AQUEOUS DISPERSION OF KETO- AND PHOSPHORUS ACID MONOMER-FUNCTIONALIZED POLYMER PARTICLES

• US 20190322889A1
• Filed: 03/12/2019
• Published: 10/24/2019
• Est. Priority Date: 04/18/2018
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.), Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.), Rohm and Haas Company (Dow, Inc.)
• Inventors: Bohling, James C., Luo, Pu, Zhang, Qing
• Granted Patent: US 10,858,531 B2
• Time in Patent Office: Days
• CPC Class Codes: C09D 125/14 with unsaturated esters
• CPC Class Codes: C09D 5/00 Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced electrically insulating plastics, resins or waxes H01B3/30; Filling pastes
• CPC Class Codes: C09D 5/1668 Vinyl-type polymers
• CPC Class Codes: C09D 7/43 Thickening agents
• CPC Class Codes: C09D 7/45 Anti-settling agents

Abstract

The present invention is related to a coating composition comprising a) an aqueous dispersion of acrylic or styrene-acrylic polymer particles functionalized with structural units of a monomer with keto functionality and structural units of a phosphorus acid monomer; b) a dispersant comprising structural units of a carboxylic acid monomer and a monomer with keto functionality; and c) a dihydrazide crosslinking agent. The composition of the present invention is useful for improving scrub resistance in a coating formed from the composition.

Claims

1. A coating composition comprising a) an aqueous dispersion of acrylic or styrene-acrylic polymer particles functionalized with from 0.5 to 10 weight percent structural units of a monomer with keto functionality and from 0.05 to 5 weight percent structural units of a phosphorus acid monomer based on the weight of the polymer particles;

b) from 0.1 to 5 weight percent of a dispersant, based on the dry weight of the composition, and having a M_w in the range of from 500 to 50,000 Daltons and comprising from i) 5 to 90 weight percent structural units of a carboxylic acid monomer; and

ii) from 0.5 to 10 weight percent structural units of a monomer with keto functionality; and

c) a dihydrazide crosslinking agent;

wherein the solids content of polymer particles is from 5 to 60 weight percent based on the weight of the composition.

2. The composition of claim 1 wherein the dispersant comprises from 10 to 80 weight percent structural units of the carboxylic acid monomer, and further comprises, based on the weight of the dispersant, and further comprises from 10 to 80 weight percent structural units of one or more ancillary monomer selected from the group consisting of methyl methacrylate, ethyl acrylate, butyl acrylate, butyl methacrylate, 2-ethylhexyl acrylate, hydroxyethyl methacrylate, hydroxyethyl acrylate, and 2-hydroxypropyl acrylate.

3. The composition of claim 1 wherein the mole-to-mole ratio of the dihydrazide to the structural units of the monomer with keto functionality present in the dispersant and the polymer particles is in the range of from 0.2:

1 to 2;

1.

4. The composition of claim 3 wherein the dihydrazide is adipic acid dihydrazide, the monomer with keto functionality is diacetone acrylamide, and the phosphorus acid monomer is phosphoethyl methacrylate, wherein the mole-to-mole ratio of adipic acid dihydrazide to the structural units of diacetone acrylamide present in the dispersant and the polymer particles is in the range of from 0.3:

1 to 1.1;

1.

5. The composition of claim 4 wherein the polymer particles have a T_g of less than 25°

C. and comprise structural units of styrene and butyl acrylate.

6. The composition of claim 5 wherein the dispersant has a M_w in the range of from 1000 to 25,000 Dalton, wherein the dispersant comprises, based on the weight of the dispersant a) from 30 to 60 weight percent structural units of a carboxylic acid monomer;

b) from 30 to 70 weight percent, structural units of butyl methacrylate; and

from 1 to 5 weight percent structural units of diacetone acrylamide;

wherein the carboxylic acid monomer is acrylic acid or methacrylic acid or a combination thereof.

7. The composition of claim 1 which further comprises one or more materials selected from the group consisting of extenders, defoamers, thickeners, coalescents, and pigments.

8. The composition of claim 7 which has an above-critical pigment volume concentration.

9. The composition of claim 8 which has a VOC concentration of less than 50 g/L.

10. The composition of claim 1 wherein the dispersant further comprises from 0.05 to 5 weight percent structural units of phosphoethyl methacrylate.