AQUEOUS INKJET INK AND INK SETS

• US 20200131387A1
• Filed: 10/26/2018
• Published: 04/30/2020
• Est. Priority Date: 10/26/2018
• Status: Active Grant

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Sowinski, Allan Francis, Eugene, Bugner Douglas, Lee, Cook Wayne
• Granted Patent: US 11,248,134 B2
• Time in Patent Office: Days
• CPC Class Codes: C08K 2003/387 Borates
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08K 3/38 Boron-containing compounds
• CPC Class Codes: C08K 5/0041 Optical brightening agents, organic pigments
• CPC Class Codes: C08K 5/05 Alcohols; Metal alcoholates
• CPC Class Codes: C08K 5/205 Compounds containing groups, e.g. carbamates
• CPC Class Codes: C09D 11/322 Pigment inks
• CPC Class Codes: C09D 11/326 characterised by the pigment dispersant
• CPC Class Codes: C09D 11/38 characterised by non-macromolecular additives other than solvents, pigments or dyes
• CPC Class Codes: C09D 11/40 Ink-sets specially adapted for multi-colour inkjet printing
• CPC Class Codes: C09D 11/54 Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink

Abstract

Aqueous inkjet ink compositions are useful in inkjet printing processes and can be used individually or as part of an inkjet ink set. Each aqueous inkjet ink composition has a dynamic viscosity of 5 centipoise (5 mPa-sec) or less at 25° C., and consists essentially of: (a) a polymer-dispersed pigment colorant at 0.9-6 weight %; (b) a composition consisting of compounds represented by the following Structure (I):

HO—CH₂—CH₂—R   (I)

wherein R is a substituted or unsubstituted phenyl group or a substituted or unsubstituted phenoxy group, at 0.5-2 weight %; (c) a water-soluble humectant, co-solvent, or both, at than or equal to 20 weight %. Each polymer-dispersed pigment colorant has a 50^th percentile particle diameter of less than 70 nm and a 95^th percentile particle diameter of less than 150 nm, as measured using a dynamic light scattering particle size analyzer.

Claims

1. An aqueous inkjet ink composition having a dynamic viscosity of less than or equal to 5 centipoise (5 mPa-sec) at 25°

C., and consisting essentially of;

(a) one or more polymer-dispersed pigment colorants in a total amount of at least 0.9 weight % and up to and including 6 weight %, based on the total weight of the aqueous inkjet ink composition;

(b) a composition consisting of one or more compounds represented by the following Structure (I);

HO—

CH₂—

CH₂—

R 

 

(I)

wherein R is a substituted or unsubstituted phenyl group or a substituted or unsubstituted phenoxy group, in a total amount of at least 0.5 weight % and up to and including 2 weight %, based on the total weight of the aqueous inkjet ink composition;

(c) one or more compounds selected from water-soluble humectants, co-solvents, and both water-soluble humectants and co-solvents, in an amount of less than or equal to 20 weight %, based on the total weight of the aqueous inkjet composition,

wherein each of the one or more polymer-dispersed pigment colorants has a 50^th percentile particle diameter of less than 70 nm and a 95^th percentile particle diameter of less than 150 nm, all particle diameters being measured using a dynamic light scattering particle size analyzer.

2. The aqueous inkjet ink composition of claim 1, further comprising a (d) supplemental antimicrobial agent that is different from the (b) composition.

3. The aqueous inkjet ink composition of claim 2, wherein the (d) supplemental antimicrobial agent is iodopropynyl butyl carbamate, piroctone olamine, 2,4-dichlorobenzyl alcohol, boric acid or a metal ion salt derived from boric acid, or a combination these compounds.

4. The aqueous inkjet ink composition of claim 1, wherein the one or more (c) compounds are present in an amount of least 0.5 weight % and up to and including 15 weight %, based on the total weight of the aqueous inkjet ink composition.

5. The aqueous inkjet ink composition of claim 1, further containing an anionic polyurethane, an anionic non-aromatic acrylic polymer, an anionic styrene-acrylic polymer, or a combination of two or more of such materials, each of these materials having an acid number of at least 50.

6. The aqueous inkjet ink composition of claim 1, wherein each of the one or more polymer-dispersed pigment colorants has a 50^th percentile particle diameter of less than 60 nm and a 95^th percentile particle diameter of less than 110 nm, all particle diameters being measured using a dynamic laser light scattering particle size analyzer.

7. The aqueous inkjet ink composition of claim 1 having a pH of at least 7.5 and up to and including 11.

8. The aqueous inkjet ink composition of claim 1, further containing one or more promoters for the one or more Structure (I) compounds in the (b) composition, each of which promoter is an alkane diol having a least 7 carbon atoms and up to and including 12 carbon atoms, in an amount of less than or equal to 1.5 weight %, based on the total weight of the aqueous inkjet ink composition.

9. The aqueous inkjet ink composition of claim 8, wherein the promoter is 1,2-octanediol.

10. The aqueous inkjet ink composition of claim 1, wherein R is either an unsubstituted phenyl group or an unsubstituted phenoxy group.

11. An ink set comprising two or more aqueous inkjet ink compositions, each of which independently has a dynamic viscosity of less than or equal to 5 centipoise (5 mPa-sec) at 25°

C., and each of which aqueous inkjet ink compositions independently consists essentially of;

(a) one or more polymer-dispersed pigment colorants in a total amount of at least 0.9 weight % and up to and including 6 weight %, based on the total weight of the aqueous inkjet ink composition;

(b) a composition consisting of one or more compounds represented by the following Structure (I);

HO—

CH₂—

CH₂—

R 

 

(I)

wherein R is a substituted or unsubstituted phenyl group or a substituted or unsubstituted phenoxy group, in a total amount of at least 0.5 weight % and up to and including 2 weight %, based on the total weight of the aqueous inkjet ink composition;

(c) one or more compounds selected from water-soluble humectants, co-solvents, and a combination of water-soluble humectants and co-solvents, in an amount of less than or equal to 20 weight %, based on the total weight of the aqueous inkjet composition,

wherein each of the one or more polymer-dispersed pigment colorants has a 50^th percentile particle diameter of less than or equal to 70 nm and a 95^th percentile particle diameter of less than or equal to 150 nm, all particle diameters being measured using a dynamic light scattering particle size analyzer.

12. The ink set of claim 11, comprising two or more of the following:

(i) an aqueous inkjet ink composition comprising a polymer-dispersed cyan pigment colorant,

(ii) an aqueous inkjet ink composition comprising a polymer-dispersed magenta pigment colorant,

(iii) an aqueous inkjet ink composition comprising a polymer-dispersed yellow pigment colorant, and

(iv) an aqueous inkjet ink composition comprising a polymer-dispersed black pigment colorant.

13. The ink set of claim 11, further comprising a particle-free colorless inkjet composition.

14. The ink set of claim 13, wherein the particle-free colorless inkjet composition comprises the same or different (b) composition as is present in each of the two or more aqueous inkjet ink compositions.

15. The ink set of claim 11, wherein any of the two or more aqueous inkjet ink compositions further contains a (d) supplemental antimicrobial agent that is different from the (b) composition.

16. The ink set of claim 15, wherein the (d) supplemental antimicrobial agent is iodopropynyl butyl carbamate, piroctone olamine, 2,4-dichlorobenzyl alcohol, boric acid or metal ion salt derived from boric acid, or a combination of these compounds.

17. The ink set of claim 11, wherein each of the one or more polymer-dispersed pigment colorants has a 50^th percentile particle diameter of less than 60 nm and a 95^th percentile particle diameter of less than 110 nm, all particle diameters being measured using a dynamic laser light scattering particle size analyzer.

18. The ink set of claim 11, wherein any of the two or more aqueous inkjet ink compositions further contains one or more promoters for the one or more Structure (I) compounds of the (b) composition, each of which promoters is an alkane diol having a least 7 carbon atoms and up to and including 12 carbon atoms, in an amount of less than or equal to 1.5 weight %, based on the total weight of the aqueous inkjet ink composition.

19. The ink set of claim 18 wherein the promoter is 1,2-octanediol.

20. The ink set of claim 11, wherein R is either an unsubstituted phenyl group or an unsubstituted phenoxy group.