BLOW MOLDED ARTICLES FORMED FROM POLYOLEFIN COMPOSITIONS

• US 20200131350A1
• Filed: 10/24/2019
• Published: 04/30/2020
• Est. Priority Date: 10/24/2018
• Status: Active Application

• Current Assignee: Braskem SA
• Original Assignee: Braskem SA
• Inventors: Mano, Barbara Iria Silva, Farah, Marcelo, Stocker, Mariele Kaipers, Bueno, Marcos Roberto Paulino, Laurini, Rafael Vilela, Gomes, Ronaldo Bollinelli, Camilo, Ana Paula Rodrigues
• Application Number:
  US16/663,121
• Publication Number:
  US 20200131350A1
• Time in Patent Office: Days
• CPC Class Codes: B29C 49/0005 characterised by the material
• CPC Class Codes: B29K 2023/06 PE, i.e. polyethylene
• CPC Class Codes: B29K 2023/0691 PEX, i.e. crosslinked polyethylene
• CPC Class Codes: B29K 2105/16 Fillers
• CPC Class Codes: B29K 2105/24 crosslinked or vulcanised
• CPC Class Codes: B29K 2105/26 Scrap or recycled material
• CPC Class Codes: B29L 2031/712 Containers; Packaging elements or accessories, Packages closures therefor B29L2031/56; ink or toner cartridges B29L2031/7678; squeeze tubes B29L2023/20; suitcases B29L2031/7418
• CPC Class Codes: C08L 2205/025 containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
• CPC Class Codes: C08L 2205/035 containing four or more polymers in a blend
• CPC Class Codes: C08L 2205/14 containing polymeric additives characterised by shape
• CPC Class Codes: C08L 2207/02 Heterophasic composition
• CPC Class Codes: C08L 2207/062 HDPE
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 2310/00 Masterbatches

Abstract

A blow molded article may include a polymer matrix comprising virgin or recycled polyolefin; and one or more polymer particles dispersed in the polymer matrix, wherein the one or more polymer particles comprise a polar polymer selectively crosslinked with a crosslinking agent. The one or more polymer particles has an average particle size of up to 200 μm. Further, the blow molded article may possess improved ESCR, while maintaining stacking resistance, drop impact resistance, leakproofness, internal hydrostatic pressure resistance, and/or barrier to volatile organic compounds.

Claims

1. A blow molded article, comprising:

a polymer matrix comprising a polyolefin; and

one or more polymer particles dispersed in the polymer matrix, wherein the one or more polymer particles comprise a polar polymer selectively crosslinked with a crosslinking agent, and wherein the one or more polymer particles has an average particle size of up to 200 μ

m.

2. The blow molded article of claim 1, wherein the blow molded article has an environmental stress cracking resistance value that is at least 25% higher than that of a comparative blow molded article formed from the polymer matrix.

3. The blow molded articles of claim 1, wherein the polymer matrix further comprises a functionalized polyolefin.

4. The blow molded article of claim 1, wherein the polyolefin comprises a high density polyethylene having a density, measured according to ASTM D792, ranging from 0.935 to 0.970 g/cm³.

5. The blow molded article of claim 4, wherein the high density polyethylene has a melt index, measured according to ASTM D1238 at 190°

C./21.6 kg, ranging from 1 to 60 g/10 min.

6. The blow molded article of any claims 4, wherein the high density polyethylene has a melt index, measured according to ASTM D1238 at 190°

C./2.16 kg, ranging from 0.01 to 5 g/10 min.

7. The blow molded article of claim 1, wherein the matrix polymer comprises at least one selected from post consumer resin, post industrial resin, regrind polymer, and combinations thereof.

8. The blow molded article of claim 1, wherein the polar polymer comprises a hydroxyl functional group.

9. The blow molded article of claim 8, wherein the polar is selected from PVOH and/or EVOH.

10. The blow molded article of claim 1, wherein the blow molded article has a substantially similar compressive strength, drop impact resistance and/or internal hydrostatic pressure resistance compared to a comparative blow molded article formed from the polymer matrix.

11. The blow molded article of claim 1, wherein the blow molded article can withstand a UN stacking test for at least 28 days without collapsing.

12. The blow molded article of claim 1, wherein the blow molded article can withstand a UN burst resistance test holding at least 250 kPa without leaking.

13. The blow molded article of claim 1, wherein the blow molded article is a monolayer article.

14. The blow molded article of claim 1, wherein the blow molded article is a multilayered article comprising an innermost layer comprising:

the polymer matrix comprising a polyolefin; and

the one or more polymer particles dispersed in the polymer matrix.

15. The blow molded article of claim 1, further comprising:

one or more additives chosen from pigments, processing aids, fillers, nucleating agents, plasticizers, flame retardants and stabilizers.

16. A blow molded article comprising:

a masterbatch composition comprising a polymer matrix comprising a polyolefin and one or more polymer particles dispersed in the polymer matrix, wherein the one or more polymer particles comprise a polar polymer selectively crosslinked with a crosslinking agent, and wherein the one or more polymer particles has an average particle size of up to 200 μ

m; and

a secondary polymer comprising a polyolefin.

17. The blow molded article of claim 16, wherein the blow molded article has an environmental stress cracking resistance value that is at least 25% higher than that of a comparative blow molded article formed from the secondary polymer.

18. The blow molded articles of claim 16, wherein the polymer matrix further comprises a functionalized polyolefin.

19. The blow molded article of claim 16, wherein the polyolefin comprises a high density polyethylene having a density, measured according to ASTM D792, ranging from 0.935 to 0.970 g/cm³.

20. The blow molded article of claim 19, wherein the high density polyethylene has a melt index, measured according to ASTM D1238 at 190°

C./21.6 kg, ranging from 1 to 60 g/10 min.

21. The blow molded article of any claims 19, wherein the high density polyethylene has a melt index, measured according to ASTM D1238 at 190°

C./2.16 kg, ranging from 0.01 to 5 g/10 min.

22. The blow molded article of claim 16, wherein the matrix polymer comprises at least one selected from post consumer resin, post industrial resin, regrind polymer, and combinations thereof.

23. The blow molded article of claim 16, wherein the secondary polymer comprises at least one selected from post consumer resin, post industrial resin, regrind polymer, and combinations thereof.

24. The blow molded article of claim 16, wherein the masterbatch composition is used in an amount as low as 0.05 wt %, and the secondary polymer is used in an amount as much as 99.5 wt %, relative to the combined total of masterbatch composition and the secondary polymer.

25. The blow molded article of claim 16, wherein the blow molded article has a substantially similar compressive strength, drop impact resistance and/or internal hydrostatic pressure resistance compared to a comparative blow molded article formed from the secondary polymer.

26. The blow molded article of claim 16, wherein the blow molded article can withstand a UN stacking test for at least 28 days without collapsing.

27. The blow molded article of claim 16, wherein the blow molded article can withstand a UN burst resistance test holding at least 250 kPa without leaking.

28. The blow molded article of claim 16, wherein the blow molded article is a monolayer article.

29. The blow molded article of claim 16, wherein the blow molded article is a multilayered article comprising an innermost layer comprising:

the polymer matrix comprising a polyolefin; and

the one or more polymer particles dispersed in the polymer matrix.

30. The blow molded article of claim 16, further comprising:

one or more additives chosen from pigments, processing aids, fillers, nucleating agents, plasticizers, flame retardants and stabilizers.

32. The process of claim 20, further comprising:

melt blending a masterbatch composition comprising the polyolefin in which the polymer particles are dispersed with a secondary polymer.

33. The process of claim 20, further comprising:

dry blending a masterbatch composition comprising the polyolefin in which the polymer particles are dispersed with a secondary polymer.

31. A process for preparing an article, the process comprising:

blow molding a polymer composition to form a blow molded article, the blow molded article comprising;

a polymer matrix comprising a polyolefin; and

one or more polymer particles dispersed in the polymer matrix, wherein the one or more polymer particles comprise a polar polymer selectively crosslinked with a crosslinking agent, and wherein the one or more polymer particles has an average particle size of up to 200 μ

m.