STRETCHABLE FABRIC BASED ELECTRODE-POLYMER ELECTROLYTE BATTERY

• US 20200136101A1
• Filed: 04/24/2018
• Published: 04/30/2020
• Est. Priority Date: 04/27/2017
• Status: Active Grant

• Current Assignee: University of Houston System
• Original Assignee: University of Houston System
• Inventors: Ardebili, Haleh, Moradi, Bahar
• Granted Patent: US 11,108,106 B2
• Time in Patent Office: Days
• CPC Class Codes: H01M 10/0436 Small-sized flat cells or batteries for portable equipment
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/0565 Polymeric materials, e.g. gel-type or solid-type
• CPC Class Codes: H01M 10/0585 of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 4/131 Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• CPC Class Codes: H01M 4/133 Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
• CPC Class Codes: H01M 4/661 Metal or alloys, e.g. alloy coatings H01M4/669 take precedence
• CPC Class Codes: H01M 4/747 Woven material
• CPC Class Codes: H01M 50/121 Organic material
• CPC Class Codes: H01M 50/136 Flexibility or foldability
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A flexible and stretchable fabric based electrode-polymer electrolyte battery described herein comprises at least one electrochemical cell. The electrochemical cell comprises a first stretchable electrode having a first active material coupled with a first stretchable fabric current collector, a second stretchable electrode having a second active material coupled with a second stretchable fabric current collector, a stretchable separator configured between the first and second electrodes, and at least one stretchable encapsulant material, wherein the stretchable material encapsulates the electrochemical cell and is capable of reversible bending, twisting, folding and stretching.

Claims

1. A stretchable battery, comprising:

at least one electrochemical cell, wherein the electrochemical cell comprises;

a first stretchable electrode, wherein the first stretchable electrode comprises a first stretchable fabric current collector layer having an inner surface and an upper surface, a first electrode material coupled to the inner surface of the first stretchable fabric current collector layer to form a first active electrode surface on the inner surface of the first stretchable fabric current collector layer, and a first electrode terminal connected to the upper surface of the first stretchable fabric current collector layer;

a second stretchable electrode, wherein the second stretchable electrode comprises a second stretchable fabric current collector layer having an inner surface and an upper surface, a second electrode material coupled to the inner surface of the second stretchable fabric current collector layer to form a second active electrode surface on the inner surface of the second stretchable fabric current collector layer, and a second electrode terminal connected to the upper surface of the first stretchable fabric current collector layer;

a stretchable separator material coupled to the first active electrode surface and the second active electrode surface, wherein the first active electrode surface and the second active electrode surface are separated by the stretchable separator material, wherein the first stretchable electrode and the second stretchable electrode form an electrode assembly, and wherein the upper surfaces of the first stretchable fabric current collector layer and the second stretchable fabric current collector layer form outer layers of the electrode assembly; and

an encapsulant material surrounding at least a portion of the electrode assembly, wherein a portion of the first electrode terminal and a portion of the second electrode terminal extend out of the encapsulant material.

2. The stretchable battery of claim 1, wherein at least one of the first stretchable fabric current collector layer or the second stretchable fabric current collector layer is comprised of inherently electrically conductive material.

3. The stretchable battery of claim 2, wherein the inherently electrically conductive material is a stretchable silver woven fabric.

4. The stretchable battery of claim 1, wherein at least one of the first stretchable fabric current collector layer or the second stretchable fabric current collector layer is comprised of nonconductive stretchable fabric further comprising conductive filler materials that form a network within the nonconductive stretchable fabric.

5. The stretchable battery of claim 4, wherein the conductive filler materials are carbon fillers.

6. The stretchable battery of claim 1, wherein the first electrode material comprises cathode active materials and the second electrode material comprises anode active materials.

7. The stretchable battery of claim 1, wherein the stretchable separator material is electrically insulating stretchable fabric.

8. The stretchable battery of claim 1, wherein the stretchable separator material is ion conductive electrolyte material.

9. The stretchable battery of claim 1, wherein the stretchable separator material is a solid polymer electrolyte.

10. The stretchable battery of claim 1, wherein the stretchable separator material is ion nonconductive material integrated with an electrolyte material.

11. The stretchable battery of claim 1, wherein the encapsulant material is a curing agent, lamination agent, adhesive agent, or combinations thereof.

12. The stretchable battery of claim 11, wherein the encapsulant material is viscous silicone paste.

13. The stretchable battery of claim 1, wherein the encapsulant material is a solid encapsulant material.

14. The stretchable battery of claim 13, wherein the solid encapsulant material is very high bond tape or silicone.

15. A method for preparing a stretchable battery, comprising:

(a) coupling a first electrode material to an inner surface of a first stretchable fabric current collector layer to form a first active electrode surface on the inner surface of the first stretchable fabric current collector layer;

(b) connecting a first electrode terminal to an upper surface of the first stretchable fabric current collector layer, wherein the first electrode material, the first stretchable fabric current collector layer, and the first electrode terminal make up a first stretchable electrode;

(c) coupling a second electrode material to an inner surface of a second stretchable fabric current collector layer to form a second active electrode surface on the inner surface of the second stretchable fabric current collector layer;

(d) connecting a second electrode terminal to an upper surface of the second stretchable fabric current collector layer, wherein the second electrode material, the second stretchable fabric current collector layer, and the second electrode terminal make up a second stretchable electrode;

(e) coupling a stretchable separator material to the first active electrode surface and the second active electrode surface, whereby the first active electrode surface and the second active electrode surface are separated by the stretchable separator material, and wherein the first stretchable electrode and the second stretchable electrode form an electrode assembly;

(f) surrounding at least a portion of the electrode assembly with an encapsulant material to form a first electrochemical cell making up a stretchable battery, wherein a portion of the first electrode terminal and a portion of the second electrode terminal extend out of the encapsulant material.

16. The method of claim 15, further comprising repeating steps (a)-(f) to form one or more additional electrochemical cells making up the stretchable battery.