PLANT AND PROCESS FOR PRODUCING NITRIC ACID

• US 20200131039A1
• Filed: 12/31/2019
• Published: 04/30/2020
• Est. Priority Date: 09/19/2016
• Status: Active Grant

• Current Assignee: Stamicarbon B.V. (MAIRE)
• Original Assignee: Stamicarbon B.V. (MAIRE)
• Inventors: POSTMA, Leonardus Hubertus, MUNOZ LOPEZ, Maria Paz, VOORWINDEN, Martinus
• Granted Patent: US 10,988,380 B2
• Time in Patent Office: Days
• CPC Class Codes: B01D 2252/103 Water
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 53/002 by condensation
• CPC Class Codes: B01D 53/14 by absorption
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/8625 Nitrogen oxides
• CPC Class Codes: B01D 53/8631 Processes characterised by a specific device
• CPC Class Codes: C01B 21/26 Preparation by catalytic or non-catalytic oxidation of ammonia
• CPC Class Codes: C01B 21/40 Preparation by absorption of oxides of nitrogen C01B21/26 takes precedence
• CPC Class Codes: Y02C 20/20 of methane

Abstract

Disclosed is a dual pressure plant for the production of nitric acid on the basis of the oxidation of ammonia. The plant comprises a reactor configured to produce a burner gas stream; a gas cooling section configured to form a cooled burner gas; a condensation section configured to form an aqueous nitric acid condensate and an uncondensed nitrogen oxides gas stream; an absorption section configured to produce raw nitric acid and a tail gas; and a tail gas treatment system configured to form a purified tail gas. In a tail gas heating section a further heat exchanger configured to receive heat from the burner gas stream, said further heat exchanger being positioned relatively close to the reactor.

Claims

1-5. -5. (canceled)

6. A dual pressure process for producing nitric acid comprising reacting a gas mixture of ammonia and air in a burner section thereby forming a burner gas stream;

cooling said burner gas stream in a gas cooling section forming a cooled burner gas;

condensing said cooled burner gas stream in a condensation section forming an aqueous nitric acid condensate and an uncondensed nitrogen oxides gas stream;

feeding said aqueous nitric acid condensate and said uncondensed nitrogen oxides gas stream to an absorption/oxidation section, forming a raw nitric acid product stream and a tail gas;

treating said tail gas in a tail gas treatment section, comprising a tail gas heating section, a nitrous gas removal section, and an expansion section, thereby forming a purified tail gas;

releasing said purified tail gas to the atmosphere;

the process comprising heating the tail gas in the gas cooling section to a temperature greater than 460°

C.

7. A process according to claim 6, performed in a plant comprising:

(a) a reactor comprising at least one gas inlet for ammonia and compressed air, a combustion chamber provided with an ammonia combustion catalyst and configured to produce a burner gas stream comprising nitrogen oxides resulting from the combustion of ammonia and subsequent oxidation, and a gas outlet for burner gas;

(b) a gas cooling section having a gas inlet which is in fluid communication with the outlet for burner gas of the reactor, said gas cooling section being configured to subject the burner gas stream to cooling, so as to form a cooled burner gas, the gas cooling section comprising a steam circuit heat exchanger configured to transfer heat from the burner gas stream to a steam circuit so as to generate superheated steam, and a gas outlet for cooled burner gas;

(c) a condensation section having a gas inlet which is in fluid communication with the outlet for cooled burner gas of the gas cooling section, said condensation section being configured to subject the cooled burner gas to condensation so as to form an aqueous nitric acid condensate and an uncondensed nitrogen oxides gas stream, said condensation section having a liquid outlet for the aqueous nitric acid condensate and a gas outlet for the uncondensed nitrogen oxides gas stream;

(d) an absorption section having a gas inlet which is in fluid communication with the gas outlet of the condensation section, said absorption section being configured to subject the nitrogen oxides gas stream to absorption in water, optionally in the form of a dilute nitric acid solution;

said absorption section further comprising a liquid inlet which is in fluid communication with the liquid outlet of the condensation section and a gas outlet for nitrogen oxides tail gas;

(e) a tail gas treatment system comprising a tail gas heating section, a nitrous gas removal section, and an expansion section, said tail gas treatment system being configured to subject nitrogen oxides gas to purification so as to form a purified tail gas and to subject said purified tail gas to expansion, said tail gas treatment section comprising a gas inlet for nitrogen oxides tail gas and a gas outlet for purified tail gas;

wherein the tail gas heating section comprises a further heat exchanger configured to receive heat from the burner gas stream, said further heat exchanger being positioned downstream of the steam circuit heat exchanger, and upstream of the gas outlet for cooled burner gas, and wherein the reactor, the steam circuit heat exchanger, and the further heat exchanger are integrated into one single apparatus.

8. A process according to claim 6, wherein the cooled burner gas stream entering the condensation section has a temperature between 170°

C. and 190°

C.

9. A method of modifying a pre-existing plant for the production of nitric acid, said plant comprising

(a) a reactor comprising a gas inlet for ammonia and a gas inlet for compressed air, a combustion chamber provided with an ammonia combustion catalyst and configured to produce a burner gas stream comprising nitrogen oxides resulting from the combustion of ammonia and subsequent oxidation, and a gas outlet for burner gas;

(b) a gas cooling section having a gas inlet which is in fluid communication with the outlet for burner gas of the reactor, said gas cooling section being configured to subject the burner gas stream to cooling, so as to form a cooled burner gas, the gas cooling section comprising a steam circuit heat exchanger configured to transfer heat from the burner gas stream to a steam circuit so as to generate superheated steam, and a gas outlet for cooled burner gas;

(c) a condensation section having a gas inlet which is in fluid communication with the outlet for cooled burner gas of the gas cooling section, said condensation section being configured to subject the cooled burner gas to condensation so as to form an aqueous nitric acid condensate and an uncondensed nitrogen oxides gas stream, said condensation section having a liquid outlet for the aqueous nitric acid condensate and a gas outlet for the uncondensed nitrogen oxides gas stream;

(d) an absorption section having a gas inlet which is in fluid communication with the gas outlet of the condensation section, said absorption section being configured to subject the nitrogen oxides gas stream to absorption in water;

said absorption section further comprising a liquid inlet which is in fluid communication with the liquid outlet of the condensation section and a gas outlet for nitrogen oxides tail gas;

(e) a tail gas treatment system comprising a tail gas heating section, a nitrous gas removal section, and an expansion section, said tail gas treatment system being configured to subject nitrogen oxides gas to purification so as to form a purified tail gas and to subject said purified tail gas to expansion, said tail gas treatment section comprising a gas inlet for nitrogen oxides tail gas and a gas outlet for purified tail gas;

wherein the method comprises adding to the tail gas heating section a heat exchanger configured to receive heat from the burner gas stream, said heat exchanger being positioned downstream of the steam circuit heat exchanger, and upstream of the gas outlet for cooled burner gas.