Composite Membrane and Method of Separating Gas Using the Same

• US 20190321787A1
• Filed: 11/02/2017
• Published: 10/24/2019
• Est. Priority Date: 11/04/2016
• Status: Abandoned Application

• Current Assignee: Kyoto University
• Original Assignee: Kyoto University
• Inventors: Sivaniah, Easan, Ghalei, Behnam, Sakurai, Kento, Kinoshita, Yosuke, Kitagawa, Susumu
• Application Number:
  US16/347,332
• Publication Number:
  US 20190321787A1
• Time in Patent Office: Days
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/204 Metal organic frameworks (MOF's)
• CPC Class Codes: B01D 2257/102 Nitrogen
• CPC Class Codes: B01D 2257/104 Oxygen
• CPC Class Codes: B01D 2257/108 Hydrogen
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/502 Carbon monoxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/228 characterised by specific membranes
• CPC Class Codes: B01D 67/00793 Dispersing a component, e.g. as particles or powder, in another component
• CPC Class Codes: B01D 69/148 Organic/inorganic mixed matrix membranes
• CPC Class Codes: B01D 71/0281 Zeolites
• CPC Class Codes: B01D 71/72 Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, not provided for in a single one of the groups B01D71/46 - B01D71/70 and B01D71/701 - B01D71/702
• CPC Class Codes: C08J 2371/12 Polyphenylene oxides
• CPC Class Codes: C08J 2383/04 Polysiloxanes
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets

Abstract

Disclosed is a composite membrane comprising a mixed matrix membrane comprising a polymer matrix and fillers dispersed in the polymer matrix. The polymer matrix comprises a polymer having a polar functional group. The H₂ permeability coefficient of the polymer matrix is 20 Barrer or more at 4 bar and 298 K. The filler has a polar functional group that may be capable of forming a hydrogen bond with the polar functional group of the polymer, and has an average diameter of 100 nm or less.

Claims

1-14. -14. (canceled)

15. A composite membrane comprising a mixed matrix membrane comprising:

a polymer matrix comprising a polymer having a polar functional group, the H₂ permeability coefficient of the polymer matrix being 20 Barrer or more at 4 bar and 298 K; and

a filler having a polar functional group, having an average diameter of 100 nm or less, and dispersed in the polymer matrix.

16. The composite membrane according to claim 15, wherein the polar functional group of the filler is capable of forming a hydrogen bond with the polar functional group of the polymer.

17. The composite membrane according to claim 15, wherein the porous filler comprises at least one selected from the group consisting of a metal organic framework particle, a zeolite particle and a silica gel particle.

18. The composite membrane according to claim 15, wherein the filler include a polyhedral oligomeric silsesquioxane particle.

19. The composite membrane according to claim 15, wherein the filler comprises at least one selected from the group consisting of an organic or inorganic nanotube, an organic or inorganic nanosheet, and a nanodiamond.

20. The composite membrane according to claim 15, wherein the content of the filler is 50% by mass or less with respect to the total mass of the mixed matrix membrane.

21. The composite membrane according to claim 15, wherein the content of the filler is 20% by mass or less with respect to the total mass of the mixed matrix membrane.

22. The composite membrane according to claim 15, wherein the H₂ permeability coefficient of the polymer matrix is 200 Barrer or more at 4 bar and 298 K.

23. The composite membrane according to claim 15, wherein

one of the polar functional group of the polymer or the polar functional group of the filler includes at least one kind selected from the group consisting of an amide group, an carboxyl group, a hydroxyl group and an amino group, and

the other includes at least one kind selected from the group consisting of an amide group, a nitrile group, an ether group, a carboxylic acid ester group, ketone group, a nitro group and a halide group.

24. The composite membrane according to claim 15, wherein the thickness of the mixed matrix membrane is 3.0 micrometers or less.

25. The composite membrane according to claim 15, wherein the composite membrane further comprises a porous substrate, and the mixed matrix membrane is stacked on the porous substrate.

26. A method of separating a predetermined gas from a mixed gas, the method comprising:

causing the predetermined gas in the mixed gas to pass selectively through the composite membrane according to claim 15, the predetermined gas being at least one kind of gas selected from the group consisting of;

hydrocarbon; and

other gases containing at least one of a hydrogen atom, a sulphur atom, an oxygen atom or a nitrogen atom.

27. The method according to claim 26, wherein the predetermined gas is at least one kind of gas selected from the group consisting of H₂, H₂S, CO, CO₂, alkane, alkene, N₂ and O₂.