PNEUMATIC TIRE HAVING A DUAL LAYER TREAD

• US 20180134086A1
• Filed: 11/16/2016
• Published: 05/17/2018
• Est. Priority Date: 11/16/2016
• Status: Active Grant

• Current Assignee: Goodyear Tire & Rubber Company
• Original Assignee: Goodyear Tire & Rubber Company
• Inventors: SCHWEITZER, Claude, THOMAS, Jean-Louis Marie Flicien, AHRENS, Bodo, AGOSTINI, Giorgio, PRAVATA, Laurent Carmelo Joseph Andre, KASZAS, Gabor, BURKE, Karen Karas
• Granted Patent: US 10,427,463 B2
• Time in Patent Office: Days
• CPC Class Codes: B60C 1/0016 Compositions of the tread
• CPC Class Codes: B60C 11/0041 comprising different tread rubber layers
• CPC Class Codes: B60C 11/0058 with different cap rubber layers in the axial direction
• CPC Class Codes: B60C 11/0075 with different base rubber layers in the axial direction
• CPC Class Codes: B60C 2011/016 different rubber for tread wings
• CPC Class Codes: B60C 2011/0341 Circumferential grooves
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08K 3/06 Sulfur
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08K 5/09 Carboxylic acids; Metal salts thereof; Anhydrides thereof
• CPC Class Codes: C08K 5/47 Thiazoles
• CPC Class Codes: C08K 5/548 containing sulfur C08K5/5477 takes precedence
• CPC Class Codes: C08L 2205/035 containing four or more polymers in a blend
• CPC Class Codes: C08L 61/06 of aldehydes with phenols
• CPC Class Codes: C08L 7/00 Compositions of natural rubber
• CPC Class Codes: C08L 9/00 Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
• CPC Class Codes: C08L 9/06 Copolymers with styrene
• CPC Class Codes: C08L 91/06 Waxes
• CPC Class Codes: Y02T 10/86 Optimisation of rolling resistance, e.g. weight reduction

Abstract

The invention relates to a pneumatic tire comprising a carcass and a tread located radially outward of the carcass and extending between the tire sidewalls; the tread providing a radially outermost tread running surface; the tread comprising a first tread layer comprising a first rubber compound and a second tread layer comprising a second rubber compound; wherein the second tread layer is located radially adjacent to the first tread layer; wherein the first rubber compound is compositionally distinct from the second rubber compound; wherein the second tread layer comprises one or more integrally formed extensions of the second tread layer extending radially outwardly toward the tread running surface; wherein each of the integrally formed extensions of the second tread layer comprises a circumferentially continuous groove and a reinforcement zone disposed on a side of the groove; wherein the first rubber compound comprises 100 parts by weight of at least one diene based elastomer, and from 1 to 150 phr of silica; and the second rubber compound comprises a diene base elastomer, from 50 to 120 phr of a filler, wherein at least 20 phr of the filler is a high surface area carbon black having an iodine adsorption number of at least 100 g/kg, from 1 to 45 phr of a methylene acceptor, from 1 to 25 phr of a methylene donor, and from 1 to 30 phr of at least one additive selected from the group consisting of carbamic resins, liquid diene based polymers having a number average molecular weight ranging from 1000 to 25000, and aromatic hydrocarbon resins.

Claims

1. A pneumatic tire comprising a carcass and a tread located radially outward of the carcass and extending between the tire sidewalls;

the tread providing a radially outermost tread running surface;

the tread comprising a first tread layer comprising a first rubber compound and a second tread layer comprising a second rubber compound;

wherein the second tread layer is located radially adjacent to the first tread layer;

wherein the first rubber compound is compositionally distinct from the second rubber compound;

wherein the second tread layer comprises one or more integrally formed extensions of the second tread layer extending radially outwardly toward the tread running surface;

wherein each of the integrally formed extensions of the second tread layer comprises a circumferentially continuous groove and a reinforcement zone disposed on a side of the groove;

wherein the first rubber compound comprises 100 parts by weight of at least one diene based elastomer, and from 1 to 150 phr of silica; and

the second rubber compound comprises a diene base elastomer, from 50 to 120 phr of a filler, wherein at least 20 phr of the filler is a high surface area carbon black having an iodine adsorption number of at least 100 g/kg, from 1 to 45 phr of a methylene acceptor, from 1 to 25 phr of a methylene donor, and from 1 to 30 phr of at least one additive selected from the group consisting of carbamic resins, liquid diene based polymers having a number average molecular weight ranging from 1000 to 25000, and aromatic hydrocarbon resins.

2. The pneumatic tire of claim 1, wherein the reinforcement zone comprises first and second reinforcement zones disposed on axially opposite sides of the groove.

3. The pneumatic tire of claim 1, wherein at least one reinforcement zone extends radially from a radially innermost surface of the groove to the tread running surface.

4. The pneumatic tire of claim 1, wherein at least one reinforcement zone extends radially from a radially innermost surface of the groove and radially partially to the tread running surface.

5. The pneumatic tire of claim 1, wherein the methylene acceptor is selected from the group consisting of resorcinol, resorcinolic derivatives, monohydric phenols and their derivatives, dihydric phenols and their derivatives, polyhydric phenols and their derivatives, unmodified phenol novolak resins, modified phenol novolak resin, phenol formaldehyde resin, resorcinol novolak resins and mixtures thereof.

6. The pneumatic tire of claim 1, wherein the methylene acceptor is a phenol formaldehyde resin.

7. The pneumatic tire of claim 1, wherein the methylene donor is selected from the group consisting of hexamethylenetetramine, hexamethoxymethylmelamine, hexaethoxymethylmelamine, imino-methoxymethylmelamine, imino-isobutoxymethylmelamine, lauryloxymethylpyridinium chloride, ethoxymethylpyridinium chloride trioxan and hexamethoxymethylmelamine, and N-substituted oxymethylmelamines, of the general formula:

8. The pneumatic tire of claim 1, wherein the amount of methylene acceptor ranges from 2 to 30 phr.

9. The pneumatic tire of claim 1, wherein the amount of methylene donor ranges from 2 to 20 phr.

10. The pneumatic tire of claim 1, wherein the copolymer resin of styrene and α

-methyl styrene comprises from 40 to 70 weight percent units derived from styrene and, from 60 to 30 weight percent units derived from α

-methylstyrene.

11. The pneumatic tire of claim 1, wherein the copolymer resin of styrene and α

-methyl styrene has a softening point according to ASTM No. E-28 in a range of 80°

C. to 145°

C.

12. The pneumatic tire of claim 1, wherein the amount of copolymer resin of styrene and α

-methyl styrene ranges from 5 to 25 phr.

13. The pneumatic tire of claim 1, wherein the second rubber composition further comprises a carbamic resin.

14. The pneumatic tire of claim 1, wherein the second rubber composition further comprises a carbamic resin derived from a monofunctional or multifunctional aldehyde A, and an organic compound C having at least one carbamate group —

O—

CO—

NH₂, and an organic radical, where the radical can be a monovalent radical R selected from the group consisting of linear, branched or cyclic aliphatic radicals having from one to thirty carbon atoms, and aralkyl radicals, or a divalent organic radical —

R′

—

selected from the group consisting of linear, branched or cyclic aliphatic diradicals having from two to thirty carbon atoms and bisalkyl aryl radicals having from 8 to 30 carbon atoms.

15. The pneumatic tire of claim 1, wherein the second rubber composition further comprises a carbamic resin derived from n-butylcarbamate and formaldehyde.

16. The pneumatic tire of claim 13, wherein the amount of carbamic resin ranges from 1 to 15 phr.

17. The pneumatic tire of claim 1, wherein the second rubber composition comprises a liquid diene based polymers having a number average molecular weight ranging from 1000 to 25000.

18. The pneumatic tire of claiml, wherein the first rubber compound comprises less than 50 phr of filler, a first rubber with a glass transition temperature above −

25°

C., and a second rubber with a glass transition temperature below −

40°

C.

19. The pneumatic tire of claim 18, wherein the first rubber is 3,4-polyisoprene or styrene-butadiene rubber with a bound styrene content larger than 45% by weight, and the second rubber is selected from the group consisting of natural rubber, high cis synthetic polyisoprene, and high-cis polybutadiene having a cis 1,4 content greater than 95 percent and a Tg ranging from −

80 to −

110°

C.

20. The pneumatic tire of claim 18, wherein the first rubber is an emulsion polymerized styrene butadiene rubber comprising more than 45 percent by weight of bound styrene, more than 98 percent of the repeat units derived from styrene in blocks containing less than five repeat units, and a Tg greater than −

25°

C.