MANUFACTURING PROCESS OF POZZOLAN WITH COLOR CHANGE AND POZZOLAN THUS OBTAINED

• US 20200131087A1
• Filed: 04/23/2018
• Published: 04/30/2020
• Est. Priority Date: 04/26/2017
• Status: Active Grant

• Current Assignee: Dynamis Engenharia E Comercio Ltda.
• Original Assignee: Dynamis Engenharia E Comercio Ltda.
• Inventors: FERREIRA, Guilherme Martins, FABIANI, Luis Filipe Von Rainer, DE PINHO, Luiz Felipe, BORGES, Rodrigo De Souza
• Granted Patent: US 11,485,680 B2
• Time in Patent Office: Days
• CPC Class Codes: C04B 14/106 Kaolin
• CPC Class Codes: C04B 20/04 Heat treatment
• CPC Class Codes: C04B 20/061 in rotary kilns
• CPC Class Codes: C04B 20/065 in fluidised beds
• CPC Class Codes: C04B 2103/0088 Compounds chosen for their latent hydraulic characteristics, e.g. pozzuolanes
• CPC Class Codes: C04B 2111/80 Optical properties, e.g. transparency or reflexibility
• CPC Class Codes: C04B 28/18 containing mixtures of the silica-lime type
• CPC Class Codes: C04B 7/12 Natural pozzuolanas; Natural pozzuolana cements; Artificial pozzuolanas or artificial pozzuolana cements other than those obtained from waste or combustion residues, e.g. burned clay; Treating inorganic materials to improve their pozzuolanic characteristics cements containing slag C04B7/14
• CPC Class Codes: C04B 7/13 Mixtures thereof with inorganic cementitious materials, e.g. Portland cements
• CPC Class Codes: C04B 7/44 Burning; Melting
• CPC Class Codes: C04B 7/4415 Waste hot gases
• CPC Class Codes: C04B 7/47 Cooling ; Waste heat management

Abstract

The present invention refers to a manufacturing process of artificial pozzolan which has the final color gray. In order to perform the processes in the desired way, the kiln atmosphere shall contain low oxygen concentration and the presence of reducing agents. However the presence of carbon monoxide at the kiln outlet is not desirable, due to environmental impacts and the increase in specific heat consumption of the kiln. So the process described in this invention comprises the following steps: heating (1), which consists of heating the raw materials to a temperature between 100-350° C. until drying of the material to a moisture mass fraction of 0-5% (wet basis); mixing (2), which consists of mixing the dry raw materials from the heating process with the right proportion of fuel, in from 1% to 5% in mass fraction, according to the concentration of hematite present in the raw material; calcining (3), which consists of heating the fuel and raw materials blend to a temperature between 700-900° C., with oxygen concentration between 1-5% and, finally, cooling (4), which consists of an initial step of rapid decrease in pozzolan temperature until 600° C. and a final step of slow decrease in pozzolan temperature until 120° C.

Claims

1. Manufacturing process of pozzolan with color change, comprising the following steps:

Heating (1);

consists of heating the a raw material blend to a temperature between 100-350°

C. until the material is dried to a range of moisture between 0-5% (wet basis);

Mixture (2);

consists of mixing dry raw materials that came from the heating step, with 1-5% of fuel mass fraction according to the hematite concentration of the raw material;

Calcining (3);

consists of heating the blend of fuel with the dry raw materials to a temperature between 700-900°

C., with oxygen concentration between 1-5%; and

Cooling (4);

consists of an initial step with fast decrease in temperature to 600°

C. and a final step with pozzolan temperature decrease to 120°

C.

2. A process, according to claim 1, characterized by the mixture step (2) preceding the heating step (1), the heating step consisting of heating a blend of the raw materials and solid fuel from the mixture step (2) to a temperature between 100-350°

C. until drying of the blend to a moisture mass fraction of 0-5% (wet basis).

3. A process, according to claim 1, characterized by the fact that the fuel is a solid selected from the following:

mineral coal, charcoal, petroleum coke, pulverized coal, biomass or a carbon rich waste.

4. A process, according to claim 1, characterized by the fact that during the mixture step (2) an amount of solid fuel added is about 0% for a hematite concentration below 3% in the raw material composition;

about 1.5% for a hematite concentration between 3-5% in the raw material composition;

about 3% for a hematite concentration between 5-8% in the raw material composition; and

about 5% for a hematite concentration between 8-12% in the raw material composition.

5. A process, according to claim 1, characterized by the fact that the calcining step (3) makes use of low oxygen recirculated gases from exhaust.

6. A process, according to claim 1, characterized by the fact that during the calcining step (3) the combustion of solid, liquid or gaseous fuel takes place inside a compact combustion pre-chamber.

7. A process, according to claim 1, characterized by the fact that the calcining equipment is selected from:

rotating kiln or fluidized bed or flash calciner.

8. A process, according to claim 1, characterized by the fact that the cooling (4) takes place in a cooler selected from:

rotary cooler or fluidized bed or flash cooler.

9. A process, according to claim 8, characterized by the fact that the cooling (4) comprises keeping the external side of the drum wet, in case of a rotary or flash cooler, or by the use of a water serpentine, in case of a fluidized bed.

10. A process, according to claim 1, characterized by the fact that the cooling (4) comprises a second step that is selected according to the concentration of hematite in the raw material.

11. A process, according to claim 10, characterized by the fact that the second step of the cooling (4) comprises:

Direct use of ambient air, for a concentration of hematite below 3%;

Direct use of recirculated gases, for a concentration of hematite between 3-6%;

Direct use of ambient air combined with indirect use of water, for a concentration of hematite between 6-10%;

or

Direct use of recirculated gases combined with indirect use of water, for a concentration of hematite above 10%.

12. Pozzolan, characterized by being manufactured according to the process of claim 1.

13. Pozzolan, characterized by being manufactured according to the process of claim 2.

14. Pozzolan, characterized by being manufactured according to the process of claim 4.