THERMALLY CONDUCTIVE, ELECTRICALLY INSULATING COATING FOR WIRES

• US 20200131401A1
• Filed: 06/29/2018
• Published: 04/30/2020
• Est. Priority Date: 06/30/2017
• Status: Abandoned Application

• Current Assignee: SHPP Global Technologies BV (Government of Saudi Arabia)
• Original Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Inventors: XIE, Yuming, ODEH, Ihab, PANNALA, Sreekanth
• Application Number:
  US16/626,931
• Publication Number:
  US 20200131401A1
• Time in Patent Office: Days
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C08G 73/14 Polyamide-imides
• CPC Class Codes: C08K 2003/382 and nitrogen
• CPC Class Codes: C08K 2201/005 Additives being defined by their particle size in general
• CPC Class Codes: C08K 2201/016 Additives defined by their aspect ratio
• CPC Class Codes: C08K 3/38 Boron-containing compounds
• CPC Class Codes: C08K 9/02 Ingredients treated with inorganic substances
• CPC Class Codes: C08K 9/06 with silicon-containing compounds
• CPC Class Codes: C08L 2201/00 Properties
• CPC Class Codes: C08L 2203/202 use in electrical wires or wirecoating
• CPC Class Codes: C09D 179/08 Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
• CPC Class Codes: C09D 181/08 Polysulfonates
• CPC Class Codes: H01B 3/306 Polyimides or polyesterimides
• CPC Class Codes: H01B 3/307 Other macromolecular compounds
• CPC Class Codes: H01B 3/427 Polyethers

Abstract

A coating composition comprises: exfoliated boron nitride nano sheets (BNNS); and a thermoplastic polymer matrix, wherein the coating composition: (i) has a thermal conductivity greater than or equal to 1.0 W/mK; (ii) has an electric breakdown voltage higher than or equal to 20 kV/mm; and (iii) is pliable. The coating composition can also include the exfoliated BNNS bound to the surfaces of a plurality of co-particles that aligns a plane of the BNNS not parallel to a longitudinal axis of an electromagnetic wire. The non-parallel alignment increases thermal conductivity through the coating. The polymer matrix can be a polyester imide, a polyamide-imide, polysulfones, a polyimide, a polyether ketone, or combinations thereof. Methods of forming the coating include forming the exfoliated BNNS; combining a first monomer and a second monomer to form the thermoplastic polymer matrix; and causing or allowing the exfoliated BNNS to be dispersed throughout the thermoplastic polymer matrix.

Claims

1. A coating composition comprising:

exfoliated boron nitride nano sheets; and

a thermoplastic polymer matrix, wherein the coating composition;

(i) has a thermal conductivity greater than or equal to 1.0 W/mK;

(ii) has an electric breakdown voltage greater than or equal to 20 kV/mm; and

(iii) is pliable.

2. The coating composition according to claim 1, wherein the exfoliated boron nitride nano sheets are in a concentration in the range of about 1% to about 25% by volume of the coating composition.

3. The coating composition according to claim 1, further comprising a plurality of co-particles, wherein a first edge of the exfoliated boron nitride nano sheets are bound to the surfaces of the co-particles.

4. The coating composition according to claim 3, wherein the co-particles are selected from the group consisting of boron nitride BN, boron carbide B₄C, aluminum nitride AlN, aluminum oxide Al₂O₃, silicon dioxide SiO₂, magnesium oxide MgO, silicon carbide SiC, silicon nitride Si₃N₄, zinc oxide ZnO, beryllium oxide BeO, diamond, metal oxides, titanium oxide, quartz, ceramics, and combinations thereof.

5. The composition according to claim 3, wherein the co-particles are BN.

6. The composition according to claim 3, wherein the co-particles are in a concentration in the range of about 1% to about 20% by volume of the coating composition.

7. The composition according to claim 1, wherein the thermoplastic polymer is thermally stable up to a temperature of 180°

C.

8. The composition according to claim 7, wherein the thermoplastic polymer is polyester imide.

9. The composition according to claim 1, wherein the thermoplastic polymer is thermally stable up to a temperature of 200°

C.

10. The composition according to claim 9, wherein the thermoplastic polymer is polyamide-imide, polysulfones, or combinations thereof.

11. The composition according to claim 1, wherein the thermoplastic polymer is thermally stable at a temperature greater than or equal to 240°

C.

12. The composition according to claim 11, wherein the thermoplastic polymer is a polyimide or a polyether ketone.

13. The composition according to claim 1, wherein the coating composition is coated onto an electromagnetic wire.

14. The composition according to claim 1, wherein the exfoliated boron nitride nano sheets have an average thickness of less 10 molecular layers and an aspect ratio greater than 350.

15. A method of forming a coating composition comprising:

forming exfoliated boron nitride nano sheets;

combining a first monomer and a second monomer to form a thermoplastic polymer matrix; and

causing or allowing the exfoliated boron nitride nano sheets to be dispersed throughout the thermoplastic polymer matrix, wherein the coating composition;

(i) has a thermal conductivity greater than or equal to 1.0 W/mK;

(ii) has an electric breakdown voltage greater than or equal to 20 kV/mm; and

(iii) is pliable.

16. The method according to claim 15, further comprising oxidizing the surface of boron nitride powder prior to the step of forming the exfoliated boron nitride nano sheets.

17. The method according to claim 16, further comprising:

adding the surface oxidized boron nitride powder to the first monomer and a solvent;

then exfoliating the boron nitride nano sheets and performing a silane treatment on the exfoliated boron nitride nano sheets and first monomer;

and then combining the second monomer with the exfoliated boron nitride nano sheets and first monomer.

18. The method according to claim 17, further comprising adding a plurality of co-particles after the step of combining the second monomer with the exfoliated boron nitride nano sheets and first monomer, and allowing the exfoliated boron nitride nano sheets to bond to the surfaces of the plurality of co-particles to form a filler.

19. The method according to claim 15, further comprising adding a plurality of co-particles before the step of combining the second monomer with first monomer, and allowing the exfoliated boron nitride nano sheets to bond to the surfaces of the plurality of co-particles to form a filler.

20. The method according to claim 15, further comprising dip coating the coating composition onto an electromagnetic wire.

21. (canceled)