RARE-EARTH REGENERATOR MATERIAL PARTICLES, AND GROUP OF RARE-EARTH REGENERATOR MATERIAL PARTICLES, REFRIGERATOR AND MEASURING APPARATUS USING THE SAME, AND METHOD FOR MANUFACTURING THE SAME

• US 20190309203A1
• Filed: 06/25/2019
• Published: 10/10/2019
• Est. Priority Date: 08/25/2009
• Status: Active Grant

• Current Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Original Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation)
• Inventors: YAMADA, Katsuhiko, Fuse, Keiichi
• Granted Patent: US 10,907,081 B2
• Time in Patent Office: Days
• CPC Class Codes: B22F 9/08 by casting, e.g. through sieves or in water, by atomising or spraying using electric discharge B22F9/14
• CPC Class Codes: B22F 9/10 using centrifugal force
• CPC Class Codes: B23P 15/26 heat exchangers or the like making heat exchangers by methods covered by other subclasses B21D53/02
• CPC Class Codes: C09K 5/041 for compression-type refrigeration systems
• CPC Class Codes: C09K 5/08 Materials not undergoing a change of physical state when used C09K5/16, C09K5/20 take precedence
• CPC Class Codes: C09K 5/14 Solid materials, e.g. powdery or granular
• CPC Class Codes: C22C 2202/02 Magnetic
• CPC Class Codes: F25B 2309/003 characterised by construction or composition of the regenerator
• CPC Class Codes: F25B 2309/1415 Pulse-tube cycles characterised by regenerator details
• CPC Class Codes: F25B 9/14 characterised by the cycle used, e.g. Stirling cycle
• CPC Class Codes: F25B 9/145 pulse-tube cycle
• CPC Class Codes: G01R 33/3804 Additional hardware for cooling or heating of the magnet assembly, for housing a cooled or heated part of the magnet assembly or for temperature control of the magnet assembly
• CPC Class Codes: G01R 33/3815 with superconducting coils, e.g. power supply therefor
• CPC Class Codes: H01F 1/015 Metals or alloys
• CPC Class Codes: Y10T 428/12014 having metal particles

Abstract

Provided is a group of rare-earth regenerator material particles having an average particle size of 0.01 to 3 mm, wherein the proportion of particles having a ratio of a long diameter to a short diameter of 2 or less is 90% or more by number, and the proportion of particles having a depressed portion having a length of 1/10 to ½ of a circumferential length on a particle surface is 30% or more by number. By forming the depressed portion on the surface of the regenerator material particles, it is possible to increase permeability of an operating medium gas and a contact surface area with the operating medium gas.

Claims

1-17. -17. (canceled)

18. A method of manufacturing a Gifford MacMahon type (GM) refrigerator for accumulating an extremely low temperature cold, comprising:

providing a vacuum chamber;

providing an external cylinder so as to be disposed in the vacuum chamber, the external cylinder enclosing an inner space;

providing at least one regenerator container for accumulating cold which is arranged at the inner space inside of the external cylinder;

installing a seal ring between the external cylinder and the regenerator container;

forming an expanding chamber between the external cylinder and the regenerator container;

combining a compressor for compressing a cooling medium gas; and

packing a group of regenerator material particles in the regenerator container;

wherein the group of regenerator material particles have an average particle size of 0.045 to 3 mm,

wherein a proportion of particles having a ratio of a long diameter to a short diameter of 2 or less is 90% or more by number, a proportion of particles having a depressed portion having a length of 1/10 to ½

of a particle circumferential length of a particle on a particle surface is 30% or more by number and wherein the depressed portion has depth of 1/10 or less of a particle diameter.

19. The method according to claim 18, wherein two or more stages of regenerator material-filled zones are formed through a mesh material in at least one regenerator container, and the group of regenerator material particles are packed in at last one stage of the regenerator material-filled zones.

20. The method according to claim 19, wherein metal mesh-like members as the mesh material are packed in at least one stage of the regenerator material-filled zones.

21. The method according to claim 20, wherein the mesh material comprising a metal mesh-like member composed of copper or a copper alloy is packed.

22. The method according to claim 20, wherein the metal mesh-like members are packed in a regenerator material-filled zone which is located at a higher temperature side than the regenerator material-filled zone into which the group of regenerator material particles are packed.

23. The method according to claim 18, wherein two or more regenerator containers are connected.

24. The method according to claim 23, wherein the method further comprised the step of packing the mesh material comprising a metal mesh-like member composed of copper or a copper alloy.

25. The method according to claim 18, wherein the refrigerator is used for forming an extremely low temperature cold zone having a temperate of lower than 10K.

26. The method according to claim 18, wherein the group of regenerator material particles comprises at least one element selected from a group consisting of yttrium (Y), lanthanum (La), Cecerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), and ytterbium (Yb).

27. The method according to claim 18, wherein the group of regenerator material particles comprise at least one substance selected from a group consisting of a rare-earth element of single substance, and alloy with Cu (including an intermetallic compound), a rare-earth with Ni (including an intermetallic compound), a rare-earth oxide (including a rare-earth complex oxide), and a rare-earth sulfide.

28. The method according to claim 18, wherein the regenerator material particles comprise at least one substance selected from the group consisting of Nd, Er₃Ni, ErNi, HoCu₂, Gd₂O₃ and Gd₂O₂S.

29. A method of manufacturing a superconducting magnet provided with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the GM refrigerator manufactured by the method according to claim 18.

30. A method of manufacturing a measuring apparatus provided with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the GM refrigerator manufactured by the method according claim 18.

31. A method of manufacturing an MRI provided with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the GM refrigerator manufactured by the method according to claim 18.

32. A method of manufacturing a NMR provide with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the GM refrigerator manufactured by the method according to claim 18.

33. A method of manufacturing a cryopump provided with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the GM refrigerator manufactured by the method according to claim 18.

34. A method of manufacturing a pulse tube refrigerator for accumulating an extremely low temperature cold, comprising:

providing at least one regenerator unit; and

packing a group of regenerator material particles in the regenerator container;

wherein the group of regenerator material particles have an average particle size of 0.045 to 3 mm,

wherein a proportion of particles having a ratio of a long diameter to a short diameter of 2 or less is 90% or more by number, a proportion of particles having a depressed portion having a length of 1/10 to ½

of a particle circumferential length of a particle on a particle surface is 30% or more by number, and

wherein the depressed portion has a depth of 1/10 or less of a particle diameter.

35. The method according to claim 34, wherein the pulse tube refrigerator is a two-staged pulse tube refrigerator comprising two regenerator units.

36. The method according to claim 34, wherein the pulse tube refrigerator is a multi-staged pulse tube refrigerator comprising two or more regenerator units.

37. The method according to claim 34, wherein the group of regenerator material particles comprises at least one element selected from a group consisting of yttrium (Y), lanthanum (La), Cecerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), and ytterbium (Yb).

38. The method according to claim 34, wherein the group of regenerator material particles comprise at least one substance selected from a group consisting of a rare-earth element of single substance, and alloy with Cu (including an intermetallic compound), a rare-earth with Ni (including an intermetallic compound), a rare-earth oxide (including a rare-earth complex oxide), and a rare-earth sulfide.

39. The method according to claim 34, wherein the regenerator material particles comprise at least one substance selected from the group consisting of Nd, Er₃Ni, ErNi, HoCu₂, Gd₂O₃ and Gd₂O₂S.

40. A method of manufacturing a superconducting magnet provided with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the pulse tube refrigerator manufactured by the method according to claim 34.

41. A method of manufacturing a measuring apparatus provided with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the pulse tube refrigerator manufactured by the method according to claim 34.

42. A method of manufacturing an MRI provided with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the pulse tube refrigerator manufactured by the method according to claim 34.

43. A method of manufacturing a NMR provide with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the pulse tube refrigerator manufactured by the method according to claim 34.

44. A method of manufacturing a cryopump provided with a refrigerator for accumulating an extremely low temperature cold,

wherein the refrigerator is the pulse tube refrigerator manufactured by the method according to claim 34.