METHOD TO MAKE MAGNETIC RAMDOM ACCESSS MEMROY ARRAY WITH SMALL FOOTPRINT

• US 20180033957A1
• Filed: 07/26/2016
• Published: 02/01/2018
• Est. Priority Date: 07/26/2016
• Status: Abandoned Application

• Current Assignee: Shanghai CIYU Information Technologies Company Limited
• Original Assignee: Shanghai CIYU Information Technologies Company Limited
• Inventors: Zhang, Yun Sen, Xiao, Rongfu, Guo, Yimin, Chen, Jun
• Application Number:
  US15/219,286
• Publication Number:
  US 20180033957A1
• Time in Patent Office: Days
• CPC Class Codes: H10N 50/01 Manufacture or treatment

Abstract

This invention is about a method to make magnetic random access memory with small footprint directly on CMOS VIA with a self-aligned etching process. The process schemes of the method proceeds as: (1) Etch MTJ and BE using one or more of RIE and/or IBE processes with Ta as hard mask; (2) Etch BE using one or more of RIE and/or IBE processes with Ta & sidewall protection layer on MTJ as hard mask; and (3) Etch a part of MTJ and BE using one or more of RIE and/or IBE processes with Ta & sidewall protection layer on top portion of MTJ as hard mask. All the three schemes lead the BE to be self-aligned to MTJ cells, the photo overlay margin is not necessary and circuits could be made extremely small with lower manufacturing cost; The invention also provides schemes to prevent the electrical shorting across the tunnel barrier layer. Through trimming and sidewall protection deposition process, device performance and electrical/magnetic properties could be greatly improved.

Claims

1. A method of manufacturing a magnetic random access memory array with small footprint comprising:

forming a bottom electrode (BE) stack element;

forming a magnetic tunneling junction (MTJ) stack element above the BE;

forming a hard mask (HM) stack element above the MTJ;

forming a photoresist (PR) stack element above the HM;

patterning the MTJ using UV photolithography;

etching the HM stack element using PR stack as mask;

etching the MTJ stack element using the HM stack as mask;

etching the BE stack element using the HM stack as mask; and

refilling the etched area of MTJ and BE with dielectric materials.

2. The method of claim 1, wherein forming a BE comprises forming a seed layer such as Ta, TaN, Ti or TiN, a main conducting layer such as Cu, CuN, Ru, Mo or W and a capping layer such as Ta, TaN, W or WN.

3. The method of claim 1, wherein forming a MTJ stack comprises forming a magnetic reference element such as [X/Co]nRuCo[X/Co]m/Y/CoFeB/where X is selected from Pt, Pd or Ni and Y is selected from Ta, W, or Mo, an oxide tunnel barrier layer such as MgO or MgZnO, and magnetic memory element such as CoFeB and/or CoFe, or a reversed stack of magnetic memory, tunnel barrier and reference elements.

4. The method of claim 1, wherein forming a HM stack comprises forming a Ta single layer, a Ta/Si-dielectric bi-layer, or Ta/C/Si-dielectric tri-layer.

5. The method of claim 1, wherein forming a PR stack comprises forming a BARC/PR bi-layer or OPL/ARC/PR tri-layer, wherein PR refers to a photo resist, BARC refers to a bottom antireflection coat (ARC), OPL refers an organic planarization layer.

6. The method of claim 1, wherein patterning the MTJ comprises using a single litho-etch (LE) or double litho-etch (LELE) process.

7. The method of claim 1, wherein etching the HM stack element comprises using a series of reactive ion etch using Fluorine (such as CF4 or SF6) or C12 based gases for Ta and Si-dielectric, and oxygen for C layer.

8. The method of claim 1, wherein etching the MTJ stack comprises using one or more of reactive ion etching (RIE) process and/or ion-beam etch (IBE) process, using Ta as a hard mask.

9. The method of claim 8 wherein the RIE process comprises using one or more of a main etchant gas methanol (CH3OH), ethanol, and a mixture of CO and NH4 or CH4 and H2.

10. The method of claim 8 wherein the IBE process comprises using one or more of Ar, Kr or Xe as main etch gases.

11. The method of claim 1, wherein etching the BE stack element comprises using one or more of reactive ion etching (RIE) process and/or ion-beam etch (IBE) process, through self-alignment with MTJ stack using Ta as a hard mask.

12. The method of claim 1, wherein etching the MTJ comprises using a capping layer adjacent to the BE.

13. The method of claim 1, wherein etching the MTJ further comprises trimming exposed edges of a post-etched MTJ by a low energy IBE to remove re-deposition and/or etch-damaged dead layers.

14. The method of claim 1, wherein refilling the etched area of MTJ and the BE with dielectric materials comprises using a chemical vapor deposition (CVD) or atomic layer deposition (ALD).

15. The method of claim 1, wherein etching the BE comprises applying RIE and/or IBE using Ta &

protection layer on MTJ as a mask through self-alignment.

16. The method of claim 1, wherein etching the MTJ further comprises using an end-point detection control for terminating etching at the tunnel barrier layer (MgO or MgZnO) .

17. The method of claim 1, wherein refilling the etched area of MTJ with dielectric materials comprises using a CVD or ALD on edges of a partially-etched MTJ.

18. The method of claim 1, wherein etching the MTJ and etching the BE comprise applying RIE and/or IBE on remaining un-etched MTJ layers and BE stack in process using Ta &

protection layer on top portion of MTJ as a mask through self-alignment.

19. The method of claim 1, wherein etching the BE stack element and refilling the etched area of MTJ and BE with dielectric materials can be one time or repeated several times until the BE is completely etched without damaging the exposed MTJ junction.

20. The method of claim 1, wherein refilling the etched area of MTJ and BE with dielectric materials comprise using a materials selected from SiO2, SiON, SiN, SiCN, SiC, MgO or Al2O3.