Method for Manufacturing a Glass Preform for Optical Fibers

• US 20200131073A1
• Filed: 10/30/2019
• Published: 04/30/2020
• Est. Priority Date: 10/30/2018
• Status: Active Grant

• Current Assignee: Prysmian SPA
• Original Assignee: Prysmian SPA
• Inventors: Caronna, Valeria, Grieco, Stefano, Di Giambattista, Irene, Cocchini, Franco, Schiaffo, Antonio
• Granted Patent: US 11,186,515 B2
• Time in Patent Office: Days
• CPC Class Codes: C03B 2201/12 doped with fluorine C03B2201/14 takes precedence
• CPC Class Codes: C03B 37/01446 Thermal after-treatment of preforms, e.g. dehydrating, consolidating, sintering C03B37/01853 takes precedence
• CPC Class Codes: C03B 37/01453 for doping the preform with flourine
• CPC Class Codes: C03B 37/0146 Furnaces therefor, e.g. muffle tubes, furnace linings

Abstract

Methods for manufacturing fluorine-doped glass preforms for optical fibers are disclosed. An exemplary method includes exposing a soot preform to an atmosphere containing a fluorine-containing gas in a first elongated chamber of a first furnace. The first elongated chamber typically has a single isothermal hot zone, which may be maintained at a doping temperature of about 800° C. to 1200° C., to obtain a fluorine-doped soot preform. The exemplary method further includes dehydrating the fluorine-doped soot preform by exposing it to an atmosphere containing a chlorine-containing gas in a second elongated chamber of a second furnace. The second elongated chamber typically has an upper hot zone, which may be maintained at a dehydration temperature of about 1000° C. to 1350° C., and a lower hot zone, which may be maintained at a consolidation temperature of about 1500° C. to 1650° C. Dehydration of the fluorine-doped soot preform typically occurs in the upper hot zone of the second furnace. The exemplary method further includes consolidating the fluorine-doped soot preform within the lower hot zone of the second furnace to form a fluorine-doped glass preform.

Claims

1. A method for manufacturing a fluorine-doped glass preform for optical fibers, the method comprising:

exposing a soot preform to an atmosphere containing a fluorine-containing gas in a first elongated chamber of a first furnace, the first elongated chamber having a single isothermal hot zone kept at a doping temperature of from 800°

C. to 1200°

C. to obtain a fluorine-doped soot preform;

dehydrating the fluorine-doped soot preform by exposing it to an atmosphere containing a chlorine-containing gas and being substantially devoid of fluorine in a second elongated chamber of a second furnace, the second elongated chamber having an upper hot zone at a dehydration temperature of from 1000°

C. to 1350°

C. and a lower hot zone at a consolidation temperature of from 1500°

C. to 1650°

C., wherein dehydration takes place in the upper hot zone of the second furnace; and

consolidating the fluorine-doped soot preform by moving it down into the lower hot zone of the second furnace so as to form a fluorine-doped glass preform.

2. The method according to claim 1, wherein, during exposure of the soot preform to an atmosphere containing a fluorine-containing gas, the soot preform is maintained at the doping temperature for a doping time between 20 minutes and 120 minutes.

3. The method according to claim 1, comprising, after exposing the soot preform to an atmosphere containing a fluorine-containing gas and before dehydrating the fluorine-doped soot preform, transferring the fluorine-doped soot preform into the second elongated chamber and positioning the fluorine-doped soot preform in the upper hot zone of the second elongated chamber.

4. The method according to claim 1, wherein the first elongated chamber extends in a vertical direction, the soot preform has a preform length and the single isothermal zone has a length equal to or larger than the preform length so that the whole soot preform is isothermally heated at the doping temperature while exposing the soot preform to an atmosphere containing a fluorine-containing gas.

5. The method according to claim 1, wherein the fluorine-containing gas is a fluorocarbon gas and/or a sulfur/sulfuryl fluoride gas.

6. The method according to claim 1, wherein the first elongated chamber is a first muffle tube of generally cylindrical shape arranged vertically and the first furnace comprises a heater arranged peripherally to the first muffle tube, the heater defining the single isothermal zone.

7. The method according to claim 6, wherein

the first furnace comprises a gas inlet port positioned above the heater and an inner pipe having an inlet end opening and an outlet end opening, the inner pipe being fluidly connected to the gas inlet port through its inlet end opening,

wherein the inner pipe extends vertically downward inside the first muffle tube for guiding an inlet gas flow to a lower portion of the first muffle tube, and

wherein exposing a soot preform to an atmosphere containing a fluorine-containing gas comprises feeding the fluorine-containing gas into an inlet pipe through the gas inlet port to the outlet end opening for the outlet gas flow.

8. The method according to claim 7, wherein the heater extends vertically for a heater length (L) and the inner pipe extends vertically at least throughout the heater length (L).

9. The method according to claim 8, wherein the inner pipe extends downward from the heater so that the outlet end opening of the inner pipe is vertically positioned lower than the heater.

10. The method according to claim 1, wherein the second elongated chamber of the second furnace is a second muffle tube of generally cylindrical shape arranged vertically and the second furnace comprises an upper heater defining the upper hot zone and a lower heater defining the lower hot zone, wherein the lower heater is positioned below the upper heater and the upper heater and the lower heater are arranged peripherally to the second muffle tube.

11. A method for manufacturing a fluorine-doped glass preform for optical fibers, the method comprising:

exposing a soot preform to an atmosphere containing a fluorine-containing gas in a first elongated chamber of a first furnace, the first elongated chamber having an isothermal hot zone maintained at a doping temperature between 800°

C. and 1200°

C. to obtain a fluorine-doped soot preform;

dehydrating the fluorine-doped soot preform by exposing it to an atmosphere containing a chlorine-containing gas in a second elongated chamber of a second furnace, the second elongated chamber having a dehydration hot zone maintained at a dehydration temperature and a consolidation hot zone maintained at a consolidation temperature, wherein dehydration takes place in the dehydration hot zone of the second furnace, wherein the consolidation temperature of the consolidation hot zone is greater than the dehydration temperature of the dehydration hot zone; and

consolidating the fluorine-doped soot preform by positioning it within the consolidation hot zone of the second furnace so as to form a fluorine-doped glass preform.

12. The method according to claim 11, comprising transferring the fluorine-doped soot preform into the second elongated chamber of the second furnace and positioning the fluorine-doped soot preform in the dehydration hot zone of the second elongated chamber of the second furnace.

13. The method according to claim 11, wherein, during dehydration of the fluorine-doped soot preform, the dehydration hot zone is maintained at a dehydration temperature between 1000°

C. and 1350°

C.

14. The method according to claim 11, wherein, during consolidation of the fluorine-doped soot preform, the consolidation hot zone is maintained at a consolidation temperature between 1500°

C. and 1650°

C.

15. The method according to claim 11, wherein, during fluorine-doping of the soot preform, fluorine-containing gas is fed into the first elongated chamber of the first furnace to achieve an atmosphere that contains a fluorine-containing gas but that is substantially devoid of chlorine.

16. The method according to claim 11, wherein, during dehydration and/or consolidation of the fluorine-doped soot preform, chlorine-containing gas is fed into the second elongated chamber of the second furnace to achieve an atmosphere that contains a chlorine-containing gas but that is substantially devoid of fluorine.

17. The method according to claim 11, wherein, during dehydration and consolidation of the fluorine-doped soot preform, the atmosphere within the second elongated chamber of the second furnace is less than 0.01 volume-percent fluorine.

18. The method according to claim 11, wherein the fluorine-doped soot preform is consolidated in an atmosphere substantially devoid of both chlorine and fluorine.

19. A method for manufacturing a fluorine-doped glass preform for optical fibers, the method comprising:

(i) exposing a soot preform to an atmosphere containing a fluorine-containing gas and being substantially devoid of chlorine in a first elongated chamber of a first furnace, the first elongated chamber having a single isothermal hot zone maintained at a doping temperature between 800°

C. and 1200°

C. to obtain a fluorine-doped soot preform,

wherein the first elongated chamber is a first muffle tube of generally cylindrical shape arranged vertically and the first furnace comprises a heater arranged peripherally to the first muffle tube, the heater defining the single isothermal zone,

wherein the first furnace comprises a gas inlet port positioned above the heater and an inner pipe having an inlet end opening and an outlet end opening, the inner pipe being fluidly connected to the gas inlet port through its inlet end opening,

wherein the inner pipe extends vertically downward inside the first muffle tube for guiding an inlet gas flow to a lower portion of the first muffle tube, and

wherein exposing a soot preform to an atmosphere containing a fluorine-containing gas comprises feeding the fluorine-containing gas into an inlet pipe through the gas inlet port to the outlet end opening for the outlet gas flow;

(ii) dehydrating the fluorine-doped soot preform by exposing it to an atmosphere containing a chlorine-containing gas and being substantially devoid of fluorine in a second elongated chamber of a second furnace, the second elongated chamber having an upper hot zone maintained at a dehydration temperature between 1000°

C. and 1350°

C. and a lower hot zone maintained at a consolidation temperature between 1500°

C. and 1650°

C., wherein dehydration takes place in the upper hot zone of the second furnace; and

(iii) consolidating the fluorine-doped soot preform by moving it into the lower hot zone of the second furnace to form a fluorine-doped glass preform.

20. The method according to claim 19, wherein the second elongated chamber of the second furnace is a second muffle tube of generally cylindrical shape arranged vertically and the second furnace comprises an upper heater defining the upper hot zone and a lower heater defining the lower hot zone, wherein the lower heater is positioned below the upper heater and the upper heater and the lower heater are arranged peripherally to the second muffle tube.