METHOD AND SYSTEM FOR PRODUCING AN ARTICLE BY LAYER-BY-LAYER BUILDUP IN A STAMPING PROCESS

• US 20190315062A1
• Filed: 11/22/2017
• Published: 10/17/2019
• Est. Priority Date: 11/22/2016
• Status: Active Application

• Current Assignee: Covestro Deutschland AG
• Original Assignee: Covestro Deutschland AG
• Inventors: ACHTEN, Dirk, BUSGEN, Thomas, TOMCZYK, Christoph, WAGNER, Roland, METTMANN, Bettina, DIJKSTRA, Dirk, AKBAS, Levent, GUEDOU, Arnaud
• Application Number:
  US16/462,268
• Publication Number:
  US 20190315062A1
• Time in Patent Office: Days
• CPC Class Codes: B29C 64/153 using layers of powder being selectively joined, e.g. by selective laser sintering or melting
• CPC Class Codes: B29C 64/264 Arrangements for irradiation
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 30/00 Apparatus for additive manufacturing; Details thereof or accessories therefor

Abstract

A method for producing an article in which a layer (200) of meltable polymer is selectively melted at least partially. This takes place according to a selected cross section of the article to be formed. The at least partially melted material is added on layer by layer to a carrier (500) or to previous layers bonded to the carrier (500). A system that is suitable for carrying out the method according to the invention has a substrate (100), a control unit (600), an application unit (700) for applying the particles to the substrate (100), an energy exposure unit (700) and a contacting unit (800).

Claims

1-15. -15. (canceled)

16. A process for producing an article comprising the steps of:

I) providing a layer on a substrate, wherein the layer contains a meltable polymer;

II) energizing a selected portion of the layer provided in step I) corresponding to a first selected cross section of the article so that the layer in the selected portion is at least partially melted and at least one at least partially melted volume is obtained;

III) contacting the at least one volume obtained in step II) with a carrier so that the at least one volume is joined to the carrier;

IV) removing the carrier including the at least one volume joined to the carrier from the substrate;

V) providing a further layer on the substrate or on a further substrate, wherein the layer contains a meltable polymer;

VI) energizing a selected portion of the layer provided in step V) corresponding to a further selected cross section of the article so that the layer in the selected portion is at least partially melted and at least one at least partially melted volume is obtained;

VII) contacting the at least one volume obtained in step VI) with at least one of the volumes previously joined to the carrier so that the volume obtained in step VI) is joined to at least one of the volumes previously joined to the carrier;

VIII) removing the carrier including the volumes joined to the carrier from the substrate;

IX) repeating steps V) to VIII) until the article is formed.

17. The process as claimed in claim 16, wherein the steps II) and/or VI) are performed such that the energizing of the selected portion of the layer is carried out by irradiation with an energy beam or a plurality of energy beams.

18. The process as claimed in claim 16, wherein the steps II) and/or VI) are performed such that they comprise initially applying a liquid onto the selected portion of the layer, wherein the liquid increases the absorption of energy in the regions of the layer contacted by it relative to the regions not contacted by it, and subsequently subjecting the layer to an energy source.

19. The process as claimed in claim 16, wherein the steps I) and/or V) are performed such that a layer comprising particles is applied to the substrate, wherein the particles contain a meltable polymer.

20. The process as claimed in claim 16, wherein the steps I) and/or V) are performed such that a film containing a meltable polymer is provided, wherein the film is arranged on a carrier film as a substrate.

21. The process as claimed in claim 16, wherein the contacting in step III) and/or step VII) is performed such that it comprises performing a relative movement of the carrier toward the substrate, monitoring the distance between the carrier and the substrate and/or between the carrier and the surface of the layer and interrupting the relative movement upon falling below a predetermined distance.

22. The process as claimed in claim 16, wherein the contacting in step III) and/or step VII) is performed such that it comprises performing a relative movement of the carrier toward the substrate, monitoring the contact pressure between the carrier and the substrate and/or between the carrier and the surface of the layer and interrupting the relative movement upon exceedance of a predetermined contact pressure.

23. The process as claimed in claim 16, wherein the meltable polymer is selected such that a droplet of the meltable polymer in the molten state has a contact angle to the substrate used in the process of ≥

60°

to ≤

180°

and/or

the meltable polymer is selected such that a droplet of the meltable polymer in the molten state has a contact angle to the carrier used in the process of ≥

0°

to ≤

90°

.

24. The process as claimed in claim 16, wherein the steps II) and/or VI) are performed such that the at least one obtained volume does not contact the substrate.

25. The process as claimed in claim 16, wherein the steps II) and/or VI) are performed such that after the at least partial melting of the particles their molten material at a temperature of ≥

20°

C. above the melting point of their material has a storage modulus G′

(determined by viscometric measurement with a plate/plate oscillation shear viscometer at an angular frequency of 1/s) of ≥

5·

10³ Pa to ≤

1·

10⁷ Pa.

26. The process as claimed in claim 16, wherein the steps III) and/or VII) are performed such that volumes previously joined to the carrier have a storage modulus G′

(determined by viscometric measurement with a plate/plate oscillation shear viscometer at an angular frequency of 1/s) of >

1·

10⁷ Pa.

27. The process as claimed in claim 16, wherein the meltable polymer is selected from the group consisting of polyurethane, polyester, polyalkylene oxide, plasticized PVC, polyamide, protein, PEEK, PEAK, polypropylene, polyethylene, thermoplastic elastomer, POM, polyacrylate, polymethylmethacrylate, polystyrene, polycarbonate or a combination of at least two of these.

28. The process as claimed in claim 16, wherein the substrate is in the form of a movable conveyor belt having a side carrying the layer comprising particles.

29. A system for performing the process as claimed in claim 16 comprising:

a control unit;

a substrate;

an application unit for providing a layer on a substrate, wherein the layer contains a meltable polymer;

an energizing unit for energizing a selected portion of the layer corresponding to a selected cross section of an article to be produced so that the layer in the selected portion are at least partially melted and an at least partially melted volume or a plurality of at least partially molten volumes are obtained;

a contacting unit for contacting the volume or volumes obtained via the energizing unit and for removing this volume or volumes from the substrate;

wherein the energizing unit performs the energizing under command of the control unit and the contacting unit performs the contacting under command of the control unit.

30. The system as claimed in claim 29, wherein

the substrate is in the form of a movable conveyor belt having a side carrying a layer comprising particles and this side has a movement direction;

the energizing unit is in the form of an irradiation unit;

the application unit is arranged upstream of the energizing in the movement direction of the substrate and

the energizing unit is arranged upstream of the contacting unit in the movement direction of the substrate.