³ is H, F, Cl, or CN.

5. A molecule according to claim 1 wherein R⁴ is Cl, Br, or C(O)H.

6. A molecule according to claim 1 wherein R³ and R⁴ together are —

OCH₂O—

.

7. A molecule according to claim 1 wherein R², R³, and R⁴ are Cl.

8. A molecule according to claim 1 wherein R⁷ is CF₃ or CF₂CH₃.

9. A molecule according to claim 1 wherein R⁸ is H, OCH₃, or OCH₂CH₃.

10. A molecule according to claim 1 wherein R¹⁰ is F, Cl, Br, CH₃, CH₂CH₃, CHF₂, or CF₃.

11. A molecule according to claim 1 wherein R¹¹ is H or CH₃.

12. A molecule according to claim 1 wherein L is —

CH₂CH₂—

, —

CH(CH₃)CH₂—

, —

CH(CH₂CH₃)CH₂—

, —

CH(CH(CH₃)₂)CH₂—

, —

C(CH₃)₂CH₂—

, —

CH(CH₃)CH₂CH₂—

, —

CH(CH₂OCH₃)CH₂—

, —

C(cyclopropyl)CH₂—

, —

CH₂C(3,3-oxetanyl)-, or —

CH₂CH(SCH₂CH₃)—

.

13. A molecule according to claim 1 wherein n is 0, 1, or 2.

14. A molecule according to claim 1 wherein R¹³ is CH₃, CH₂CH₃, CH₂CH₂CH₃, CH(CH₃)₂, CH₂CH(CH₃)₂, CH₂CH═

CH₂, CH₂CF₃, CH₂CH₂CF₃, phenyl, CH₂phenyl, CH(CH₃)phenyl, CH₂cyclopropyl, or NHCH₂CF₃, wherein each phenyl and cyclopropyl is optionally substituted with one or more substituents selected from the group consisting of F, Cl, Br, and CN.

15. A molecule according to claim 1 wherein

(A) R¹, R⁵, R⁶, R⁹, and R¹² are H;

(B) R² is selected from the group consisting of Cl and Br;

(C) R³ and R⁴ are, each independently selected from the group consisting of (D), H, F, Cl, Br, I, CN, and C(O)H;

(D) R³ and R⁴ together can optionally form a 3- to 5-membered saturated or unsaturated, heterohydrocarbyl link, which may contain one or more heteroatoms selected from the group consisting of nitrogen, sulfur, and oxygen,

wherein said heterohydrocarbyl link may optionally be substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, and OH;

(E) R⁷ is (C₁-C₆)haloalkyl;

(F) R⁸ is selected from the group consisting of H and (C₁-C₄)alkoxy;

(G) R¹⁰ is selected from the group consisting of F, Cl, Br, I, (C₁-C₄)alkyl, and (C₁-C₄)haloalkyl;

(H) R¹¹ is selected from the group consisting of H and (C₁-C₄)alkyl;

(I) L is a linker that is selected from the group consisting of (C₁-C₈)alkyl, (C₁-C₄)alkoxy, (C₃-C₆)cycloalkyl-(C₁-C₄)alkyl, (C₁-C₄)alkyl-(C₃-C₆)cycloalkoxy, and (C₁-C₄)alkyl-S—

(C₁-C₄)alkyl,

wherein each alkyl, alkoxy, cycloalkyl, and haloalkyl may optionally be substituted with one or more (C₁-C₄)alkoxy substituents;

(J) n is selected from the group consisting of 0, 1, and 2; and

(k) R13 is selected from the group consisting of (C₁-C₄)alkyl, (C₂-C₄)alkenyl, (C₁-C₄)haloalkyl, phenyl, (C₁-C₄)alkyl-phenyl, (C₁-C₄)alkyl-(C₃-C₆)cycloalkyl, and NH(C₁-C₄)haloalkyl,

wherein each alkyl, alkenyl, haloalkyl, alkoxy, haloalkoxy, phenyl, and cycloalkyl, may optionally be substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, I, and CN.

16. A molecule according to claim 1 wherein

(A) R¹, R⁵, R⁶, R⁹, and R¹² are H;

(B) R² is selected from the group consisting of Cl and Br;

(C) R³ and R⁴ are, each independently selected from the group consisting of H, F, Cl, Br, I, and CN.

(E) R⁷ is (C₁-C₆)haloalkyl;

(F) R⁸ is H;

(G) R¹⁰ is selected from the group consisting of F, Cl, Br, I, (C₁-C₄)alkyl, and (C₁-C₄)haloalkyl;

(H) R¹¹ is selected from the group consisting of H and (C₁-C₄)alkyl;

(I) L is a linker that is selected from the group consisting of (C₁-C₅)alkyl, (C₃-C₆)cycloalkyl-(C₁-C₄)alkyl, and (C₁-C₄)alkyl-S—

(C₁-C₄)alkyl;

(J) n is selected from the group consisting of 0, 1, and 2; and

(K) R¹³ is selected from the group consisting of (C₁-C₄)alkyl, (C₂-C₄)alkenyl, (C₁-C₄)haloalkyl, (C₁-C₄)alkyl-phenyl, (C₁-C₄)alkyl-(C₃-C₆)cycloalkyl, and NH(C₁-C₄)haloalkyl,

wherein each alkyl, alkenyl, haloalkyl, alkoxy, haloalkoxy, and cycloalkyl, may optionally be substituted with one or more substituents independently selected from the group consisting of F, Cl, Br, and I.

17. A molecule according to claim 1 wherein said molecule is selected from one of the molecules in Table 1

18. A pesticidal composition comprising a molecule according to claim 1 further comprising one or more active ingredients.

19. A pesticidal composition according to claim 18 wherein said active ingredient is from AIGA.

20. A pesticidal composition according to claim 18 wherein said active ingredient is selected from the group consisting of AI-1, 1,3-dichloropropene, chlorpyrifos, chlorpyrifos-methyl, hexaflumuron, methoxyfenozide, noviflumuron, spinetoram, spinosad, sulfoxaflor, and sulfuryl fluoride.

21. A pesticidal composition comprising a molecule according to claim 1 further comprising one or more MoA Materials.

22. A pesticidal composition according to claim 21 wherein said MoA Material is from MoAMGA.

23. A pesticidal composition comprising a molecule according to claim 1 and a seed.

24. A process to control a pest said process comprising applying to a locus, a pesticidally effective amount of a pesticidal composition wherein said pesticidal composition comprises a molecule according to claim 1.