CORRUGATED FUEL ELECTRODE

• US 20190319278A1
• Filed: 10/20/2017
• Published: 10/17/2019
• Est. Priority Date: 10/21/2016
• Status: Active Grant

• Current Assignee: Form Energy, Inc.
• Original Assignee: NantEnergy, Inc.
• Inventors: HAYES, Joel Ryan, KRISHNAN, Ramkumar, TRIMBLE, Todd, ANDERSON, Clifford
• Granted Patent: US 11,335,918 B2
• Time in Patent Office: Days
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 4/661 Metal or alloys, e.g. alloy coatings H01M4/669 take precedence
• CPC Class Codes: H01M 4/742 perforated material
• CPC Class Codes: H01M 4/747 Woven material
• CPC Class Codes: H01M 4/78 Shapes other than plane or cylindrical, e.g. helical
• CPC Class Codes: H01M 8/0232 Metals or alloys
• CPC Class Codes: H01M 8/0245 in the form of layered or coated products
• CPC Class Codes: H01M 8/0247 characterised by the form characterised by a channel configuration H01M8/0258
• CPC Class Codes: H01M 8/0254 corrugated or undulated
• CPC Class Codes: H01M 8/184 Regeneration by electrochemical means
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel electrode incorporates a first and second corrugated portion that are attached to each other at offset angles respect to their corrugation axis and therefore reinforce each other. A first corrugated portion may extend orthogonally with respect to a second corrugated portion. The first and second corrugated portions may be formed from metal wire and may therefore have a very high volumetric void fraction and a high surface area to volume ratio (sa/vol). In addition, the strands of the wire may be selected to enable high conductivity to the current collectors while maximizing the sa/vol. In addition, the shape of the corrugation, including the period distance, amplitude and geometry may be selected with respect to the stiffness requirements and electrochemical cell application factors. The first and second corrugated portions may be calendared or crushed to reduce thickness of the fuel electrode.

Claims

1. A rechargeable electrochemical cell comprising:

a fuel electrode comprising;

a) a first corrugated portion formed of electrically conductive material, the first corrugated portion having a first corrugation axis and comprising a plurality of apertures therethrough;

b) a second corrugated portion formed of electrically conductive material, the second corrugated portion having a second corrugation axis that is offset from said first corrugation axis and comprising a plurality of apertures extending therethrough; and

c) electrode attachments attaching the first corrugated portion and the second corrugated portion to each other;

a cathode;

an ionically conductive medium communicating the fuel electrode and the cathode; and

a metal fuel for electrodeposition on the corrugated portions of the fuel electrode during charging and oxidation at the fuel electrode during discharging.

2. The rechargeable electrochemical cell of claim 1, wherein the offset of the second corrugation axis from the first corrugation axis is between about 25 degrees to about 90 degrees.

3. The rechargeable electrochemical cell of claim 1, wherein the second corrugation axis is about 45 degrees offset from said first corrugation axis.

4. The rechargeable electrochemical cell of claim 1, wherein the second corrugation axis is about 90 degrees offset from said first corrugation axis.

5. The rechargeable electrochemical cell of claim 1, wherein the corrugated portions comprise a surface area to volume ratio sa/vol) between about 0.5 and about 10.0.

6. The rechargeable electrochemical cell of claim 1, wherein the corrugated portions comprise a surface area to volume ratio (sa/vol) between about 0.25 and about 30.0.

7. The rechargeable electrochemical cell of claim 6, wherein the corrugated portions comprise a surface area to volume ratio (sa/vol) of about 1.0 and about 10.0.

8. The rechargeable electrochemical cell of claim 1, wherein corrugated portions comprise an open surface area between about 50% to about 95%.

9. The rechargeable electrochemical cell of claim 1, wherein the fuel electrode has a volumetric void fraction between about 90% to about 99.5%.

10. The rechargeable electrochemical cell of claim 1, wherein at least one of the first corrugated portion and the second corrugated portions comprises a sheet having the apertures therethrough, wherein said sheet has a substantially uniform thickness.

11. The rechargeable electrochemical cell of claim 1, wherein at least one of the first corrugated portion and the second corrugated portion comprises a screen.

12. The rechargeable electrochemical cell of claim 11, wherein the screen is a woven screen.

13. The rechargeable electrochemical cell of claim 11, wherein the first corrugated portion and second corrugated portion comprise corrugation-axis extensions and cross-corrugation extensions.

14. The rechargeable electrochemical cell of claim 13, wherein the corrugation-axis extensions and cross-corrugation extensions are wires.

15. The rechargeable electrochemical cell of claim 13, wherein both the first and second corrugated portions are screens and the corrugation-axis extensions of the first corrugated portion extend and connect to a current collector.

16. The rechargeable electrochemical cell of claim 1, wherein the first corrugated portion has a first corrugation ratio and the second corrugated portion has a second corrugation ratio, wherein both the first and second corrugation ratios are greater than 0.75 and no more than about 5.0.

17. The rechargeable electrochemical cell of claim 1, wherein the electrode attachments are stitches.

18. The rechargeable electrochemical cell of claim 1, wherein the electrode attachments comprise a staple that extends from the first corrugated portion around a portion of the second corrugated portion.

19. The rechargeable electrochemical cell of claim 1, wherein the electrode attachments comprise a weld attachment that comprises the first corrugated portion fused to the second corrugated portion.

20. The rechargeable electrochemical cell of claim 1, further comprising:

a) a third corrugated portion formed of an electrically conductive material, the third corrugated portion having a third corrugation axis that is offset from said second corrugation axis and having a plurality of apertures extending therethrough;

wherein the third corrugated portion and said first and second corrugated portions are attached to each other by said electrode attachments.

21. The rechargeable electrochemical cell of claim 1, wherein the first corrugated portion and second corrugated portion are each a metal screen.

22. The rechargeable electrochemical cell of claim 14, wherein the wire has essentially no internal surface area.

23. The rechargeable electrochemical cell according to claim 1, wherein the first corrugated portion and the second corrugated portion are calendared or crushed together.

24. The rechargeable electrochemical cell according to claim 1, wherein the cell is a metal-air battery and the cathode is an air electrode.

25. The rechargeable electrochemical cell according to claim 24, further comprising a charging electrode.

26. The rechargeable electrochemical cell according to claim 24, wherein the first corrugated portion and the second corrugated portion are calendared or crushed together.

27. A fuel electrode for a rechargeable electrochemical cell in which a metal fuel is electrodeposited the fuel electrode during charging and oxidized at the fuel electrode during discharging, comprising:

a) a first corrugated portion formed of electrically conductive material, the first corrugated portion having a first corrugation axis and comprising a plurality of apertures therethrough;

b) a second corrugated portion formed of electrically conductive material, the second corrugated portion having a second corrugation axis that is offset from said first corrugation axis and comprising a plurality of apertures extending therethrough; and

c) electrode attachments attaching the first corrugated portion and the second corrugated portion to each other;

wherein the electroconductive material of each corrugated portion has a smooth continuous outer surface with essentially no internal surface area and receives the electrodeposited fuel thereon during charging.

28. The rechargeable electrochemical cell of claim 27, wherein at least one of the first corrugated portion and the second corrugated portion is a screen.

29. The rechargeable electrochemical cell of claim 28, wherein the screen is a woven screen.

30. The rechargeable electrochemical cell of claim 28, wherein the screen is formed of corrugation-axis extensions and cross-corrugation extensions.

31. The rechargeable electrochemical cell of claim 30, wherein the corrugation-axis extensions and cross-corrugation extensions are wires of the electroconductive material having essentially no internal surface area.

32. A rechargeable electrochemical cell comprising:

the fuel electrode according to claim 27;

a cathode;

an conically conductive medium communicating the fuel electrode and the cathode; and

a metal fuel for electrodeposition on the corrugated portions of the fuel electrode during charging and oxidation at the fuel electrode during discharging.

33. The rechargeable electrochemical cell according to claim 32, wherein the cell is a metal-air battery and the cathode is an air electrode.

34. The rechargeable electrochemical cell according to claim 33, further comprising a charging electrode.