PROCESS AND APPARATUS FOR RECOVERING HYDROGEN FROM HYDROPROCESSED STRIPPER OFF GAS

• US 20180280863A1
• Filed: 06/04/2018
• Published: 10/04/2018
• Est. Priority Date: 12/18/2015
• Status: Active Grant

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Sood, Simmi, Zhu, Xin X.
• Granted Patent: US 11,033,853 B2
• Time in Patent Office: Days
• CPC Class Codes: B01D 2256/24 Hydrocarbons
• CPC Class Codes: B01D 2257/108 Hydrogen
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: C01B 3/501 by diffusion
• CPC Class Codes: C01B 3/56 by contacting with solids; Regeneration of used solids C01B3/508 takes precedence
• CPC Class Codes: C10G 2300/207 Acid gases, e.g. H2S, COS, SO2, HCN
• CPC Class Codes: C10G 2300/4081 Recycling aspects
• CPC Class Codes: C10G 67/02 plural serial stages only
• CPC Class Codes: C10G 7/00 Distillation of hydrocarbon oils

Abstract

A stripper off gas stream from a low pressure hydroprocessing unit may be routed to a hydrogen recovery unit to recover hydrogen. The stripper off gas stream may be scrubbed of acid gases and then compressed to hydrogen recovery pressure before it is subjected to hydrogen recovery such as in a pressure swing adsorption unit to recover high purity hydrogen.

Claims

1. A hydroprocessing process comprising:

hydroprocessing a hydrocarbon feed stream in a hydroprocessing reactor to provide a hydroprocessing effluent stream;

separating said hydroprocessing effluent stream in a separator to provide a gaseous stream and a liquid stream;

stripping light gases from said liquid stream to provide a stripper off gas stream and a stripped hydroprocessed stream;

compressing said stripper off gas stream; and

recovering hydrogen from said stripper off gas stream.

2. The process of claim 1 wherein recovering hydrogen from said stripper off gas stream comprises adsorbing impurities from hydrogen in said stripper off gas stream to provide a hydrogen stream.

3. The process of claim 1 further comprising absorbing acid gases from said stripper off gas stream prior to compression.

4. The process of claim 1 further comprising separating said separator gaseous stream in a cold separator to provide a cold gaseous stream and a cold liquid stream and stripping said cold liquid stream to provide said stripper off gas stream.

5. The process of claim 4 further comprising stripping said cold liquid stream and said hot liquid stream together.

6. The process of claim 1 further comprising storing said stripped hydroprocessed stream as product.

7. The process of claim 1 further comprising stripping said light gases from said separator liquid stream at less than 2.0 MPa (g) (300 psig).

8. The process of claim 1 further comprising cooling a stripper overhead off gas stream and separating said stripper overhead off gas stream into said stripper off gas stream and a stripper overhead liquid stream.

9. The process of claim 1 further comprising hydroprocessing said hydrocarbon feed stream at a pressure of no more than 6.9 MPa (gauge) (1000 psig).

10. The process of claim 1 further comprising pressuring said stripper off gas stream to a pressure of about 2200 kPa (gauge) (320 psig) to about 3100 kPa (gauge) (450 psig).

11. A hydroprocessing process comprising:

hydroprocessing a hydrocarbon feed stream in a hydroprocessing reactor at a pressure of no more than 6.9 MPa (gauge) (1000 psig) to provide a hydroprocessing effluent stream;

separating said hydroprocessing effluent stream in a separator to provide a gaseous stream and a liquid stream;

stripping light gases from said liquid stream to provide a stripper off gas stream and a stripped hydroprocessed stream;

compressing said stripper off gas stream; and

recovering hydrogen from said stripper off gas stream by adsorbing impurities from hydrogen in said stripper off gas stream to provide a hydrogen stream.

12. The process of claim 11 further comprising separating said separator gaseous stream in a cold separator to provide a cold gaseous stream and a cold liquid stream and stripping said cold liquid stream to provide said stripper off gas stream.

13. The process of claim 12 further comprising stripping said cold liquid stream and said hot liquid stream together.

14. The process of claim 11 further comprising absorbing acid gases from said stripper off gas stream prior to compression.

15. The process of claim 11 further comprising storing said stripped hydroprocessed stream as product.

16. The process of claim 11 further comprising stripping said light gases from said separator liquid stream at less than 2.0 MPa (g) (300 psig).

17. A hydroprocessing apparatus comprising:

a hydrotreating reactor;

a separator in communication with said hydrotreating reactor;

a stripping column in communication with a bottoms line of said separator;

a compressor in communication with an overhead line from said stripping column; and

a hydrogen recovery unit in communication with an overhead of said stripping column.

18. The apparatus of claim 17 further comprising an absorption column in downstream communication with said overhead line of said stripping column and said hydrogen recovery unit is in downstream communication with said absorption column.

19. The apparatus of claim 17 wherein said hydrogen recovery unit is a pressure swing adsorption unit.

20. The apparatus of claim 18 further comprising a cold separator in downstream communication with an overhead line of said separator and said stripping column is in downstream communication with a bottoms line of said cold separator.