COMPOUND AND INTERMEDIATE THEREOF

• US 20190308931A1
• Filed: 06/23/2017
• Published: 10/10/2019
• Est. Priority Date: 06/28/2016
• Status: Active Grant

• Current Assignee: Dai Nippon Printing Company Limited, Yamamoto Chemicals, Inc. (Mitsui Chemicals)
• Original Assignee: Dai Nippon Printing Company Limited
• Inventors: OKADA, Masato, YOSHIDA, Takafumi, KINOSHITA, Satoshi
• Granted Patent: US 10,640,456 B2
• Time in Patent Office: Days
• CPC Class Codes: B01J 31/00 Catalysts comprising hydrides, coordination complexes or organic compounds catalyst compositions used only in polymerisation reactions C08 ; catalytic antibodies C12N9/0002
• CPC Class Codes: B01J 31/04 containing carboxylic acids or their salts B01J31/0277 - B01J31/0298 take precedence; multi-metal carboxylate complexes like Pd (II) acetate, i.e. Pd3 (OAc) 6 or Cr(II)acetate, i.e. Cr2(OAc)4 B01J31/2226
• CPC Class Codes: C07C 211/53 having the nitrogen atom of at least one of the amino groups further bound to a hydrocarbon radical substituted by amino groups
• CPC Class Codes: C07C 211/64 having quaternised nitrogen atoms bound to carbon atoms of six-membered aromatic rings
• CPC Class Codes: C07C 251/20 having carbon atoms of imino groups being part of rings other than six-membered aromatic rings
• CPC Class Codes: C07C 2601/14 The ring being saturated
• CPC Class Codes: C07C 2602/42 the bicyclo ring system containing seven carbon atoms
• CPC Class Codes: C09B 11/12 without any OH group bound to an aryl nucleus
• CPC Class Codes: C09B 11/16 Preparation from diarylketones or diarylcarbinols , e.g. benzhydrol
• CPC Class Codes: C09B 11/24 Phthaleins containing amino groups ; Phthalanes; Fluoranes; Phthalides; Rhodamine dyes; Phthaleins having heterocyclic aryl rings; Lactone or lactame forms of triarylmethane dyes
• CPC Class Codes: C09B 69/02 Dyestuff salts, e.g. salts of acid dyes with basic dyes for Na, K or NH4+ salts or for chlorides, sulfates or chlorozincates, see the relevant dye groups
• CPC Class Codes: C09B 69/103 containing a diaryl- or triarylmethane dye
• CPC Class Codes: C09B 69/109 containing other specific dyes

Abstract

A compound represented by the following general formula (I):

(the symbols in the general formula (I) are as described in the Description),

• • wherein the compound contains one or more structures selected from the following (i) and (ii):
  • (i) “A” is an aliphatic hydrocarbon group containing two or more alicyclic hydrocarbon groups, containing a saturated aliphatic hydrocarbon group at a terminal position directly bound to “N”, and optionally containing O, S, N in a carbon chain
  • (ii) at least one of R², R³, R⁴ and R⁵ is a cycloalkyl group optionally containing a substituent group or an aryl group optionally containing a substituent group.

Claims

1. A compound represented by the following general formula (I):

3. The compound according to claim 1, wherein the compound further contains a structure represented by the following (ii):

(ii) at least one of R², R³, R⁴ and R⁵ is a cycloalkyl group optionally containing a substituent group or an aryl group optionally containing a substituent group.

4. The compound according to claim 1, wherein at least one of R², R³, R⁴ and R⁵ is a substituent group represented by the following formula (III) or (IV):

5. The compound according to claim 1, wherein “

A”

is a substituent group represented by the following general formula (V);

6. The compound according to claim 3, wherein “

A”

is a substituent group represented by the following general formula (V);

7. The compound according to claim 5, wherein Ar¹ is a divalent condensed polycyclic aromatic hydrocarbon group optionally containing a substituent group.

11. An intermediate for production of the compound defined by claim 7, wherein the intermediate is represented by the following general formula (VI):

2. A compound represented by the following general formula (II):

8. The compound according to claim 2, wherein the anion represented by B^c−

is a heteropolyoxometalate containing one or more elements selected from tungsten and molybdenum.

9. The compound according to claim 8, wherein at least one of R², R³, R⁴ and R⁵ is a substituent group represented by the following formula (III) or (IV):

10. The compound according to claim 8, wherein “

A”

is a substituent group represented by the following general formula (V);

12. The compound according to claim 2, wherein the compound further contains a structure represented by the following (ii):

(ii) at least one of R², R³, R⁴ and R⁵ is a cycloalkyl group optionally containing a substituent group or an aryl group optionally containing a substituent group.

13. The compound according to claim 2, wherein at least one of R², R³, R⁴ and R⁵ is a substituent group represented by the following formula (III) or (IV):

14. The compound according to claim 2, wherein “

A”

is a substituent group represented by the following general formula (V);

15. The compound according to claim 12, wherein “

A”

is a substituent group represented by the following general formula (V);

16. The compound according to claim 14, wherein Ar¹ is a divalent condensed polycyclic aromatic hydrocarbon group optionally containing a substituent group.