PROCESS AND APPARATUS FOR SEPARATING ENTRAINED AMINES FROM A GAS STREAM

• US 20170312681A1
• Filed: 10/27/2015
• Published: 11/02/2017
• Est. Priority Date: 10/27/2014
• Status: Abandoned Application

• Current Assignee: Carbonoro B.V.
• Original Assignee: Carbonoro B.V.
• Inventors: JURG, Immanuel
• Application Number:
  US15/521,866
• Publication Number:
  US 20170312681A1
• Time in Patent Office: Days
• CPC Class Codes: B01D 2252/20405 Monoamines
• CPC Class Codes: B01D 2252/20421 Primary amines
• CPC Class Codes: B01D 2252/20426 Secondary amines
• CPC Class Codes: B01D 2252/20431 Tertiary amines
• CPC Class Codes: B01D 2252/20436 Cyclic amines
• CPC Class Codes: B01D 2252/504 Mixtures of two or more absorbents
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 2258/05 Biogas
• CPC Class Codes: B01D 53/1406 Multiple stage absorption
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1462 Removing mixtures of hydrogen sulfide and carbon dioxide
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: F23J 15/04 using washing fluids scrubbers for removing solids only F23J15/022
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation

Abstract

This disclosure relates to a process for removing acid gases from a gas stream enriched in acid gases, wherein: (a) the gas stream enriched in acid gases is contacted in an absorption zone with an absorption medium, wherein the absorption medium is an aqueous medium comprising an amine, to form a gas stream depleted in acid gases which comprises an entrained amine and an absorption medium enriched in acid gases; and (b) treating the gas stream depleted in acid gases which comprises an entrained amine in a first scrubbing zone with a first scrubbing medium, wherein the first scrubbing medium is an aqueous medium comprising an amine, the amount of amine comprised by the scrubbing medium being about 0.1 to about 50.0 wt. %, wherein the aqueous medium is saturated with carbon dioxide such that at least 75 wt. % of the amine, based on the total amount of amine comprised by the aqueous medium, is in its carbamate or carbonate form, to form a gas stream depleted in acid gases and in amine and a first scrubbing medium enriched in amine.

Claims

1. A process for removing acid gases from a gas stream enriched in acid gases, wherein:

(a) the gas stream enriched in acid gases is contacted in an absorption zone with an absorption medium, wherein the absorption medium is an aqueous medium comprising an amine, to form a gas stream depleted in acid gases which comprises an entrained amine and an absorption medium enriched in acid gases; and

(b) treating the gas stream depleted in acid gases which comprises an entrained amine in a first scrubbing zone with a first scrubbing medium, wherein the first scrubbing medium is an aqueous medium comprising an amine, the amount of amine comprised by the scrubbing medium being about 0.1 to about 50.0 wt. %, wherein the aqueous medium is saturated with carbon dioxide such that at least 75 wt. % of the amine, based on the total amount of amine comprised by the aqueous medium, is in its carbamate or carbonate form, to form a gas stream depleted in acid gases and in amine and a first scrubbing medium enriched in amine.

2. The process according to claim 1, wherein the amount of amine comprised by the scrubbing medium is about 0.1 to about 10.0 wt. %.

3. The process according to claim 1 or claim 2, wherein the first scrubbing medium is produced by treating an aqueous medium comprising an amine with carbon dioxide.

4. The process according to claim 3, wherein the aqueous medium comprising the amine is saturated with carbon dioxide such that at least 90 wt. % of the amine is in its carbamate or carbonate form.

5. The process according to claim 1, wherein step (b) is performed countercurrently.

6. The process according to claim 1 wherein the first scrubbing zone is a packed column.

7. The process according to claim 1 wherein the first scrubbing medium originates from a stripper column.

8. The process according to claim 1, wherein the first scrubbing medium enriched in amine is returned to a stripper column.

9. The process according to claim 1, wherein the amine has a partition coefficient log P of more than −

0.5 and not higher than 3.

10. The process according to any one of claims 19, claim 1 wherein the amine is selected from the group consisting of primary amines, secondary amines, tertiary amines and mixtures thereof.

11. The process according to claim 10, wherein the amine is a cyclic amine.

12. The process according to claim 11, wherein the amine is N,N-dimethylcyclohexylamine (DMCA), N-methylcyclohexylamine (MCA) or a combination thereof.

13. The process according to claim 1, wherein the acid gases are carbon dioxide, hydrogen sulfide or a mixture thereof.

14. The process according to claim 1, wherein the gas stream enriched in acid gases is a biogas.

15. The process according to claim 1 wherein the process further comprises step (c), said step (c) comprising treating the gas stream depleted in acid gases and in amine in a second scrubbing zone with a second scrubbing medium, wherein the second scrubbing medium is an aqueous medium comprising an amine, the amount of amine comprised by the second scrubbing medium being about 0 to about 6.0 wt. %, to form a second gas stream depleted in acid gases and in amine and a second scrubbing medium enriched in amine.