DETERGENT COMPOSITION COMPRISING PHOSPHINOSUCCINIC ACID ADDUCTS AND METHODS OF USE

• US 20190316063A1
• Filed: 06/26/2019
• Published: 10/17/2019
• Est. Priority Date: 09/13/2012
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: SILVERNAIL, CARTER M., OLSON, ERIK C.
• Granted Patent: US 11,001,784 B2
• Time in Patent Office: Days
• CPC Class Codes: C11D 2111/16 Metals
• CPC Class Codes: C11D 2111/18 Glass; Plastics
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/08 Silicates
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/2082 Polycarboxylic acids-salts thereof
• CPC Class Codes: C11D 3/365 containing carboxyl groups

Abstract

Detergent compositions effective for controlling hard water scale accumulation are disclosed. Detergent compositions employing phosphinosuccinic acid and mono-, bis- and oligomeric phosphinosuccinic acid (PSO) derivatives with alkali metal carbonate and/or alkali metal hydroxide reduce had water scale accumulation on treated surfaces at alkaline conditions between about pH of 9 and 12.5. Methods employing the detergent compositions and preventing hard water scale accumulation are also provided.

Claims

1. A detergent composition comprising:

between about 0.01 wt-% and about 40 wt-% of a phosphinosuccinic acid derivative comprising a phosphinosuccinic acid and mono-, bis- and oligomeric phosphinosuccinic acid adducts; and

between about 1 wt-% and about 90 wt-% of an alkalinity source comprising an alkali metal hydroxide, carbonate, metasilicate, and/or silicate;

wherein the composition contains a greater weight percentage of the alkalinity source than the phosphinosuccinic acid derivative; and

wherein a use solution of the detergent composition has a pH greater than 9; and

the composition does not contain a bleaching agent.

2. The composition of claim 1, further comprising a water soluble polymer.

3. The composition of claim 2, wherein the water soluble polymer is selected from the group consisting of a polycarboxylic acid and hydrophobically modified polycarboxylic acid.

4. The composition of claim 1, further comprising a nonionic surfactant.

5. The composition of claim 4, wherein the nonionic surfactant comprises ethylene oxide, propylene oxide, or a combination of ethylene and propylene oxide.

6. The composition of claim 1, wherein the phosphinosuccinic acid derivative comprises at least 10 mol % of an adduct comprising a ratio of succinic acid to phosphorus from about 1:

1 to 20;

1.

7. The composition of claim 1, wherein the composition comprises between about 1 wt-% and about 20 wt-% of the phosphinosuccinic acid derivative and between about 10 wt-% and about 70 wt-% of the alkali metal hydroxide.

8. The composition of claim 1, wherein the phosphinosuccinic acid (I) and mono- (II), bis- (III) and oligomeric (IV) phosphinosuccinic acid adducts have the follow formulas:

9. The composition of claim 1, where the use solution comprises from about 100-1500 ppm of the alkalinity source, from about 5-500 ppm of the phosphinosuccinic acid derivative and has a pH between about 10.5 and 12.5.

10. The composition of claim 4, wherein the nonionic surfactant is selected from the group consisting of an ethylene oxide/propylene oxide copolymer, capped ethylene oxide/propylene oxide copolymer, ethylene oxide/propylene oxide block copolymer, alcohol alkoxylate, capped alcohol alkoxylate, and combinations thereof.

11. The composition of claim 10, wherein the nonionic surfactant is an ethylene oxide/propylene oxide block copolymer.

12. The composition of claim 4, wherein the composition comprises between about 0.1 wt-% and about 40 wt-% of the nonionic surfactant.

13. The composition of claim 4, wherein the composition comprises from about 10 wt-% to about 70 wt-% of the alkalinity source, from about 1 wt-% to about 20 wt-% of the phosphinosuccinic acid derivative, and from about 0.1 wt-% to about 25 wt-% of the nonionic surfactant.

14. The composition of claim 4, wherein the detergent composition use solution comprises from about 100-1500 ppm of the alkalinity source, from about 1-500 ppm of the phosphinosuccinic acid derivative, and from about 1-50 ppm of a nonionic surfactant.

15. The composition of claim 4, wherein the composition comprises from about 10-80 wt-% of the alkalinity source, from about 1-20 wt-% of the phosphinosuccinic acid derivative, and from about 1-10 wt-% the nonionic surfactant.

16. The composition of claim 1, wherein the phosphinosuccinic acid derivative comprises at least 10 mol % of an adduct comprising a ratio of succinic acid to phosphorus from about 1:

1 to 15;

1.

17. The composition of claim 1, wherein the composition further comprises a defoaming agent.

18. The composition of claim 17, wherein the defoaming agent comprises silica dispersed in polydimethylsiloxane, fatty amide, hydrocarbon wax, fatty acid, fatty ester, fatty alcohol, fatty acid soap, ethoxylate, mineral oil, polyethylene glycol ester, alkyl phosphate ester, and combinations thereof.

19. The composition of claim 1, wherein the composition further contains water in the amount of from about 0.01 wt-% to about 90 wt-%.

20. The composition of claim 1, further comprising at least one of an etch protectant, a fragrance, a dye, an enzyme, a dispersant, and an anti-redeposition agent.