POLYETHYLENE TEREPHTHALATE COLORING SYSTEMS AND METHODS

• US 20180126595A1
• Filed: 11/10/2016
• Published: 05/10/2018
• Est. Priority Date: 11/10/2016
• Status: Active Grant

• Current Assignee: Aladdin Manufacturing Corporation (Mohawk Industries Incorporated)
• Original Assignee: Mohawk Industries Incorporated
• Inventors: Clark, Thomas R.
• Granted Patent: US 10,751,915 B2
• Time in Patent Office: Days
• CPC Class Codes: B29B 13/022 Melting the material to be shaped
• CPC Class Codes: B29B 7/325 Static mixers in general B01F25/42
• CPC Class Codes: B29B 7/42 with screw or helix
• CPC Class Codes: B29B 7/46 with more than one shaft
• CPC Class Codes: B29B 7/485 with three or more shafts provided with screws
• CPC Class Codes: B29B 7/726 Measuring properties of mixture, e.g. temperature or density B29B7/724 takes precedence
• CPC Class Codes: B29B 7/7461 Combinations of dissimilar mixers
• CPC Class Codes: B29B 7/748 Plants B29B7/7433, B29B7/7485, B29B7/7495 take precedence
• CPC Class Codes: B29B 7/7485 with consecutive mixers, e.g. with premixing some of the components
• CPC Class Codes: B29B 7/86 for working at sub- or superatmospheric pressure B01F33/70 takes precedence
• CPC Class Codes: B29B 7/88 Adding charges , i.e. additives
• CPC Class Codes: B29B 7/94 Liquid charges
• CPC Class Codes: B29C 48/0255 for extruding parallel streams of material, e.g. several separate parallel streams of extruded material forming separate articles B29C48/0013, B29C48/345 takes precedence
• CPC Class Codes: B29C 48/05 Filamentary, e.g. strands
• CPC Class Codes: B29C 48/362 using static mixing devices
• CPC Class Codes: B29C 48/425 using three or more screws serially arranged screws B29C48/38, B29C48/385
• CPC Class Codes: B29C 48/43 Ring extruders
• CPC Class Codes: B29C 48/435 Sub-screws
• CPC Class Codes: B29K 2067/003 PET, i.e. poylethylene terephthalate
• CPC Class Codes: B29K 2105/0032 Pigments, colouring agents or opacifiyng agents
• CPC Class Codes: B29K 2105/26 : Scrap or recycled material
• CPC Class Codes: B29L 2031/731 : Filamentary material, i.e. comprised of a single element, e.g. filaments, strands, threads, fibres cables B29L2031/707
• CPC Class Codes: B29L 2031/7322 : Carpets
• CPC Class Codes: D01D 4/06 : Distributing spinning solution or melt to spinning nozzles
• CPC Class Codes: D01D 5/08 : Melt spinning methods D01D5/0023 takes precedence
• CPC Class Codes: D01D 5/082 : of mixed yarn
• CPC Class Codes: D01F 1/04 : Pigments
• CPC Class Codes: D01F 1/06 : Dyes
• CPC Class Codes: D01F 6/62 : from polyesters
• CPC Class Codes: D10B 2503/04 : Floor or wall coverings; Carpets

Abstract

A method of manufacturing a plurality of colors of bulked continuous carpet filament from a single multi-screw extruder which, in various embodiments, comprises: (A) passing PET through an extruder that melts the PET and purifies the resulting PET polymer melt; (B) splitting the extruded polymer melt into a plurality of melt streams and adding a colorant to each of the plurality of melt streams; (C) using one or more static mixers (e.g., thirty six static mixers) to substantially uniformly mix (e.g., homogeneously mix) each of the plurality of melt streams with its respective added colorant; and (D) feed each of the uniformly mixed and colored plurality of melt streams into a respective spinning machines that turns the polymer into filament for use in manufacturing carpet, rugs, and other products.

Claims

1. A method of manufacturing a plurality of colors of bulked continuous carpet filament from polyethylene terephthalate (PET) using a single multi-screw extruder, the method comprising:

(A) providing a multi-screw extruder;

(B) using the multi-screw extruder to at least partially melt the PET into a polymer melt and at least partially purify the polymer melt;

(C) after the step of using the multi-screw extruder to at least partially melt the PET into a polymer melt and at least partially purify the polymer melt, splitting the polymer melt into a plurality of individual polymer streams downstream from the multi-screw extruder;

(D) providing, for each of the plurality of individual polymer streams, a respective secondary extruder;

(E) using each the respective secondary extruder to add a respective colorant to each of the plurality of individual polymer streams;

(F) providing, for each of the plurality of individual polymer streams, one or more respective static mixers, each of the one or more respective static mixers comprising a substantially cylindrical housing and at least thirty individual static mixing elements disposed within the substantially cylindrical housing;

(G) after the step of using each the respective secondary extruder to add a respective colorant to each of the plurality of individual polymer streams, using the one or more respective static mixers to substantially thoroughly mix each of the plurality of individual polymer streams with the respective colorant; and

(F) after the step of using the one or more respective static mixers to substantially thoroughly mix each of the plurality of individual polymer streams with the respective colorant, forming each of the plurality of individual polymer streams into bulked continuous carpet filament.

2. The method of claim 1, the method further comprising:

providing, for each of the plurality of individual polymer streams, a respective spinning machine; and

forming each of the plurality of individual polymer streams into bulked continuous carpet filament using each the respective spinning machine to form each of the plurality of individual polymer streams into the bulked continuous carpet filament.

3. The method of claim 1, wherein the at least thirty individual static mixing elements comprise at least one helical static mixing element.

4. The method of claim 3, wherein:

the at least one helical static mixing element comprises a substantially rectangular plate defining a leading edge that extends diametrically between opposing interior portions of the substantially cylindrical housing and a trailing edge that extends diametrically between opposing interior portions of the substantially cylindrical housing; and

the substantially rectangular plate extends helically within the substantially cylindrical housing from the leading edge to the trailing edge such that the substantially rectangular plate is twisted about 180 degrees between the leading edge and the trailing edge.

5. The method of claim 4, wherein:

the at least one helical static mixing element is a first helical mixing element;

the at least thirty individual static mixing elements comprise a second helical static mixing element, wherein the second helical static mixing element is substantially structurally identical to the first helical static mixing element; and

the second helical static mixing element is disposed adjacent the first static mixing element within the substantially cylindrical housing such that;

the trailing edge of the first helical static mixing element abuts at least a portion of the leading edge of the second helical static mixing element; and

the trailing edge of the first helical static mixing element forms an angle with the leading edge of the second helical static mixing element of between about zero degrees and about ninety degrees.

6. The method of claim 5, wherein the trailing edge of the first helical static mixing element forms an angle with the leading edge of the second helical static mixing element of about ninety degrees.

7. The method of claim 1, wherein the at least thirty individual static mixing elements comprises at least one static mixing element comprising:

a plurality of substantially rectangular mixing bars disposed within the substantially cylindrical housing.

8. The method of claim 7, wherein, the at least thirty individual static mixing elements comprise thirty static mixing elements each comprising a plurality of substantially rectangular mixing bars disposed within the substantially cylindrical housing.

9. The method of claim 8, wherein:

the at least thirty static mixing elements are structurally identical;

the at least thirty static mixing elements comprise a first static mixing element and a second static mixing element;

the first static mixing element is disposed adjacent the second static mixing element;

the first static mixing element is disposed in a first orientation relative to the at least thirty individual static mixing elements; and

the second static mixing element is disposed in an orientation other than the first orientation.

10. The method of claim 1, wherein the at least thirty individual static mixing elements comprise thirty six individual static mixing elements.

11. The method of claim 1, wherein:

the plurality of individual polymer streams comprise a first individual polymer stream; and

the method further comprises;

providing a first secondary extruder;

using the first secondary extruder to add a first colorant to the first individual polymer stream;

providing, for the first individual polymer stream, one or more first static mixers;

using the one or more first static mixers to substantially thoroughly mix the first individual polymer stream and the first colorant;

forming the first individual polymer stream into bulked continuous filament of a first color;

changing the first colorant to a second colorant;

using the one or more first static mixers to substantially thoroughly mix the first individual polymer stream and the second colorant; and

forming the first individual polymer stream into bulked continuous filament of a second color.

12. The method of claim 11, wherein:

the method produces waste bulked continuous filament when changing the first colorant to the second colorant at least as a result of residual first colorant in the first secondary extruder; and

the waste bulked continuous filament is less than about one hundred pounds of bulked continuous filament.

13. A method of manufacturing at least four colors of bulked continuous carpet filament from polyethylene terephthalate (PET) using a single multi-screw extruder, the method comprising:

(A) providing a multi-screw extruder;

(B) using the multi-screw extruder to at least partially melt the PET into a polymer melt and at least partially purify the polymer melt;

(C) after the step of using the multi-screw extruder to at least partially melt the PET into a polymer melt and at least partially purify the polymer melt, splitting the polymer melt into at least four individual polymer streams downstream from the multi-screw extruder;

(D) providing, for each of the at least four individual polymer streams, a respective secondary extruder;

(E) using each the respective secondary extruder to add a respective colorant to each of the at least four individual polymer streams;

(F) providing, for each of the at least four individual polymer streams, one or more respective static mixers, each of the one or more respective static mixers comprising a substantially cylindrical housing and at least thirty six individual static mixing elements disposed within the substantially cylindrical housing;

(G) after the step of using each the respective secondary extruder to add a respective colorant to each of the at least four individual polymer streams, using the one or more respective static mixers to substantially uniformly mix each of the at least four individual polymer streams with the respective colorant; and

(F) after the step of using the one or more respective static mixers to substantially thoroughly mix each of the plurality of individual polymer streams with the respective colorant, forming each of the at least four individual polymer streams into bulked continuous carpet filament.

14. The method of claim 13, wherein the method further comprises:

after the step of using the multi-screw extruder to at least partially melt the PET into a polymer melt and at least partially purify the polymer melt, splitting the polymer melt into at least six individual polymer streams downstream from the multi-screw extruder;

providing, for each of the at least six individual polymer streams, a respective secondary extruder;

using each the respective secondary extruder to add a respective colorant to each of the at least six individual polymer streams;

providing, for each of the at least six individual polymer streams, one or more respective static mixers, each of the one or more respective static mixers comprising a substantially cylindrical housing and at least thirty six individual static mixing elements disposed within the substantially cylindrical housing;

after the step of using each the respective secondary extruder to add a respective colorant to each of the at least six individual polymer streams, using the one or more respective static mixers to substantially uniformly mix each of the at least six individual polymer streams with the respective colorant; and

after the step of using the one or more respective static mixers to substantially thoroughly mix each of the plurality of individual polymer streams with the respective colorant, forming each of the at least six individual polymer streams into bulked continuous carpet filament.

15. The method of claim 14, wherein the PET comprises recycled PET.

16. The method of claim 15, wherein the at least thirty six individual static mixing elements comprise a first static mixing element of a first type and a second static mixing element of a second type.

17. The method of claim 16, wherein the first static mixing element of the first type comprises a helical mixing element.

18. A method of manufacturing at least four colors of bulked continuous carpet filament from recycled polyethylene terephthalate (PET) bottles using a single multi-screw extruder:

(A) providing a plurality of recycled PET bottles

(B) grinding the plurality of recycled PET bottles into a group of polymer flakes, the group of flakes comprising a first plurality of flakes that consist essentially of PET and a second plurality of flakes that do not consist essentially of PET;

(C) washing the group of polymer flakes to remove at least a portion of one or more contaminants from a surface of the polymer flakes;

(D) after the step of washing the first plurality of flakes;

(i) scanning the washed group of flakes to identify the second plurality of flakes,

(ii) separating the second plurality of flakes from the first plurality of flakes;

(E) providing a multi-screw extruder that comprises;

(i) a first satellite screw extruder, the first satellite screw extruder comprising a first satellite screw that is mounted to rotate about a central axis of the first satellite screw;

(ii) a second satellite screw extruder, the second satellite screw extruder comprising a second satellite screw that is mounted to rotate about a central axis of the second satellite screw;

(iii) a third satellite screw extruder, the third satellite screw extruder comprising a third satellite screw that is mounted to rotate about a central axis of the third satellite screw;

(iv) a fourth satellite screw extruder, the fourth satellite screw extruder comprising a fourth satellite screw that is mounted to rotate about a central axis of the fourth satellite screw; and

(v) a pressure regulation system that is adapted to maintain a pressure within the first, second, third, and fourth satellite screw extruders between about 0 millibars and about 5 millibars,

(F) using the pressure regulation system to reduce a pressure within the first, second, third, and fourth satellite screw extruders to between about 0 millibars and about 5 millibars;

(G) using the multi-screw extruder to at least partially melt the first plurality of flakes into a polymer melt and at least partially purify the polymer melt by, while maintaining the pressure within the first, second, third, and fourth satellite screw extruders between about 0 millibars and about 5 millibars, passing the polymer melt through the multi-screw extruder so that;

(1) a first portion of the melt passes through the first satellite screw extruder, (2) a second portion of the melt passes through the second satellite screw extruder, (3) a third portion of the melt passes through the third satellite screw extruder, and (4) a fourth portion of the melt passes through the fourth satellite screw extruder;

(H) after the step of using the multi-screw extruder to at least partially melt the first plurality of flakes into a polymer melt and at least partially purify the polymer melt, splitting the polymer melt into at least four individual polymer streams downstream from the multi-screw extruder, the at least four individual polymer streams comprising a first polymer stream, a second polymer stream, a third polymer stream, and a fourth polymer stream;

(I) adding a first colorant to the first polymer stream, a second colorant to the second polymer stream, a third colorant to the third polymer stream, and a fourth colorant to the fourth polymer stream;

(J) providing, for the first polymer stream, one or more first static mixers comprising at least 36 first static mixing elements;

(K) providing, for the second polymer stream, one or more second static mixers comprising at least 36 second static mixing elements;

(L) providing, for the third polymer stream, one or more third static mixers comprising at least 36 third static mixing elements;

(M) providing, for the fourth polymer stream, one or more fourth static mixers comprising at least 36 fourth static mixing elements;

(N) after the step of adding the first colorant to the first polymer stream, using the one or more first static mixers to substantially mix the first polymer stream with the first colorant;

(O) after the step of adding the second colorant to the second polymer stream, using the one or more second static mixers to substantially mix the second polymer stream with the second colorant;

(P) after the step of adding the third colorant to the third polymer stream, using the one or more third static mixers to substantially mix the third polymer stream with the third colorant;

(Q) after the step of adding the fourth colorant to the fourth polymer stream, using the one or more fourth static mixers to substantially mix the fourth polymer stream with the fourth colorant;

(R) providing a first spinning machine, a second spinning machine, a third spinning machine, and a fourth spinning machine;

(S) after the step of using the one or more first static mixers to substantially mix the first polymer stream with the first colorant, forming the first polymer stream into a first colored bulked continuous carpet filament using the first spinning machine to form the first polymer stream into the first colored bulked continuous carpet filament;

(T) after the step of using the one or more second static mixers to substantially mix the second polymer stream with the second colorant, forming the second polymer stream into a second colored bulked continuous carpet filament using the second spinning machine to form the second polymer stream into the second colored bulked continuous carpet filament;

(U) after the step of using the one or more third static mixers to substantially mix the third polymer stream with the third colorant, forming the third polymer stream into a third colored bulked continuous carpet filament using the third spinning machine to form the third polymer stream into the third colored bulked continuous carpet filament; and

(V) after the step of using the one or more fourth static mixers to substantially mix the fourth polymer stream with the fourth colorant, forming the fourth polymer stream into a fourth colored bulked continuous carpet filament using the fourth spinning machine to form the fourth polymer stream into the fourth colored bulked continuous carpet filament.

19. The method of claim 19, wherein:

the first colorant comprises a first liquid colorant;

the second colorant comprises a second liquid colorant;

the third colorant comprises a third liquid colorant;

the fourth colorant comprises a fourth liquid colorant;

the method further comprises providing a first pump operatively coupled to the first polymer stream via a first hose, a second pump operatively coupled to the second polymer stream via a second hose, a third pump operatively coupled to the third polymer stream via a third hose, and a fourth pump operatively coupled to the fourth polymer stream via a fourth hose;

adding the first colorant to the first polymer stream comprises using the first pump to pump the first colorant into the first polymer stream via the first hose;

adding the second colorant to the second polymer stream comprises using the second pump to pump the second colorant into the second polymer stream via the second hose;

adding the third colorant to the third polymer stream comprises using the third pump to pump the third colorant into the third polymer stream via the third hose;

adding the fourth colorant to the fourth polymer stream comprises using the fourth pump to pump the fourth colorant into the fourth polymer stream via the fourth hose.

20. The method of claim 19, further comprising:

providing a fifth colorant comprising a fifth liquid colorant,

providing a fifth hose;

changing the first colorant to the fifth colorant for the first polymer stream by;

ceasing adding the first colorant to the first polymer stream;

replacing the first house with the fifth house; and

adding the fifth colorant to the first polymer stream by using the first pump to pump the fifth colorant into the first polymer stream via the fifth hose;

after the step of adding the fifth colorant to the first polymer stream, using the one or more first static mixers to substantially mix the first polymer stream with the fifth colorant;

after the step of using the one or more first static mixers to substantially mix the first polymer stream with the fifth colorant, forming the first polymer stream into a fifth colored bulked continuous carpet filament using the first spinning machine to form the first polymer stream into the fifth colored bulked continuous carpet filament.