TREATMENT METHOD FOR REDUCING CARBON DIOXIDE EMISSION OF COMBUSTION EXHAUST GAS

• US 20200131045A1
• Filed: 04/11/2019
• Published: 04/30/2020
• Est. Priority Date: 05/19/2018
• Status: Active Grant

• Current Assignee: Nanao Horiishi, Sentec Co. Ltd.
• Original Assignee: Sentec Co. Ltd.
• Inventors: HORIISHI, Nanao, UENO, Hiromoto
• Granted Patent: US 11,414,323 B2
• Time in Patent Office: Days
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/604 Hydroxides
• CPC Class Codes: B01D 2252/10 Inorganic absorbents
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 53/18 Absorbing units; Liquid distributors therefor B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/73 After-treatment of removed components
• CPC Class Codes: B01D 53/78 with gas-liquid contact
• CPC Class Codes: C01D 1/22 with carbonates or bicarbonates
• CPC Class Codes: C01D 7/10 Preparation of bicarbonates from carbonates ammonia soda process C01D7/18
• CPC Class Codes: C01D 7/12 Preparation of carbonates from bicarbonates or bicarbonate-containing product
• CPC Class Codes: C01D 7/126 Multi-step processes, e.g. from trona to soda ash
• CPC Class Codes: C01F 11/02 Oxides or hydroxides production of lime C04B2/00

Abstract

A treatment method for reducing carbon dioxide emission of combustion exhaust gas includes: a caustic soda synthesis step; a treatment step of reducing carbon dioxide emission of combustion exhaust gas; and a recycling step. In the caustic soda synthesis step, a natural sodium carbonate aqueous solution (Na₂CO₃) prepared by dissolving natural sodium carbonate ore powder composed of Na₂CO₃ and NaHCO₃ in a caustic soda aqueous solution is used to generate a caustic soda aqueous solution and calcium carbonate precipitate by a causticization reaction with slaked lime, and solid-liquid separation is performed to obtain a synthetic caustic soda aqueous solution. In the treatment step, the synthetic caustic soda aqueous solution and purified combustion exhaust gas are brought into gas-liquid countercurrent contact so that carbon dioxide in the exhaust gas is absorbed by the synthetic caustic soda aqueous solution and immobilized as sodium carbonate.

Claims

1. (canceled)

2. A caustic soda synthesis method for synthesizing a caustic soda aqueous solution from a natural sodium carbonate ore, the method comprising:

a causticization reaction step of generating a caustic soda aqueous solution and calcium carbonate precipitate by a causticization reaction of adding slaked lime to the natural sodium carbonate aqueous solution obtained by being refined by a method for refining natural sodium carbonate ore consisting of sodium carbonate and sodium bicarbonate, the method including a pulverization step of pulverizing natural sodium carbonate ore, a conversion step of dissolving the pulverized sodium carbonate ore in a caustic soda aqueous solution to convert the sodium bicarbonate as a component into sodium carbonate, and a filtration step of filtering the aqueous solution after conversion and removing water-insoluble components to obtain a natural sodium carbonate aqueous solution;

a solid-liquid separation step of performing solid-liquid separation on the caustic soda aqueous solution and the calcium carbonate precipitate; and

a step of recycling all or a part of caustic soda aqueous solution obtained by the solid-liquid separation, and/or all or a part of alkaline drainage obtained by washing calcium carbonate obtained by the solid-liquid separation with water into the conversion step.

3. The caustic soda synthesis method according to claim 2, further comprising:

a sodium bicarbonate production step of generating sodium bicarbonate by extracting a part of the natural sodium carbonate aqueous solution obtained by being refined by a method for refining natural sodium carbonate ore, the method including a pulverization step of pulverizing natural sodium carbonate ore, a conversion step of dissolving the pulverized sodium carbonate ore in a caustic soda aqueous solution to convert the sodium bicarbonate as a component into sodium carbonate, and a filtration step of filtering the aqueous solution after conversion, and removing water-insoluble components to obtain a natural sodium carbonate aqueous solution, and carbonating the extracted part with carbon dioxide,

wherein as the carbon dioxide, carbon dioxide produced by roasting limestone is used, and slaked lime produced by hydrating quicklime produced by roasting the limestone is used in the causticization reaction step.

4. A treatment method for reducing carbon dioxide emission of combustion exhaust gas using a caustic soda aqueous solution as a carbon dioxide absorbing liquid, the method comprising:

a caustic soda synthesis step; and

a treatment step of reducing carbon dioxide emission of combustion exhaust gas,

wherein the caustic soda synthesis step is a step in which a caustic soda aqueous solution and calcium carbonate precipitate are generated by a causticization reaction by adding slaked lime to a natural sodium carbonate aqueous solution prepared by dissolving refined powder of natural sodium carbonate ore in water, and are subjected to solid-liquid separation or a natural sodium carbonate aqueous solution obtained by filtering an aqueous solution in which pulverized sodium carbonate ore powder is dissolved in a caustic soda aqueous solution to convert the sodium bicarbonate as a component into sodium carbonate, and removing and refining water insoluble components to obtain a synthetic caustic soda aqueous solution,

the treatment step of reducing carbon dioxide emission of combustion exhaust gas is a step in which the synthetic caustic soda aqueous solution generated in the caustic soda synthesis step and purified combustion exhaust gas are brought into gas-liquid countercurrent contact so that carbon dioxide in the exhaust gas is reduced by being absorbed by the synthetic caustic soda aqueous solution and immobilized as sodium carbonate, and

in the caustic soda synthesis step, the calcium carbonate precipitate obtained by solid-liquid separation of the caustic soda aqueous solution and the calcium carbonate precipitate produced by the causticization reaction is set as light calcium carbonate by washing the attached caustic soda with water and drying, and alkaline drainage generated by a water washing treatment is recycled to in the aqueous solution preparation step of sodium carbonate ore.

5. A treatment system for reducing carbon dioxide emission of combustion exhaust gas using a caustic soda aqueous solution as a carbon dioxide absorbing liquid, the system comprising:

a caustic soda synthesis apparatus; and

a treatment apparatus for reducing carbon dioxide emission of combustion exhaust gas,

wherein the caustic soda synthesis apparatus is an apparatus in which a caustic soda aqueous solution and calcium carbonate precipitate are generated by a causticization reaction due to slaked lime by using a natural sodium carbonate aqueous solution prepared by dissolving refined powder of natural sodium carbonate ore in water or a natural sodium carbonate aqueous solution obtained by filtering an aqueous solution in which pulverized sodium carbonate ore powder is dissolved in a caustic soda aqueous solution to convert the sodium bicarbonate as a component into sodium carbonate, and are subjected to solid-liquid separation to obtain a synthetic caustic soda aqueous solution,

the treatment apparatus of reducing carbon dioxide emission of combustion exhaust gas is an apparatus in which the synthetic caustic soda aqueous solution generated in the caustic soda synthesis apparatus and purified combustion exhaust gas are brought into gas-liquid countercurrent contact so that carbon dioxide in the exhaust gas is reduced by being absorbed by the synthetic caustic soda aqueous solution and immobilized as sodium carbonate, and

in the caustic soda synthesis apparatus, the calcium carbonate precipitate obtained by solid-liquid separation of the caustic soda aqueous solution and the calcium carbonate precipitate produced by the causticization reaction is set as light calcium carbonate by washing the attached caustic soda with water and drying, and alkaline drainage generated by a water washing treatment is recycled to in the aqueous solution preparation step of sodium carbonate ore.

6. The treatment system for reducing carbon dioxide emission of combustion exhaust gas according to claim 5, further comprising:

a recycling apparatus,

wherein the recycling apparatus is performed using a synthetic sodium carbonate aqueous solution in which the synthetic caustic soda aqueous solution is in gas-liquid countercurrent contact with the combustion exhaust gas to absorb carbon dioxide in the exhaust gas, and includes the following (1) a synthetic sodium carbonate production apparatus and/or (2) a bicarbonate production apparatus;

(1) the synthetic sodium carbonate production apparatus in which a synthetic sodium carbonate aqueous solution, in which the synthetic caustic soda aqueous solution absorbs carbon dioxide and becomes a treated liquid in the treatment apparatus for reducing carbon dioxide emissions of combustion exhaust gas, is used as a raw material, and concentrated and dried to produce a synthetic sodium carbonate powder product; and

(2) the sodium bicarbonate production apparatus in which a synthetic sodium carbonate aqueous solution of the treated liquid discharged from the treatment step of reducing carbon dioxide emission of combustion exhaust gas is used as a raw material, and carbonized by ventilating purified exhaust gas of the combustion exhaust gas into the synthetic sodium carbonate aqueous solution to form sodium bicarbonate, thereby producing sodium bicarbonate and sesquicarbonate soda products.