COMPOSITION FOR STEAM EXTRACTION OF BITUMEN

• US 20190322944A1
• Filed: 06/16/2017
• Published: 10/24/2019
• Est. Priority Date: 06/21/2016
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Inventors: Witham, Cole A., Kida, Yuko, Mukherjee, Biplab, Young, Timothy J., Nelson, Christopher W.
• Granted Patent: US 10,941,347 B2
• Time in Patent Office: Days
• CPC Class Codes: C09K 8/584 characterised by the use of specific surfactants
• CPC Class Codes: C09K 8/592 Compositions used in combination with generated heat, e.g. by steam injection
• CPC Class Codes: C10G 1/04 by extraction
• CPC Class Codes: C10G 1/045 Separation of insoluble materials
• CPC Class Codes: C10G 2300/80 Additives
• CPC Class Codes: E21B 43/24 using heat, e.g. steam injection
• CPC Class Codes: E21B 43/2406 Steam assisted gravity drainage [SAGD]
• CPC Class Codes: E21C 41/31 for oil-bearing deposits

Abstract

The present invention relates to a bitumen recovery process from oil sands. The oil sands may be surface mined and transported to a treatment area or may be treated directly by means of an in situ process of oil sand deposits that are located too deep for strip mining. Specifically, the present invention involves the step of treating oil sands with a composition comprising an alkanolamine and an ethylene oxide capped glycol ether and/or propylene oxide capped glycol ether.

Claims

1. A method to recover bitumen comprising the step of contacting oil sands with a composition comprising an alkanolamine and a glycol ether wherein the alkanolamine/glycol ether composition comprises:

(i) an alkanolamine described by the following structure;

R₁R₂N—

R₃OH

where R₁ is H, or a linear, branched, or cyclic alkyl group of 1 to 4 carbons, R₂ is H, —

CH₂CH₂OH, or a linear, branched, or cyclic alkyl group of 1 to 4 carbons,

and

R₃ is a linear or branched alkyl group of 2 to 5 carbons

and

(ii) one or more glycol ether selected from;

(a) an ethylene oxide capped glycol ether described by the following structure;

RO—

(CH₂CH(CH₃)O)_m(C₂H₄O)_nH

wherein R is a linear, branched, cyclic alkyl, phenyl, or alkyl phenyl group of equal to or greater than 4 carbons,

m is 0 to 3,

and

n is 1 to 3,

and

(b) a propylene oxide capped glycol ether described by the following structure;

RO—

(C₂H₄O)_o(CH₂CH(CH₃)O)_pH

wherein R is a linear, branched, cyclic alkyl, phenyl, or alkyl phenyl group of equal to or greater than 4 carbons,

o is 0 to 3,

and

p is 1 to 3,

wherein the treatment is to oil sands recovered by surface mining or in situ production.

2. The method of claim 1 comprising the steps of:

i) surface mining oil sands,

ii) preparing an aqueous slurry of the oil sands,

iii) treating the aqueous slurry with the alkanolamine/ethylene oxide capped glycol ether and/or propylene oxide capped glycol ether composition,

iv) agitating the treated aqueous slurry,

v) transferring the agitated treated aqueous slurry to a separation tank,

and

vi) separating the bitumen from the aqueous portion.

3. The method of claim 2 wherein the ethylene oxide capped glycol ether and/or propylene capped glycol ether is present in the aqueous slurry in an amount of from 0.01 to 10 weight percent based on the weight of the oil sands.

4. The method of claim 1 by in situ production comprising the steps of:

i) treating a subterranean reservoir of oil sands by injecting steam containing the alkanolamine/ethylene oxide capped glycol ether and/or propylene capped glycol ether composition into a well,

and

ii) recovering the bitumen from the well.

5. The method of claim 1 wherein the ratio of alkanolamine (i) to ethylene oxide capped glycol ether and/or propylene oxide capped glycol ether (ii) is from 10:

90 to 90;

10.

6. The method of claim 4 wherein the concentration of the ethylene oxide capped glycol ether and/or propylene oxide capped glycol ether in the steam is in an amount of from 0.01 to 10 weight percent.

7. The method of claim 1 wherein the alkanolamine is monoethanolamine, monoisopropanolamine, N-methymonoethanolamine, 3-amino-1-propanol, or mixtures thereof.

8. The method of claim 1 wherein the ethylene oxide capped glycol ether is ethylene oxide capped n-butyl ether, ethylene oxide capped n-butyl ether of propylene glycol, ethylene oxide capped n-hexyl ether, ethylene oxide capped n-hexyl ether of propylene glycol, ethylene oxide capped 2-ethylhexyl ether, or ethylene oxide capped 2-ethylhexyl ether of propylene glycol.

9. The method of claim 1 wherein the propylene oxide capped glycol ether is propylene oxide capped n-butyl ether, propylene oxide capped n-butyl ether of ethylene glycol, propylene oxide capped n-hexyl ether, propylene oxide capped n-hexyl ether of ethylene glycol, propylene oxide capped 2-ethylhexyl ether, or propylene oxide capped 2-ethylhexyl ether of ethylene glycol.