SORBENTS FOR THE OXIDATION AND REMOVAL OF MERCURY

• US 20190329215A1
• Filed: 07/11/2019
• Published: 10/31/2019
• Est. Priority Date: 08/30/2004
• Status: Abandoned Application

• Current Assignee: Midwest Energy Emissions Corp.
• Original Assignee: Midwest Energy Emissions Corp.
• Inventors: Olson, Edwin S., Holmes, Michael J., Pavlish, John H.
• Application Number:
  US16/509,146
• Publication Number:
  US 20190329215A1
• Time in Patent Office: Days
• CPC Class Codes: B01D 2253/102 Carbon
• CPC Class Codes: B01D 2253/25 Coated, impregnated or composite adsorbents
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 53/10 with dispersed adsorbents
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: B01J 20/02 comprising inorganic material
• CPC Class Codes: B01J 20/0262 Compounds of O, S, Se, Te
• CPC Class Codes: B01J 20/027 Compounds of F, Cl, Br, I
• CPC Class Codes: B01J 20/04 comprising compounds of alkali metals, alkaline earth metals or magnesium
• CPC Class Codes: B01J 20/041 Oxides or hydroxides
• CPC Class Codes: B01J 20/043 Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
• CPC Class Codes: B01J 20/10 comprising silica or silicate
• CPC Class Codes: B01J 20/106 Perlite
• CPC Class Codes: B01J 20/12 Naturally occurring clays or bleaching earth
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes
• CPC Class Codes: B01J 20/22 comprising organic material
• CPC Class Codes: B01J 20/223 containing metals, e.g. organo-metallic compounds, coordination complexes
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: B01J 20/28016 Particle form
• CPC Class Codes: B01J 20/3416 : of sorbents or filter aids comprising free carbon, e.g. activated carbon
• CPC Class Codes: B01J 2220/42 : Materials comprising a mixture of inorganic materials materials coated or impregnated on a carrier B01J20/32
• CPC Class Codes: Y10S 95/901 : Activated carbon

Abstract

A promoted carbon and/or non-carbon base sorbent are described that are highly effective for the removal of mercury from flue gas streams. The promoted sorbent comprises a carbon and/or non-carbon base sorbent that has reacted with and contains forms of halogen and halides. Optional components may be added to increase and/or preserve reactivity and mercury capacity. These may be added directly with the base sorbent, or in-flight within a gas stream (air, flue gas, etc.), to enhance base sorbent performance and/or mercury capture. Mercury removal efficiencies obtained exceed conventional methods. The promoted sorbent can be regenerated and reused. Base sorbent treatment and preparation methods are also described. New methods for in-flight preparation, introduction, and control of the active base sorbent into the mercury contaminated gas stream are described.

Claims

1. A method for reducing mercury in a mercury-containing gas, the method comprising:

combusting coal in a combustion chamber, the coal comprising an additive comprising Br₂, I₂, HBr, HI, a bromide compound, an iodide compound, or a combination thereof, to form the mercury-containing gas;

collecting mercury in the mercury-containing gas on a sorbent comprising a carbon sorbent, a non-carbon sorbent, or a combination thereof.

2. The method of claim 1, wherein the sorbent material comprises a non-carbon sorbent material.

3. The method of claim 2, wherein the non-carbon sorbent material comprises a porous felsic material, a vesicular felsic material, a porous basaltic material, a vesicular basaltic material, a clay-based compound, an alkaline compound, a calcium hydroxide compound, a sodium acetate compound, a bicarbonate compound, or a combination thereof.

4. The method of claim 1, wherein the sorbent comprises at least one of activated carbon, powdered activated carbon, granulated activated carbon, carbon black, unburned carbon, carbon fiber, carbon honeycomb or plate structure, aerogel carbon film, pyrolysis char, and regenerated activated carbon.

5. The method of claim 1, wherein the sorbent comprises activated carbon.

6. The method of claim 1, wherein the sorbent is injected into the mercury-containing gas.

7. The method of claim 1, wherein the coal comprises the added Br₂, I₂, HBr, HI, the bromide compound, the iodide compound, or a combination thereof, added to the coal before the coal enters the combustion chamber.

8. The method of claim 1, wherein the combustion chamber comprises the added Br₂, I₂, HBr, HI, the bromide compound, the iodide compound, or a combination thereof.

9. The method of claim 1, wherein the coal is combusted in the combustion chamber at a coal-combustion facility, wherein the Br₂, I₂, HBr, HI, the bromide compound, the iodide compound, or combination thereof, is added to the coal before the coal enters the combustion chamber, wherein the addition of the Br₂, I₂, HBr, HI, the bromide compound, the iodide compound, or combination thereof, to the coal is performed at the coal-combustion facility.

10. The method of claim 1, wherein the coal is combusted in the combustion chamber at a coal-combustion facility, wherein the Br₂, I₂, HBr, HI, the bromide compound, the iodide compound, or combination thereof, is added to the coal before the coal enters the combustion chamber, wherein the addition of the Br₂, I₂, HBr, HI, the bromide compound, the iodide compound, or combination thereof, to the coal is performed at a site other than the coal-combustion facility.

11. The method of claim 1, wherein the combustion chamber is an electric utility coal combustion chamber.

12. The method of claim 1, wherein the combustion chamber is a combustion furnace.

13. The method of claim 1, wherein the coal comprises subbituminous coal.

14. The method of claim 1, wherein the coal comprises lignite coal.

15. The method of claim 1, further comprising:

measuring the mercury content of the mercury-containing gas; and

modifying, in response to the measured mercury content,

an injection rate of injecting the sorbent into the mercury-containing gas,

an amount of the additive added to the coal, or

a combination thereof.

16. The method of claim 1, further comprising:

modifying, in response to a measured mercury content,

an injection rate of injecting the sorbent into the mercury-containing gas,

an amount of the additive added to the coal, or

a combination thereof.

17. The method of claim 16, wherein the measurement of the mercury content of the mercury-containing gas comprises continuous measurement.

18. The method of claim 1, wherein the mercury-containing gas comprises about 1 g to about 30 g of the element bromine per 100 g of the sorbent.

19. The method of claim 1, wherein the sorbent in the mercury-containing gas comprises about 1 g to about 30 g of the added Br₂, I₂, HBr, HI, the bromide compound, the iodide compound, or a combination thereof, per 100 g of the sorbent.

20. The method of claim 1, comprising removing greater than 70 wt % of the mercury in the mercury-containing gas.

21. The method of claim 1, comprising removing greater than 70 wt % of the mercury in the mercury-containing gas with the sorbent.

22. The method of claim 1, wherein the sorbent injected into the mercury-containing gas is a sorbent obtained by contacting a sorbent with a halogen or halide promoter prior to injection of the sorbent into the mercury-containing gas.

23. The method of claim 1, wherein the sorbent material injected into the mercury-containing gas is substantially free of halogen and halide promotion prior to injection of the sorbent into the mercury-containing gas.

24. The method of claim 1, wherein the injection of the sorbent into the mercury-containing gas occurs upstream of a particulate separator, a scrubber, an air-preheater, or a combination thereof.

25. The method of claim 24, wherein the particulate separator comprises an electrostatic precipitator, a baghouse, a fabric filter, or a combination thereof.

26. The method of claim 1, wherein a halide sorbent enhancement additive comprises the added Br₂, I₂, HBr, HI, the bromide compound, the iodide compound, or combination thereof.

27. The method of claim 1, wherein the sorbent enhancement additive comprises the bromide compound, the iodide compound, or a combination thereof.

28. A method of separating mercury from a mercury-containing gas, the method comprising:

combusting coal in a combustion chamber, to provide the mercury-containing gas, wherein

the coal comprises added Br₂, I₂, HBr, HI, a bromide compound, an iodide compound, or a combination thereof, added to the coal upstream of the combustion chamber, or

the combustion chamber comprises added Br₂, I₂, HBr, HI, a bromide compound, an iodide compound, or a combination thereof, or

a combination thereof;

injecting a sorbent into the mercury-containing gas downstream of the combustion chamber, the sorbent comprising a carbon sorbent, a non-carbon sorbent, or a combination thereof,

contacting mercury in the mercury-containing gas with the sorbent; and

separating the sorbent contacted with the mercury from the mercury-containing gas.

29. A method of separating mercury from a mercury-containing gas, the method comprising:

combusting coal in a combustion chamber, to provide the mercury-containing gas, wherein the mercury-containing gas comprises a halogen or halide promoter comprising HBr, HI, Br⁻

, I⁻

, or a combination thereof, wherein

the coal comprises added Br₂, I₂, HBr, HI, a bromide compound, an iodide compound, or a combination thereof, added to the coal before the coal enters the combustion chamber, or

the combustion chamber comprises added Br₂, I₂, HBr, HI, a bromide compound, an iodide compound, or a combination thereof, or

a combination thereof;

injecting a sorbent into the mercury-containing gas downstream of the combustion chamber, the sorbent comprising a carbon sorbent, a non-carbon sorbent, or a combination thereof;

contacting mercury in the mercury-containing gas with the sorbent; and

separating the sorbent contacted with the mercury from the mercury-containing gas.

30. A method of separating mercury from a mercury-containing gas, the method comprising:

combusting coal in a combustion chamber, to provide the mercury-containing gas, wherein the mercury-containing gas comprises a halogen or halide promoter comprising HBr, HI, Br⁻

, I⁻

, or a combination thereof, wherein

the coal comprises added Br₂, I₂, HBr, HI, a bromide compound, an iodide compound, or a combination thereof, added to the coal before the coal enters the combustion chamber, or

the combustion chamber comprises added Br₂, I₂, HBr, HI, a bromide compound, an iodide compound, or a combination thereof, or

a combination thereof;

injecting a sorbent into the mercury-containing gas downstream of the combustion chamber, the sorbent comprising a carbon sorbent, a non-carbon sorbent, or a combination thereof, such that the sorbent reacts with the halogen or halide promoter in the mercury-containing gas to form a promoted sorbent;

contacting mercury in the mercury-containing gas with the promoted sorbent;

separating the promoted sorbent contacted with the mercury from the mercury-containing gas;

measuring the mercury content of the mercury-containing gas; and

modifying, in response to the measured mercury content,

an injection rate of injecting the sorbent into the mercury-containing gas,

an amount of the Br₂, I₂, HBr, HI, the bromide compound, the iodide compound, or a combination thereof, added to the coal or the combustion chamber, or

a combination thereof.