NON-STREAKING DURABLE COMPOSITION FOR CLEANING AND DISINFECTING HARD SURFACES

• US 20180007895A1
• Filed: 07/11/2016
• Published: 01/11/2018
• Est. Priority Date: 07/11/2016
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Karandikar, Yamini, Levitt, Mark Dennis, Wegner, Joseph R., Solomon, Kim R.
• Granted Patent: US 10,433,545 B2
• Time in Patent Office: Days
• CPC Class Codes: A01N 25/22 containing ingredients stabilising the active ingredients
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 33/12 Quaternary ammonium compounds
• CPC Class Codes: A61L 2/18 Liquid substances or solutions comprising solids or dissolved gases
• CPC Class Codes: C11D 1/75 Amino oxides
• CPC Class Codes: C11D 3/30 Amines; Substituted amines ; Quaternized amines
• CPC Class Codes: C11D 3/33 Amino carboxylic acids
• CPC Class Codes: C11D 3/48 Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
• CPC Class Codes: Y02A 50/30 Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Abstract

The present invention relates to quaternary ammonium disinfecting cleaning compositions comprising a quaternary ammonium compound, an alkyl a polyglycoside with a CMC greater than 1000 ppm and a chelant. Beneficially, the compositions provide residual sanitizing efficacy without diminished performance and without scale formation when diluted with hard water. The compositions are suitable for inactivating and/or reducing infectious agents, particularly Norovirus, Adenovirus, and Polyomavirus.

Claims

1. :

A disinfectant cleaning composition comprising;

a unimer biocidal quaternary ammonium compound;

an alkyl polyglycoside with a critical micelle concentration (CMC) greater than 600 ppm;

a chelating agent; and

water.

2. :

The disinfectant cleaning composition of claim 1, substantially free of organic solvents.

3. :

The disinfectant cleaning composition of claim 1, wherein the alkyl polyglycoside has a critical micelle concentration (CMC) of greater than 2000 ppm.

4. :

The disinfectant cleaning composition of claim 1, wherein the alkyl polyglycoside has a critical micelle concentration (CMC) of greater than 1,000 ppm.

5. :

The disinfectant cleaning composition of claim 1, further comprises an amine oxide surfactant.

6. :

The disinfectant cleaning composition of claim 1, containing a primary, secondary or tertiary amine.

7. :

The disinfectant cleaning composition of claim 1, containing an N-coco-1,3-propylene diamine.

8. :

The disinfectant composition of claim 1 wherein said biocidal quaternary ammonium compound is a dialkyl quaternary ammonium compound.

9. :

The disinfectant cleaning composition of claim 1, containing an amine oxide surfactant, and a primary, secondary or tertiary amine.

10. :

The disinfectant cleaning composition of claim 1, wherein the biocidal quaternary ammonium compound is an dialkyl dimethylammonium chloride.

11. :

The disinfectant cleaning composition of claim 1, wherein the biocidal quaternary ammonium compound is an dialkyl dimethylammonium chloride blend including didecyl dimethyl ammonium chloride, dioctyl dimethyl ammonium chloride and octcyl decyl dimethyl ammonium chloride.

12. :

The disinfectant cleaning composition of claim 1, wherein the quaternary ammonium is free of benzyl or aromatic substituents.

13. :

The disinfectant cleaning composition of claim 5, wherein said amine oxide surfactant has a higher critical micelle concentration (CMC) than said quaternary ammonium compound.

14. :

The disinfectant cleaning composition of claim 5 wherein said amine oxide surfactant is a C12, diethyl or dimethyl amine oxide.

15. :

The disinfectant cleaning composition of claim 1 wherein said chelant is ethylenediaminetetraacetic acid (EDTA) or a salt thereof.

16. :

The disinfectant cleaning composition of claim 6, wherein said amine is an aliphatic amine salt, a diamines, N-coco-1,3-propylene diamine, N-oleyl-1,3-propylene diamine, N-tallow-1,3-propylene diamine, a diamine salt, or an alkyl amine, or diamine acetate.

17. :

The disinfectant cleaning composition of claim 1 wherein said composition is free of benzyl alcohol, glycol ethers, glycols and glycerin.

18. :

The disinfecting cleaning composition of claim 11 wherein said composition demonstrates residual antimicrobial activity for 24 hours.

19. :

The disinfecting cleaning composition of claim 1 wherein said composition effects disinfection in 5 minutes or less.

20. :

The disinfectant cleaning composition of claim 1 wherein said composition is active against noroviruses.

21. :

A sanitizing composition comprising;

a) from about 0.7 wt. % to about 40.0 wt. % of a unimer biocidal quaternary ammonium compound;

b) from about 1.3 wt. % to about 80.0 wt. % of a alkyl polyglycoside surfactant that exhibits a critical micelle concentration (CMC) of greater than 600 ppm at 20-25°

C.;

c) from about 1.5 wt. % to about 90.0 wt. % of a C12 amine oxide surfactant; and

d) from about 0.1 wt. % to about 4.0 wt. % of an chelant.

22. :

The composition of claim 21, further comprising a primary, secondary or tertiary amine.

23. :

The composition of claim 21 further comprising bis(3-aminopropyl) alkylamine.

24. :

The composition of claim 21 wherein the composition is diluted with water by a factor of 10 to 1000.

25. :

The composition of claim 24, wherein the composition is diluted by a factor of 50 to 500.

26. :

A method of residual sanitizing a surface comprising;

contacting a surface, article, and/or substrate with the sanitizing composition of claim 21.

27. :

The method of claim 26, wherein the contacting results in inactivation and/or reduction of infectious agents on the surface, article, and/or substrate.

28. :

The method of claim 27, wherein the infectious agents comprise bacteria, viruses, and/or yeasts.

29. :

A residual sanitizing composition comprising;

a) from about 3000 ppm to about 50 ppm of a unimer biocidal quaternary ammonium compound;

b) from about 7800 ppm to about 130 ppm of a alkyl polyglycoside surfactant that exhibits a critical micelle concentration (CMC) of greater than 600 ppm;

c) from about 4050 ppm to about 67.5 ppm of an C12 amine oxide surfactant; and

d) from about 1200 ppm to about 10 ppm of a chelant.

30. :

The composition of claim 29, further comprising a primary, secondary or tertiary amine.

31. :

A method of residual sanitizing for a surface comprising;

contacting a surface, article, and/or substrate with the sanitizing composition of claim 29.

32. :

The method of claim 31, wherein the contacting results in inactivation and/or reduction of infectious agents on the surface, article, and/or substrate.

33. :

The method of claim 32, wherein the infectious agents comprise bacteria, viruses, and/or yeasts.

34. :

An antimicrobial multi-surface cleaning composition having a five minute or less kill time against Staphylococcus aureus and Salmonella Type B as measured by a Germicidal Spray Test,

comprising;

A. a biocidal quaternary ammonium compound;

B. an alkyl polyglycoside with a critical micelle concentration (CMC) greater than 600 ppm;

C. a chelating agent; and

D. water

wherein the composition is essentially free of organic solvents.

35. :

The composition of claim 34 wherein the biocidal quaternary ammonium compound is a dialkyl dimethyl ammonium chloride.

36. :

The composition of claim 34, the composition further comprises an amine oxide surfactant.

37. :

The composition of claim 34, demonstrating virucidal performance against the Norwalk virus and containing a primary, secondary or tertiary amine.

38. :

The composition of claim 37, demonstrating virucidal performance against the Norwalk virus and containing N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine.

39. :

The composition of claim 34, the composition further comprises a C10, C12, or C14 alkyl dimethyl amine oxide, a primary, secondary or tertiary amine.

40. :

The composition of claim 34, wherein the alkyl polyglycoside has a critical micelle concentration (CMC) greater than 1000 ppm.

41. :

The composition of claim 40 further comprising a C10, C12, or C14 alkyl dimethyl amine oxide, N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine, and no organic solvent.

42. :

An antimicrobial cleaning composition having a 5 minute or less kill time against Staphylococcus aureus, additionally demonstrating norovirus inactivation, additionally demonstrating Residual Sanitizing efficacy on Hard, Non-Porous Surfaces, additionally demonstrating no or low streaking glass cleaning performance.

Comprising;

a biocidal quaternary ammonium compound;

an alkyl polyglycoside with a critical micelle concentration (CMC) greater than 600 ppm;

a chelating agent;

a primary, secondary or tertiary amine;

an amine oxide; and

water,

wherein the composition is essentially free of organic solvents.

43. :

The composition of claim 42 wherein the amine is N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine.

44. :

The composition of claim 42, the amine oxide is a C10, C12, or C14 alkyl dimethyl amine oxide, and the composition contains no glycol ether, aromatic alcohol, or glycol solvents.