POLYETHYLENE TEREPHTHALATE COLORING SYSTEMS AND RELATED METHODS

• US 20180127893A1
• Filed: 11/06/2017
• Published: 05/10/2018
• Est. Priority Date: 11/10/2016
• Status: Abandoned Application

• Current Assignee: Aladdin Manufacturing Corporation (Mohawk Industries Incorporated)
• Original Assignee: Mohawk Industries Incorporated
• Inventors: Clark, Thomas R.
• Application Number:
  US15/804,501
• Publication Number:
  US 20180127893A1
• Time in Patent Office: Days
• CPC Class Codes: B29B 17/0042 for shaping parts, e.g. multilayered parts with at least one layer containing regenerated plastic
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29B 17/0412 to large particles, e.g. beads, granules, flakes, slices
• CPC Class Codes: B29B 2017/0203 Separating plastics from plastics
• CPC Class Codes: B29B 2017/0279 Optical identification, e.g. cameras or spectroscopy
• CPC Class Codes: B29B 2017/0289 Washing the materials in liquids
• CPC Class Codes: B29B 7/325 Static mixers in general B01F25/42
• CPC Class Codes: B29B 7/60 for feeding, e.g. end guides for the incoming material B29B7/7615 takes precedence; feeding predetermined amounts for mixing in general B01F35/714
• CPC Class Codes: B29B 7/726 Measuring properties of mixture, e.g. temperature or density B29B7/724 takes precedence
• CPC Class Codes: B29B 7/7461 Combinations of dissimilar mixers
• CPC Class Codes: B29B 7/88 Adding charges , i.e. additives
• CPC Class Codes: B29B 7/885 with means for treating, e.g. milling, the charges B29B7/905 takes precedence
• CPC Class Codes: B29B 7/94 Liquid charges
• CPC Class Codes: B29C 48/362 using static mixing devices
• CPC Class Codes: B29C 48/44 Planetary screws
• CPC Class Codes: B29K 2067/003 PET, i.e. poylethylene terephthalate
• CPC Class Codes: C08G 63/183 Terephthalic acids
• CPC Class Codes: D01D 1/065 Addition and mixing of substances to the spinning solution or to the melt; Homogenising
• CPC Class Codes: D01D 1/09 Control of pressure, temperature or feeding rate
• CPC Class Codes: D01D 5/0023 the material being a polymer melt
• CPC Class Codes: D01D 5/08 : Melt spinning methods D01D5/0023 takes precedence
• CPC Class Codes: D01F 1/04 : Pigments
• CPC Class Codes: D01F 1/06 : Dyes
• CPC Class Codes: D01F 6/62 : from polyesters
• CPC Class Codes: D06P 1/0004 : General aspects of dyeing
• CPC Class Codes: Y02W 30/62 : Plastics recycling; Rubber recycling

Abstract

A method of manufacturing a plurality of colors of bulked continuous carpet filament from a single multi-screw extruder which, in various embodiments, comprises: (A) passing PET through an extruder that melts the PET and purifies the resulting PET polymer melt; (B) adding a liquid colorant to the polymer melt using a liquid metering system; (C) using one or more static mixers (e.g., up to forty static mixers) to substantially uniformly mix (e.g., homogeneously mix) the polymer melt and the liquid colorant; and (D) feed the uniformly mixed and colored polymer melt into a spinning machines that turns the polymer into filament for use in manufacturing carpet, rugs, and other products.

Claims

1. A method of manufacturing colored bulked continuous carpet filament from a polymer melt comprising polyethylene terephthalate (PET) using liquid colorant, the method comprising:

providing a static mixing assembly comprising at least thirty static mixers;

providing a liquid metering system;

providing a first liquid colorant having a first color;

using the liquid metering system to inject the first liquid into the polymer melt;

after the step of using the liquid metering system to inject the first liquid colorant into the polymer melt, passing the polymer melt and the first liquid colorant through the static mixing assembly to substantially thoroughly mix the polymer melt with the first liquid colorant; and

after the step of passing the polymer melt through the static mixing assembly to substantially thoroughly mix the polymer melt with the first liquid colorant, forming the polymer melt into bulked continuous carpet filament having a color based on the first color.

2. The method of claim 1, the method further comprising:

providing a multi-screw extruder; and

before the step of using the liquid metering system to inject the first liquid colorant into the polymer melt, using the multi-screw extruder to at least partially melt the PET into the polymer melt and at least partially purify the polymer melt;

3. The method of claim 2, the method further comprising:

providing a spinning machine; and

forming the polymer melt into bulked continuous carpet filament using the spinning machine.

4. The method of claim 1, wherein the static mixing assembly comprises forty static mixers.

6. The method of claim 1, further comprising:

providing a second liquid colorant having a second color;

using the liquid metering system to cease injection of the first liquid colorant into the polymer melt;

after the step of using the liquid metering system to cease injection of the first liquid colorant into the polymer melt, using the liquid metering system to inject the second liquid colorant into the polymer melt;

forming the polymer melt into bulked continuous carpet filament having a waste color for at least a color changeover time;

after the color changeover time has passed, passing the polymer melt and the second liquid colorant through the static mixing assembly to substantially thoroughly mix the polymer melt with the second liquid colorant;

after the step of passing the polymer melt through the static mixing assembly to substantially thoroughly mix the polymer melt with the second liquid colorant, forming the polymer melt into bulked continuous carpet filament having a color based on the second color.

7. The method of claim 6, wherein the step of substantially thoroughly mixing the polymer melt with the first liquid colorant comprises substantially thoroughly mixing the polymer melt with the first liquid colorant without using a dynamic mixer.

8. The method of claim 6, wherein the color changeover time is less than about six minutes.

9. The method of claim 6, wherein the bulked continuous filament having the waste color comprises about one doff of bulked continuous filament.

5. The method of claim 5, wherein:

the forty static mixers are structurally identical;

the forty static mixers comprise a first static mixer and a second static mixer;

the first static mixer is disposed adjacent the second static mixer in the static mixing assembly;

the first static mixer is disposed in a first orientation relative to the static mixing assembly; and

the second static mixer is disposed in an orientation other than the first orientation.

10. A method of manufacturing colored bulked continuous carpet filament from recycled polyethylene terephthalate (PET) bottles using a single multi-screw extruder:

(A) providing a plurality of recycled PET bottles

(B) grinding the plurality of recycled PET bottles into a group of polymer flakes, the group of flakes comprising a first plurality of flakes that consist essentially of PET and a second plurality of flakes that do not consist essentially of PET;

(C) washing the group of polymer flakes to remove at least a portion of one or more contaminants from a surface of the polymer flakes;

(D) after the step of washing the first plurality of flakes;

(i) scanning the washed group of flakes to identify the second plurality of flakes,

(ii) separating the second plurality of flakes from the first plurality of flakes;

(E) providing a multi-screw extruder that comprises;

(i) a first satellite screw extruder, the first satellite screw extruder comprising a first satellite screw that is mounted to rotate about a central axis of the first satellite screw;

(ii) a second satellite screw extruder, the second satellite screw extruder comprising a second satellite screw that is mounted to rotate about a central axis of the second satellite screw;

(iii) a third satellite screw extruder, the third satellite screw extruder comprising a third satellite screw that is mounted to rotate about a central axis of the third satellite screw;

(iv) a fourth satellite screw extruder, the fourth satellite screw extruder comprising a fourth satellite screw that is mounted to rotate about a central axis of the fourth satellite screw; and

(v) a pressure regulation system that is adapted to maintain a pressure within the first, second, third, and fourth satellite screw extruders between about 0 millibars and about 25 millibars,

(F) using the pressure regulation system to reduce a pressure within the first, second, third, and fourth satellite screw extruders to between about 0 millibars and about 25 millibars;

(G) using the multi-screw extruder to at least partially melt the first plurality of flakes into a polymer melt and at least partially purify the polymer melt by, while maintaining the pressure within the first, second, third, and fourth satellite screw extruders between about 0 millibars and about 5 millibars, passing the polymer melt through the multi-screw extruder so that;

(1) a first portion of the melt passes through the first satellite screw extruder, (2) a second portion of the melt passes through the second satellite screw extruder, (3) a third portion of the melt passes through the third satellite screw extruder, and (4) a fourth portion of the melt passes through the fourth satellite screw extruder;

(H) providing a liquid metering system;

(I) providing a first liquid colorant having a first color;

(J) after the step of using the multi-screw extruder to at least partially melt the first plurality of flakes into the polymer melt and at least partially purify the polymer melt, using the liquid metering system to inject the first liquid into the polymer melt;

(K) providing a static mixing assembly;

(L) passing the polymer melt and the first liquid colorant through the static mixing assembly to substantially thoroughly mix the polymer melt with the first liquid colorant; and

(M) after the step of passing the polymer melt through the static mixing assembly to substantially thoroughly mix the polymer melt with the first liquid colorant, forming the polymer melt into bulked continuous carpet filament having a color based on the first color.

11. The method of claim 10, wherein the static mixing assembly comprises at least thirty two static mixing elements.

12. The method of claim 10, wherein the liquid metering system is configured to inject a substantially continuous dose of the first liquid colorant to the polymer melt.

13. The method of claim 12, wherein the liquid metering system is configured to inject up to about 10 cubic centimeters per second of the first liquid colorant into the polymer melt.

14. The method of claim 13, wherein the method further comprises:

providing a computer controller configured to modify an injection rate of the first liquid colorant into the polymer melt by the liquid metering system; and

using the computer controller to modify the injection rate based at least in part on a desired color of the bulked continuous filament.

15. A method of manufacturing colored bulked continuous carpet filament, the method comprising:

providing a multi-screw extruder that comprises;

a first satellite screw extruder, the first satellite screw extruder comprising a first satellite screw that is mounted to rotate about a central axis of the first satellite screw;

a second satellite screw extruder, the second satellite screw extruder comprising a second satellite screw that is mounted to rotate about a central axis of the second satellite screw; and

a pressure regulation system that is adapted to maintain a pressure within the first and second satellite screw extruders between about 0 millibars and about 10 millibars;

using the pressure regulation system to reduce a pressure within the first and second satellite screw extruders to between about 0 millibars and about 10 millibars;

while maintaining the pressure within the first and second satellite screw extruders between about 0 millibars and about 10 millibars, passing a melt comprising recycled polymer through the multi-screw extruder so that;

(1) a first portion of the melt passes through the first satellite screw extruder, and (2) a second portion of the melt passes through the second satellite screw extruder; and

providing a liquid metering system;

providing a first liquid colorant having a first color;

after the step of passing the polymer melt through the multi-screw extruder, using the liquid metering system to inject the first liquid into the polymer melt;

providing a static mixing assembly comprising at least twenty individual static mixing elements;

passing the polymer melt and the first liquid colorant through the static mixing assembly to substantially thoroughly mix the polymer melt with the first liquid colorant; and

after the step of passing the polymer melt through the static mixing assembly to substantially thoroughly mix the polymer melt with the first liquid colorant, forming the polymer melt into bulked continuous carpet filament having a color based on the first color.

16. The method of claim 15, wherein passing the polymer melt and the first liquid colorant through the static mixing assembly comprises passing the polymer melt and the first liquid colorant through each of the at least twenty individual static mixing elements.

17. The method of claim 15, further comprising:

providing a second liquid colorant having a second color;

using the liquid metering system to cease injection of the first liquid colorant into the polymer melt;

after the step of using the liquid metering system to cease injection of the first liquid colorant into the polymer melt, using the liquid metering system to inject the second liquid colorant into the polymer melt;

after the step of using the liquid metering system to inject the second liquid colorant into the polymer melt, passing the polymer melt and the second liquid colorant through the static mixing assembly to substantially thoroughly mix the polymer melt with the second liquid colorant;

after the step of passing the polymer melt through the static mixing assembly to substantially thoroughly mix the polymer melt with the second liquid colorant, forming the polymer melt into bulked continuous carpet filament having a color based on the second color.

18. The method of claim 17, further comprising:

after the step of ceasing injection of the first liquid colorant into the polymer melt, disposing of at least one doff of waste bulk continuous filament.

19. The method of claim 17, further comprising:

after the step of ceasing injection of the first liquid colorant into the polymer melt, replacing at least one component of the liquid metering system.

20. The method of claim 19, wherein the at least twenty individual static mixing elements comprise at least forty static mixing means.