PLASTIC SCINTILLATOR, DETECTOR, ASSOCIATED MANUFACTURING PROCESS AND SCINTILLATION MEASUREMENT PROCESS

• US 20190331809A1
• Filed: 03/28/2017
• Published: 10/31/2019
• Est. Priority Date: 04/01/2016
• Status: Abandoned Application

• Current Assignee: Commissariat a L'Energie Atomique (French Alternative Energies and Atomic Energy Commission)
• Original Assignee: Commissariat a L'Energie Atomique (French Alternative Energies and Atomic Energy Commission)
• Inventors: HAMEL, Matthieu, BERTRAND, Guillaume, SGUERRA, Fabien
• Application Number:
  US16/089,666
• Publication Number:
  US 20190331809A1
• Time in Patent Office: Days
• CPC Class Codes: C08F 212/08 Styrene
• CPC Class Codes: C08F 222/102 of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: G01T 1/2033 Selection of materials see provisionally also G01T1/203
• CPC Class Codes: G21K 2004/08 with a binder in the phosphor layer
• CPC Class Codes: G21K 4/00 Conversion screens for the conversion of the spatial distribution of X-rays or particle radiation into visible images, e.g. fluoroscopic screens photographic processes using X-ray intensifiers G03C5/17; discharge tubes comprising luminescent screens H01J1/62; cathode ray tubes for X-ray conversion with optical output H01J31/50

Abstract

Material for plastic scintillation measurement comprising: —a polymeric matrix; —a primary fluorophore incorporated in the polymeric matrix and composed of N-(2-ethylhexyl)carbazole, the monomer form of the N-(2-ethylhexyl)carbazole being spontaneously in physicochemical equilibrium with the exciplex form; and, —a secondary fluorophore. A plastic scintillator can be manufactured in a simplified manner with the material of the invention, while having optimized properties for the plastic scintillation measurement. The invention also relates to the process for the manufacture of the material, to a part comprising the material and to the associated measurement device, and also to the process for measurement by plastic scintillation using the material.

Claims

1. A composition for plastic scintillation measurement, comprising:

a polymeric matrix;

a primary fluorophore incorporated in the polymeric matrix and composed of N-(2-ethylhexyl)carbazole, the monomer form of the N-(2-ethylhexyl)carbazole being spontaneously in physicochemical equilibrium with the exciplex form; and

,

a secondary fluorophore.

2. A composition according to claim 1, wherein the polymeric matrix is completely or partially composed of at least one polymer comprising repeat units resulting from the polymerization of a monomer comprising at least one aromatic, (meth)acrylic or vinyl group.

3. A composition according to claim 2, wherein the monomer is at least one monomer selected from the group consisting of styrene, vinyltoluene, vinylxylene, vinylbiphenyl, vinylnaphthalene, vinylcarbazole, methyl (meth)acrylate, (meth)acrylic acid and 2-hydroxyethyl (meth)acrylate.

4. A composition according to claim 3, wherein the monomer is styrene or vinyltoluene.

5. A composition according to claim 1, wherein the polymeric matrix is constituted, completely or partially, of at least one crosslinked polymer.

6. A composition according to claim 1, wherein the composition comprises from 1% by weight to 50% by weight of the primary fluorophore.

7. A composition according to claim 6, wherein the composition comprises from 1% by weight to 5% by weight of the primary fluorophore.

8. A composition according to claim 6, wherein the composition comprises from 10% by weight to 50% by weight of the primary fluorophore.

9. A composition according to claim 1, wherein the composition comprises at least one neutron absorber.

10. A composition according to claim 9, wherein the neutron absorber is selected from the group consisting of at least one organometallic lithium, boron, gadolinium or cadmium complex and a mixture of these complexes.

11. A composition according to claim 10, wherein the neutron absorber is an organometallic gadolinium complex selected from the group consisting of gadolinium tris(tetramethylheptanedionate), a gadolinium tricarboxylate and gadolinium tris(acetylacetonate).

12. A composition according to claim 10, wherein the neutron absorber is an organometallic gadolinium complex present in the material at a concentration between 0.2% by weight and 2.5% by weight of gadolinium.

13. A composition according to claim 12, wherein the polymeric matrix comprises from 0.002% by weight to 0.2% by weight of the secondary fluorophore.

14. A composition according to claim 12, wherein the secondary fluorophore is selected from the group consisting of 1,4-di[2-(5-phenyloxazolyl)]benzene, 1,4-bis(2-methylstyryl)benzene, 1,4-bis(4-methyl-5-phenyl-2-oxazolyl)benzene, 9,10-diphenylanthracene and their mixtures.

17. A device for plastic scintillation detection comprising a part comprising a composition as defined by claim 1.

19. A process for the manufacture of the composition as defined by claim 1, the process comprising the following steps:

a) having available a polymerization medium comprising;

monomers, oligomers or their mixtures intended to form at least one constituent polymer of a polymeric matrix;

a primary fluorophore composed of N-(2-ethylhexyl)carbazole; and

,

a secondary fluorophore;

b) polymerizing the polymerization medium in order to obtain the material.

20. A process according to claim 19, wherein the polymerization medium comprises a neutron absorber, a crosslinking agent, a polymerization initiator or their mixtures.

22. A process according to claim 19, wherein steps a) and b) are carried out in a mold.

23. A process according to claim 19, comprising a step c) during which the composition or the preform of the part is machined.

24. A plastic scintillation measurement process, comprising:

i) at least one composition as defined claim 1 is brought into contact with ionizing radiation or an ionizing particle in order for the material to emit radioluminescent radiation; and

ii) the radioluminescent radiation is measured.

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